Land‐based climate mitigation measures have gained significant attention and importance in public and private sector climate policies. Building on previous studies, we refine and update the mitigation potentials for 20 land‐based measures in >200 countries and five regions, comparing “bottom‐up” sectoral estimates with integrated assessment models (IAMs). We also assess implementation feasibility at the country level. Cost‐effective (available up to $100/tCO₂eq) land‐based mitigation is 8–13.8 GtCO₂eq yr⁻¹between 2020 and 2050, with the bottom end of this range representing the IAM median and the upper end representing the sectoral estimate. The cost‐effective sectoral estimate is about 40% of available technical potential and is in line with achieving a 1.5°C pathway in 2050. Compared to technical potentials, cost‐effective estimates represent a more realistic and actionable target for policy. The cost‐effective potential is approximately 50% from forests and other ecosystems, 35% from agriculture, and 15% from demand‐side measures. The potential varies sixfold across the five regions assessed (0.75–4.8 GtCO2eq yr⁻¹) and the top 15 countries account for about 60% of the global potential. Protection of forests and other ecosystems and demand‐side measures present particularly high mitigation efficiency, high provision of co‐benefits, and relatively lower costs. The feasibility assessment suggests that governance, economic investment, and socio‐cultural conditions influence the likelihood that land‐based mitigation potentials are realized. A substantial portion of potential (80%) is in developing countries and LDCs, where feasibility barriers are of greatest concern. Assisting countries to overcome barriers may result in significant quantities of near‐term, low‐cost mitigation while locally achieving important climate adaptation and development benefits. Opportunities among countries vary widely depending on types of land‐based measures available, their potential co‐benefits and risks, and their feasibility. Enhanced investments and country‐specific plans that accommodate this complexity are urgently needed to realize the large global potential from improved land stewardship.

Stabilizing the global climate within safe bounds will require greenhouse gas (GHG) emissions to reach net zero within a few decades. Achieving this is expected to require removal of CO₂ from the atmosphere to offset some hard-to-eliminate emissions. There is, therefore, a clear need for GHG accounting protocols that quantify the mitigation impact of CO₂ removal practices, such as biochar sequestration, that have the potential to be deployed at scale. Here, we have developed a GHG accounting methodology for biochar application to mineral soils using simple parameterizations and readily accessible activity data that can be applied at a range of scales including farm, supply chain, national, or global. The method is grounded in a comprehensive analysis of current empirical data, making it a robust method that can be used for many applications including national inventories and voluntary and compliance carbon markets, among others. We show that the carbon content of biochar varies with feedstock and production conditions from as low as 7% (gasification of biosolids) to 79% (pyrolysis of wood at above 600 °C). Of this initial carbon, 63–82% will remain unmineralized in soil after 100 years at the global mean annual cropland-temperature of 14.9 °C. With this method, researchers and managers can address the long-term sequestration of C through biochar that is blended with soils through assessments such as GHG inventories and life cycle analyses.

Soil organic carbon (SOC) models currently in widespread use omit known microbial processes, and assume the existence of a SOC pool whose intrinsic properties confer persistence for centuries to millennia, despite evidence from priming and aggregate turnover that cast doubt on the existence of SOC with profound intrinsic stability. Here we show that by including microbial interactions in a SOC model, persistence can be explained as a feedback between substrate availability, mineral protection and microbial population size, without invoking an unproven pool that is intrinsically stable for centuries. The microbial SOC model based on this concept reproduces long-term data (r² = 0.92; n = 90), global SOC distribution (rmse = 4.7 +/− 0.6 kg C m⁻²), and total global SOC in the top 0.3 m (822 Pg C) accurately. SOC dynamics based on a microbial feedback without stable pools are thus consistent with global SOC distribution. This has important implications for carbon management, suggesting that relatively fast cycling, rather than recalcitrant, SOC must form the primary target of efforts to build SOC stocks.

Global warming necessitates urgent action to reduce carbon dioxide (CO₂) emissions and remove CO₂ from the atmosphere. Biochar, a type of carbonized biomass which can be produced from crop residues (CRs), offers a promising solution for carbon dioxide removal (CDR) when it is used to sequester photosynthetically fixed carbon that would otherwise have been returned to atmospheric CO₂ through respiration or combustion. However, high‐resolution spatially explicit maps of CR resources and their capacity for climate change mitigation through biochar production are currently lacking, with previous global studies relying on coarse (mostly country scale) aggregated statistics. By developing a comprehensive high spatial resolution global dataset of CR production, we show that, globally, CRs generate around 2.4 Pg C annually. If 100% of these residues were utilized, the maximum theoretical technical potential for biochar production from CRs amounts to 1.0 Pg C year⁻¹ (3.7 Pg CO₂e year⁻¹). The permanence of biochar differs across regions, with the fraction of initial carbon that remains after 100 years ranging from 60% in warm climates to nearly 100% in cryosols. Assuming that biochar is sequestered in soils close to point of production, approximately 0.72 Pg C year⁻¹ (2.6 Pg CO₂e year⁻¹) of the technical potential would remain sequestered after 100 years. However, when considering limitations on sustainable residue harvesting and competing livestock usage, the global biochar production potential decreases to 0.51 Pg C year⁻¹ (1.9 Pg CO₂e year⁻¹), with 0.36 Pg C year⁻¹ (1.3 Pg CO₂e year⁻¹) remaining sequestered after a century. Twelve countries have the technical potential to sequester over one fifth of their current emissions as biochar from CRs, with Bhutan (68%) and India (53%) having the largest ratios. The high‐resolution maps of CR production and biochar sequestration potential provided here will provide valuable insights and support decision‐making related to biochar production and investment in biochar production capacity.