The aim of this work is to study the effect of reaction conditions using steamed ammonia liquid waste without the use of additives on the crystallization of calcium carbonate. CaCO₃ was prepared by steamed ammonia liquid waste (CaCl₂) and (NH₄)₂CO₃ solution. The produced crystals were characterized by scanning electron microscopy (SEM), Fourier transform infrared spectrometry (FTIR) and X-ray diffraction (XRD). We have investigated the effect of the concentration of reactants, stirring speed, Ca²⁺ : CO₃ ²⁻ ratio, aging time and adding mode on the particle size and size distribution, final morphology and polymorph of calcium carbonate crystals during precipitation. The influence of concentration of reactants, stirring speed, Ca²⁺ : CO₃ ²⁻ ratio, aging time and adding mode on the morphology, size and polymorph of CaCO₃ particles and possible formation mechanism were discussed. The exploration provides the possibility for large-scale synthesis of CaCO₃ materials with controllable morphology and crystallographic structure by steamed ammonia liquid waste without use of additives at room temperature.

The results indicated that the CaCO₃ morphology, particle size, and crystal phase were significantly influenced by the NH₄⁺ concentration were investigated upon the use of steamed ammonia liquid waste (CaCl₂) in a rapid fabrication technique.

Herein, metastable spheroidal vaterite calcium carbonate (CaCO₃) was prepared using a simple ultrasound technique. The fabricated material comprises an irregular nanoparticle aggregate when steamed ammonia liquid waste, that is, (CaCl₂) and (NH₄)₂CO₃, is used as the raw material at atmospheric temperature, without any surfactants. The effects of ultrasound amplitude, probe immersion depth, and solution volume on particle properties were investigated. The obtained samples were identified and characterized by X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, and the Brunauer–Emmett–Teller technique. Our experiments show that the probe immersion depth and the reaction volume are the key parameters that impact the diameter size and size distribution of the fabricated spheroidal vaterite CaCO₃ particles. The ultrasound amplitude considerably affected the particle size and the specific surface area. A possible formation mechanism for pure vaterite is proposed herein, which suggests that simple vaterite CaCO₃ is formed owing to the special properties of steamed ammonia liquid waste and the synergistic effects of the ultrasonic system. This study may provide a new method for vaterite CaCO₃ synthesis.

Magnesium hydroxide (Mg(OH)₂), as a green halogen-free flame retardant, has attracted significant attention in the field of flame retardant composite materials.

In the salt lake industry, large amounts of steamed ammonia liquid waste are discharged as byproducts. The conversion of the residues into high value-added vaterite-phase calcium carbonate products for industrial applications is highly desirable. In this research, the feasibility of preparing vaterite-phase CaCO₃ in different CaCl₂-CO₂-MOH-H₂O systems using steamed ammonia liquid waste was studied in the absence of additives. The effects of initial CaCl₂ concentration, stirring speed and CO₂ flow rate on the composition of the CaCO₃ crystal phase were investigated. The contents of vaterite were researched by the use of steamed ammonia liquid waste as a calcium source and pure calcium chloride as a contrast. The influence of the concentration of CNH₃·H₂O/C_Ca²⁺ on the carbonation ratio and crystal phase composition was studied. The reaction conditions on the content, particle size and morphology of vaterite influence were discussed. It was observed that single vaterite-phase CaCO₃ was favored in the CaCl₂-CO₂-NH₄OH-H₂O system. Additionally, the impurity ions in steamed ammonia liquid waste play a key role in the nucleation and crystallization of vaterite, which could affect the formation of single-phase vaterite. The obtained results provided a novel method for the preparation of single vaterite particles with the utilization of CO₂ and offered a selective method for the extensive utilization of steamed ammonia liquid waste.

Benign design of alkali-activated slag/FA geopolymer paste has attracted increasing attention for optimizing its service performance. Therefore, the replacement of fly ash (FA) with 10 wt% silica fume (SF) is investigated by mechanical strength after freeze–thawing cycles and microstructure characterization. The results show that an appropriate dosage (30 wt%) of slag is necessary to prepare heat-free curing alkali-activated slag/FA geopolymer paste with excellent mechanical performance. The SF/slag/FA (SF:slag:FA = 10:30:60, wt%) geopolymer paste exerts an enhanced compressive and flexural strength of 95.2 and 3.2 MPa, respectively. Meanwhile, the doped 10 wt% SF facilitates the propagation of (N, C)-A-S-H chains, rather than the formation of C-S-H gels. It is evidenced by the absent exothermic peak at about 861 °C from the differential scanning calorimetry (DSC) curves. The pores volume and tortuosity also rise for the pore diameter < 20 nm from mercury intrusion porosimeter (MIP) results, corresponding to an improved freezing–thawing resistance with the residual compressive strength of 52.8 MPa and the weight loss of 10.5% after 300 freeze–thawing cycles. It explores a cost-effective and benign facile approach to designing heat-free curing alkali-activated slag/FA geopolymer paste with good freezing–thawing resistance.