Efficient characterization of wastewater stream quality is vital to ensure the safe discharge or reuse of treated wastewater (WW). There are numerous parameters employed to characterize water quality, some required by directives (e.g. biological oxygen demand (BOD), total nitrogen (TN), total phosphates (TP)), while others used for process controls (e.g. flow, temperature, pH). Well-accepted methods to assess these parameters have traditionally been laboratory-based, taking place either off-line or at-line, and presenting a significant delay between sampling and result. Alternative characterization methods can run in-line or on-line, generally being more cost-effective. Unfortunately, these methods are often not accepted when providing information to regulatory bodies. The current review aims to describe available laboratory-based approaches and compare them with innovative real-time (RT) solutions. Transitioning from laboratory-based to RT measurements means obtaining valuable process data, avoiding time delays, and the possibility to optimize the (WW) treatment management. A variety of sensor categories are examined to illustrate a general framework in which RT applications can replace longer conventional processes, with an eye toward potential drawbacks. A significant enhancement in the RT measurements can be achieved through the employment of advanced soft-sensing techniques and the Internet of Things (IoT), coupled with machine learning (ML) and artificial intelligence (AI).

Extracellular polymeric substances (EPS) are crucial in sewage sludge management, influencing key processes such as sedimentation, dewatering, and drying. Despite their importance, the lack of standardized methods for EPS extraction and analysis has led to inconsistent research findings, hindering a thorough understanding of EPS's role in sludge treatment. This review paper addresses this issue by critically comparing various EPS extraction and analysis methods, emphasizing the urgent need for standardization in the field. Standardized methodologies will enable researchers to compare studies more accurately and derive meaningful insights into EPS's role across different stages of sludge treatment, ultimately advancing EPS knowledge and application in sludge management. Additionally, this paper summarizes findings from numerous studies on EPS impact in sedimentation, dewatering, and drying, offering a holistic view of their significance in sludge management. Moreover, it explores the potential EPS applications, highlighting both the future directions and the challenges associated with their production.

Water shortages, exacerbated by climate change, are posing a major global challenge, particularly impacting the agricultural sector. A growing interest is raised towards reclaimed wastewater (RWW) as an alternative irrigation source, capable of exploiting also the nutrient content through the fertigation practice. However, a prioritization methodology for selecting the most appropriate wastewater treatment plants (WWTPs) for implementing direct RWW reuse is currently missing. Such prioritization would benefit water utilities, often managing several WWTPs, and policymakers in optimizing economic asset allocation. In this work, a prioritization framework is proposed to evaluate WWTPs' suitability for implementing direct RWW reuse considering both WWTP and surrounding territory characteristics. This procedure consists of four key steps. Firstly, a techno-economic model was developed, in which monthly mass balances on water and nutrients are solved by matching crop requirements, rainfall conditions, and effluent characteristics. Economic suitability was quantified considering economic benefits due to savings in freshwater resource, mineral fertilizers and avoided greenhouse gases emissions, but also losses in crop yield due to RWW salinity content. Secondly, a classification procedure was coded to select representative WWTPs among a set of WWTPs, based on their size, presence of nutrient removal processes, and type of crops in their surroundings. The techno-economic model was then applied to these selected WWTPs. Thirdly, input parameters' relevance in determining WWTP suitability for RWW reuse was ranked. Finally, scenario analyses were conducted to study the influence of rainfall patterns and nutrient treatment removal on the RWW reuse feasibility. The type of crops surrounding the WWTPs and RWW salinity content resulted to be crucial elements in determining WWTPs suitability for RWW reuse implementation. The proposed methodology proved to be an effective support tool for policymakers and water utilities to assess the techno-economic feasibility of direct RWW reuse, generalizing results to several combinations of WWTPs and crops.

Sewage sludge is the main by-product of wastewater treatment plants, requiring significant environmental and economic burdens for its management and disposal. Recently, solar drying processes, often performed through solar greenhouses, received interest due to their limited energy requirement and renewable energy exploitation. The dried sludge shows significant volume and mass reductions, reducing transportation and disposal costs. However, its physicochemical and microbiological characteristics must be properly assessed, especially if agricultural reuse is the final sludge destination, due to the possible accumulation of (micro)pollutants in the soil. This review depicts the state-of-the-art solar drying processes of sewage sludge, with a focus on the technological aspects and the sludge quality. The review discusses greenhouse-specific features, sludge composition (organic matter, pathogens, heavy metals and emerging pollutants) and drying conditions (seasonality, ventilation, sludge mixing and thickness, and drying speed). The economic aspects connected to sludge solar drying are presented. The limitations of this technology are discussed as well, including the limited applicability to wet sludge and the environmental issues connected to greenhouse structure degradation. A wider application of sludge solar drying is recommended to increase the sustainability of small and medium wastewater treatment plants, especially in areas with high amounts of solar radiation and dry weather conditions, while thermal drying still appears preferable for large plants. More agronomic studies must be conducted to assess the possible pollutant accumulation in crops, and alternative uses of the dried sludge (e.g., energy recovery through incineration, pyrolysis or gasification; utilization in construction materials) should be explored, also using life cycle assessment.