An efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc) 2 or Cu(OAc) 2 /NHPI-catalyzed oxidation of hydride siloxanes has been proposed.
This research presents a scalable method for chemical transformation of Si-containing derivatives of benzoic acid to a wide range of corresponding esters, thioesters, amides,etc.Some of them form HOF-like structures in the crystalline state.
8 December 2025 in Macromolecular Rapid Communications