In recent years, there has been a significant accumulation of waste in the environment, and it is expected that this accumulation may increase in the years to come. Waste disposal has massive effects on the environment and can cause serious environmental problems. Thus, the development of a waste treatment system is of major importance. Agro-industrial wastewater and waste residues are mainly rich in organic substances, lignocellulose, hemicellulose, lignin, and they have a relatively high amount of energy. As a result, an effective agro-waste treatment system has several benefits, including energy recovery and waste stabilization. To reduce the impact of the consumption of fossil energy sources on our planet, the exploitation of renewable sources has been relaunched. All over the world, efforts have been made to recover energy from agricultural waste, considering global energy security as the final goal. To attain this objective, several technologies and recovery methods have been developed in recent years. The microbial fuel cell (MFC) is one of them. This review describes the power generation using various types of agro-industrial wastewaters and agricultural residues utilizing MFC. It also highlights the techno-economics and lifecycle assessment of MFC, its commercialization, along with challenges.

The crop residue burning in India particularly North-western India is responsible for air pollution episodes and public health concerns; greenhouse gases emissions and radiation imbalance; and declining soil organic matter and soil productivity. The objectives of this paper are to estimate the crop residue burning and emissions from crop residue burning, to recommend interventions in crop residue management and to propose a crop residue management-bioeconomy model incorporating strategies to sustainably manage the crop residues through interventions that enable waste valorization, food and nutritional security, farmers’ livelihood and sustainable agricultural production system. A national inventory on crop residue burning including the pollutant species was prepared using the IPCC methodology. The crop types included for the estimation are cereals, pulses, oilseeds, sugarcane, cotton, jute and Mesta. The total amount of crop residues generated and burned for the year 2017–18 was estimated at 516 million tonnes and 116 million tonnes respectively. It is estimated that 116.3 Tg of crop residues burning released about 176.1 Tg of CO₂, 10 Tg of CO, 313.9 Gg of CH₄, 8.14 Gg of N₂O, 151.14 Gg of NH₃, 813.8 Gg of NMVOC, 453.4 Gg of PM_2.5, and 935.9 Gg of PM₁₀. The emission estimates can be a proxy to prepare the national level inventory of air pollutant species from crop residue burning. The crop residue management (CRM) demands a transition from the traditional zone of CRM to bioeconomy zone of CRM, wherein the interventions aim at the sustainability of agroecosystem. The proposed bioeconomy model has a four-pronged strategy that includes smart agriculture practices, waste bioeconomy involving aspirational principles of bioeconomy, capacity building of stakeholders’ and proactive government policy. Sustainable agricultural bioeconomy provides ample opportunities to reduce crop residue burning, increase farmers’ livelihood and decarbonize the agricultural production. India’s efforts and policies can provide lessons for other agricultural regions having similar environmental constraints.

Microbial electrocatalysis reckons on microbes as catalysts for reactions occurring at electrodes. Microbial fuel cells and microbial electrolysis cells are well-known in this context; both prefer the oxidation of organic and inorganic matter for producing electricity. Notably, the synthesis of high energy-density chemicals (fuels) or their precursors by microorganisms using bio-cathode to yield electrical energy is called Microbial Electrosynthesis (MES), giving an exceptionally appealing novel way for producing beneficial products from electricity and wastewater. This review accentuates the concept, importance and opportunities of MES, as an emerging discipline at the nexus of microbiology and electrochemistry. Production of organic compounds from MES is considered as an effective technique for the generation of various beneficial reduced end-products (like acetate and butyrate) as well as in reducing the load of CO₂ from the atmosphere to mitigate the harmful effect of greenhouse gases in global warming. Although MES is still an emerging technology, this method is not thoroughly known. The authors have focused on MES, as it is the next transformative, viable alternative technology to decrease the repercussions of surplus carbon dioxide in the environment along with conserving energy.

Biofuel consists of non-fossil fuel derived from the organic biomass of renewable resources, including plants, animals, microorganisms, and waste. Energy derived from biofuel is known as bioenergy. The reserve of fossil fuels is now limited and continuing to decrease, while at the same time demand for energy is increasing. In order to overcome this scarcity, it is vital for human beings to transfer their dependency on fossil fuels to alternative types of fuel, including biofuels, which are effective methods of fulfilling present and future demands. The current review therefore focusses on second-generation lignocellulosic biofuels obtained from non-edible plant biomass (i.e., cellulose, lignin, hemi-celluloses, non-food material) in a more sustainable manner. The conversion of lignocellulosic feedstock is an important step during biofuel production. It is, however, important to note that, as a result of various technical restrictions, biofuel production is not presently cost efficient, thus leading to the need for improvement in the methods employed. There remain a number of challenges for the process of biofuel production, including cost effectiveness and the limitations of various technologies employed. This leads to a vital need for ongoing and enhanced research and development, to ensure market level availability of lignocellulosic biofuel.

Nowadays, the world is experiencing an energy crisis due to extensive globalization and industrialization. Most of the sources of renewable energy are getting depleted, and thus, there is an urge to locate alternative routes to produce energy efficiently. Microbial fuel cell (MFC) is a favorable technology that utilizes electroactive microorganisms acting as a biocatalyst at the anode compartment converting organic matter present in sewage water for bioelectricity production and simultaneously treating wastewater. However, there are certain limitations with a typical stand-alone MFC for efficient energy recovery and its practical implementation, including low power output and high cost associated with treatment. There are various modifications carried out on MFC for eliminating the limitations of a stand-alone MFC. Examples of such modification include integration of microbial fuel cell with capacitive deionization technology, forward osmosis technology, anaerobic digester, and constructed wetland technology. This review describes various integrated MFC systems along with their potential application on an industrial scale for wastewater treatment, biofuel generation, and energy production. As a result, such integration of MFCs with existing systems is urgently needed to address the cost, fouling, durability, and sustainability-related issues of MFCs while also improving the grade of treatment received by effluent.