The thermal ageing of an Ethylene-vinyl Acetate (EVA) polymer used as an adhesive and encapsulant in a photovoltaic module has been investigated. The EVA is used to bond the silicon solar cells to the front glass and backing sheet and to protect the photovoltaic materials from the environment and mechanical damage. Using a range of experimental techniques, including Dynamic Mechanical Analysis, Differential Scanning Calorimetry and Thermo-Gravimetric analysis, it was possible to show a link between changes in mechanical properties with both the transient temperature and the degree of long-time thermal ageing. Importantly, it was possible to show that the ageing related property changes were likely due to long term structural changes rather than any modification of the chemistry of the material

Soil moisture monitoring is a fundamental process to enhance agricultural outcomes and to protect the environment. The traditional methods for measuring moisture content in the soil are laborious and expensive, and therefore there is a growing interest in developing sensors and technologies which can reduce the effort and costs. In this work, we propose to use an autonomous mobile robot equipped with a state‐of‐the‐art noncontact soil moisture sensor building moisture maps on the fly and automatically selecting the most optimal sampling locations. We introduce an autonomous exploration strategy driven by the quality of the soil moisture model indicating areas of the field where the information is less precise. The sensor model follows the Poisson distribution and we demonstrate how to integrate such measurements into the kriging framework. We also investigate a range of different exploration strategies and assess their usefulness through a set of evaluation experiments based on real soil moisture data collected from two different fields. We demonstrate the benefits of using the adaptive measurement interval and adaptive sampling strategies for building better quality soil moisture models. The presented method is general and can be applied to other scenarios where the measured phenomena directly affect the acquisition time and need to be spatially mapped.

Cosmic‐Ray Neutron Probes (CRNP) have found application in soil moisture (SM) estimation due to their conveniently large (>100 m) footprints. Here, we explore the possibility of using high‐density polyethylene (HDPE) moderator to limit the field of view, and hence, the footprint of a SM sensor formed of 12 CRNP mounted on to a mobile robotic platform (Thorvald) for better in‐field localization of moisture variation. Ultra Rapid Adaptable Neutron‐Only Simulation neutron scattering simulations are used to show that 5 cm of additional HDPE moderator (used to shield the upper surface and sides of the detector) is sufficient to (a) reduce the footprint of the detector considerably, (b) approximately double the percentage of neutrons detected from within 5 m of the detector, and (c) does not affect the shape of the curve used to convert neutron counts into SM. Simulation and rover measurements for a transect crossing between grass and concrete additionally suggest that (d) SM changes can be sensed over a length scales of tens of meters or less (roughly an order of magnitude smaller than commonly used footprint distances), and (e) the additional moderator does not reduce the detected neutron count rate (and hence increase noise) as much as might be expected given the extent of the additional moderator. The detector with additional HDPE moderator was also used to conduct measurements on a stubble field over three weeks to test the rover system in measuring spatial and temporal SM variation.