Landfill leachate (LL) represents a very complex effluent difficult to treat and to manage which usually requires a chemical pre-treatment. In this study, response surface methodology (RSM) was used to identify the optimum operating conditions of the Fenton process as a pre-treatment of LL in order to reduce the high organic content and simultaneously optimize the BOD₅:TN:TP ratio. The dosages of Fenton process reagents, namely Fe²⁺ and H₂O₂, were used as variables for the implementation of RSM. Chemical oxygen demand (COD), five-days biochemical oxygen demand (BOD₅), total nitrogen (TN), total phosphorus (TP) removals (and simultaneously BOD₅:TN:TP ratio), sludge-to-iron ratio (SIR) and organic removal-to-sludge ratio (ORSR) were selected as target responses. This approach considered the SIR and ORSR parameters which are a useful tool for assessing sludge formation during the process along with organic matter removal. The variables (H₂O₂ and Fe²⁺ concentrations) significantly affected the responses, as the role of oxidation mechanism is dominant with respect to coagulation one. The pH for the process was fixed to 2.8 while the treatment time was set to 2 h. The optimum operational conditions obtained by perturbation and 3D surface plot, were found to be 4262 mg/L and 5104 mg/L for Fe²⁺ and H₂O₂, respectively (H₂O₂/Fe²⁺ molar ratio = 2) with COD, BOD₅, TN and TP removals of 70%, 67%, 84% and 96% respectively, while SIR and ORSR final values were 1.15 L/mol and 33.79 g/L respectively, in accordance with models-predicted values. Moreover, the initial unbalanced BOD₅:TN:TP ratio (9:1:1) was significantly improved (100:6:1), making the effluent suitable for a subsequent biological treatment. The investigated approach allowed to optimize the removal of organic load and nutrients as well as to minimize the sludge formation in Fenton process, providing a useful tool for the operation and management of LL pre-treatment.

In this paper, we analysed the efflorescences present in the frescos of a monumental complex named S. Pietro a Corte situated in the historic centre of Salerno (Campania, Italy). The groundwater of the historic centre is fed by two important streams (the Rafastia and the Fusandola) that can be the sources of water penetration. The aims of this work are to (i) identify the stream that reaches the ancient frigidarium of S. Pietro a Corte and (ii) characterize the efflorescences on damaged frescos in terms of chemical nature and sources. In order to accomplish the first aim, the water of the Rafastia river (7 samples) and the water of the Fusandola river (7 samples) were analysed and compared with the water of a well of the Church (7 samples). The ionic chromatography measurements on the water samples allowed us to identify the Rafastia as the river that feeds the ancient frigidarium of S. Pietro a Corte. To investigate the nature and the origin of the efflorescences (our second aim), anionic chromatography analyses, X-ray diffraction measurements, and the isotopic determination of nitrogen were performed on the efflorescences (9 samples) and the salts recovered from the well (6 samples). Results of these analyses show that efflorescences are mainly made of potassium nitrate with a δ¹⁵N value of + 9.3 ± 0.2‰. Consequently, a plausible explanation for their formation could be the permeation of sewage water on the walls of the monumental complex.

Landfill leachate is a complex and highly polluted wastewater that poses significant environmental challenges worldwide. This study proposes an innovative approach to addressing this challenge by developing an integrated anaerobic–aerobic moving bed biofilm reactor (MBBR) and biochar adsorption method for the efficient removal of organic matter and nutrients from landfill leachate. The MBBR provides a suitable environment for the growth of microorganisms that can degrade organic matter and nutrients, while biochar adsorption removes any remaining pollutants that are not biodegradable. The performance of this integrated system was evaluated under different operating conditions, such as the hydraulic retention time and the organic loading rate, to optimize its efficiency and sustainability. The results showed that the integrated system achieved high removal efficiencies for chemical oxygen demand (COD), ammonium–nitrogen (NH₄-N), and total phosphorus (TP), with maximum removal rates of 98.5% (77% after the anaerobic–aerobic MBBR and 85.4% after biochar adsorption), 91.2% (87% after the anaerobic–aerobic MBBR and 95.9% after biochar adsorption), and 99.9% (92% after the anaerobic–aerobic MBBR and 91.7% after biochar adsorption), respectively. The proposed method offers a promising solution for the treatment of landfill leachate, which is a critical environmental issue worldwide. This study also highlights the importance of developing more effective and sustainable methods for treating landfill leachate, which can have significant impacts on public health and the environment.

The presence of arsenic (As) in drinking water is a major concern for human health. As(III) is the most toxic water-soluble form and it is hard to remove by separation methods, including adsorption, while As(V) is less toxic and easily removable by adsorption. In this work homogenous photo driven advanced oxidation processes (HP-AOPs), namely UVC/H₂O₂ and UVC/NaOCl, have been investigated in the oxidation of As(III) (initial concentration of 0.1 mg/L) to As(V) and commercial available adsorbents (γ-Al₂O₃, Bayoxide E33, MgAl-LDHs and ZnAl-LDHs) were tested for subsequent As(V) removal. UVC/H₂O₂ (99% of As removal, 19 mg/L of H₂O_2, 2 min of treatment time) and UVC/NaOCl (99% of As removal, 5.1 mg/L of NaOCl, 2 min of treatment time) were found to be more effective than H₂O₂ (2% of As removal in the same condition of UVC/H₂O₂) and NaOCl (6% of As removal in the same condition of UVC/NaOCl), respectively and the optimum operation conditions were identified by response surface methodology (RSM) in distilled water and subsequently confirmed in real drinking water (with differences of less than 1%). UVC/NaOCl was the most suitable process being a good compromise among oxidation efficiency, oxidant dose and treatment time. The best results in terms of subsequent removal of As(V) by adsorption were obtained using ZnAl-LDH (88% in both distilled and drinking water). Accordingly, UVC/NaOCl advanced oxidation coupled to ZnAl-LDH adsorption is the best combination for an effective removal of arsenic from drinking water.