The development of metal halide perovskite/perovskite heterostructures is hindered by rapid interfacial halide diffusion leading to mixed alloys rather than sharp interfaces. To circumvent this outcome, we developed an ion-blocking layer consisting of single-layer graphene (SLG) deposited between the metal halide perovskite layers and demonstrated that it effectively blocks anion diffusion in a CsPbBr₃/SLG/CsPbI₃ heterostructure. Spatially resolved elemental analysis and spectroscopic measurements demonstrate the halides do not diffuse across the interface, whereas control samples without the SLG show rapid homogenization of the halides and loss of the sharp interface. Ultraviolet photoelectron spectroscopy, DFT calculations, and transient absorbance spectroscopy indicate the SLG has little electronic impact on the individual semiconductors. In the CsPbBr₃/SLG/CsPbI₃, we find a type I band alignment that supports transfer of photogenerated carriers across the heterointerface. Light-emitting diodes (LEDs) show electroluminescence from both the CsPbBr₃ and CsPbI₃ layers with no evidence of ion diffusion during operation. Our approach provides opportunities to design novel all-perovskite heterostructures to facilitate the control of charge and light in optoelectronic applications.

Combining the synthetic tunability of molecular compounds with the optical selection rules of transition metal dichalcogenides (TMDCs) that derive from spin-valley coupling could provide interesting opportunities for the readout of quantum information. However, little is known about the electronic and spin interactions at such interfaces and the influence on spin-valley relaxation. In this work, vanadyl phthalocyanine (VOPc) molecular layers are thermally evaporated on WSe2 to explore the effect of molecular layer thickness on excited-state spin-valley polarization. The thinnest molecular layer supports an interfacial state which destroys the spin-valley polarization almost instantaneously, whereas a thicker molecular layer results in longer-lived spin-valley polarization than the WSe2 monolayer alone. The mechanism appears to involve a tightly bound species at the molecule/TMDC interface that strengthens exchange interactions and is largely avoided in thicker VOPc layers that isolate electrons from WSe2 holes.

This chapter, which is based on the experiences of many voluntary agencies working with refugees in Europe, as well as on my own personal experiences over the past 14 years of directing education and training programmes for refugees in the UK, focuses primarily on refugee employment in Europe. I examine some recent work which could be useful in designing future settlement programmes and make a case for giving priority to research into refugee employment I show what moves are being made by many of the EEC governments to resist the flow of asylum-seekers into Europe. While some governments characterise asylum-seekers as economic migrants, voluntary agencies believe that economic considerations in Europe, including high levels of domestic unemployment, dominate asylum policies. <!----> <!----> <!----> <!---->