Innovative goods authentication strategies are of fundamental importance considering the increasing counterfeiting levels. Such a task has been effectively addressed with the so-called physical unclonable functions (PUFs), being physical properties of a system that characterize it univocally. PUFs are commonly implemented by exploiting naturally occurring non-idealities in clean-room fabrication processes. The broad availability of classic paradigm PUFs, however, makes them vulnerable. Here, we propose a hybrid plasmonic/photonic multilayered structure working as a three-level strong PUF. Our approach leverages on the combination of a functional nanostructured surface, a resonant response, and a unique chromatic signature all together in one single device. The structure consists of a resonant cavity, where the top mirror is replaced with a layer of plasmonic Ag nanoislands. The naturally random spatial distribution of clusters and nanoparticles formed by this deposition technique constitutes the manufacturer-resistant nanoscale morphological fingerprint of the proposed PUF. The presence of Ag nanoislands allows us to tailor the interplay between the photonic and plasmonic modes to achieve two additional security levels. The first one is constituted by the chromatic response and broad iridescence of our structures, while the second by their rich spectral response, accessible even through a common smartphone light-emitting diode. We demonstrate that the proposed architectures could also be used as an irreversible and quantitative temperature exposure label. The proposed PUFs are inexpensive, chip-to-wafer-size scalable, and can be deposited over a variety of substrates. They also hold a great promise as an encryption framework envisioning morpho-cryptography applications.

Effective optical elements with tailored properties often rely on the capability to tune the material's structure at the nanoscale. Thanks to their self‐organized 1D helical arrangement, cholesteric liquid crystals represent a beautiful example of optical materials whose properties are governed by their supramolecular structure. According to the Bragg's law, selective reflection of circular polarized light occurs for wavelengths within the photonic band gap, which, beside the refractive indices, depends on the helix pitch. Here, polymeric microstructures with tailored PBG are demonstrated by two‐photon polymerization direct laser writing in cholesteric reactive mesogens. Turning a renowned disadvantage into an opportunity, the shrinkage upon the layer‐by‐layer photopolymerization is exploited to control the effective helix pitch. Starting from a PBG of the precursor in the near infra‐red, micro‐cylinders which exhibit Bragg selective reflection at lower wavelength ranges, down to the opposite end of the visible spectrum, are fabricated in a single‐step process by tuning the laser exposure parameters. As a proof‐of‐concept, a 4D quick response (QR) micro‐tag, which adds the polarization‐selective structural color and the height of the blocks to the usual 2D black/white QR codes, is demonstrated as a novel paradigm of optical anti‐counterfeiting microdevice.

This work investigates the heat delivered by a mono-layer 1D grating of gold nanoparticles (GNPs) created by photo-reduction through two-photon direct laser writing (2P-DLW) in a poly-vinyl alcohol (PVA) matrix doped with HAuCl₄, under resonant laser radiation. We drop cast a film of a PVA + HAuCl₄ mixture onto a glass substrate, in which we create gratings of 1 mm² made by stripes of GNPs characterized by high polydispersivity. We demonstrate that, by controlling the pitch of the GNP stripes, we obtain different values of the photo-induced temperature variations. In the framework of thermo-plasmonics, the experimental investigation of the heat generation from a monolayer of gold nanoparticles represents a key element as a starting point to design thermo-smart platforms for sensing, solar energy harvesting and thermo-catalysis.

The influence of ultra-short laser modification on the surface morphology and possible chemical alteration of poly-lactic acid (PLA) matrix in respect to the optimization of cellular and antibacterial behavior were investigated in this study. Scanning electron microscopy (SEM) morphological examination of the processed PLA surface showed the formation of diverse hierarchical surface microstructures, generated by irradiation with a range of laser fluences (F) and scanning velocities (V) values. By controlling the laser parameters, diverse surface roughness can be achieved, thus influencing cellular dynamics. This surface feedback can be applied to finely tune and control diverse biomaterial surface properties like wettability, reflectivity, and biomimetics. The triggering of thermal effects, leading to the ejection of material with subsequent solidification and formation of raised rims and 3D-like hollow structures along the processed zones, demonstrated a direct correlation to the wettability of the PLA. A transition from superhydrophobic (θ > 150°) to super hydrophilic (θ < 20°) surfaces can be achieved by the creation of grooves with V = 0.6 mm/s, F = 1.7 J/cm². The achieved hierarchical architecture affected morphology and thickness of the processed samples which were linked to the nature of ultra-short laser-material interaction effects, namely the precipitation of temperature distribution during material processing can be strongly minimized with ultrashort pulses leading to non-thermal and spatially localized effects that can facilitate volume ablation without collateral thermal damage The obtained modification zones were analyzed employing Fourier transform infrared (FTIR), X-ray photoelectron spectroscopy (XPS), Energy dispersive X-ray analysis (EDX), and optical profilometer. The modification of the PLA surface resulted in an increased roughness value for treatment with lower velocities (V = 0.6 mm/s). Thus, the substrate gains a 3D-like architecture and forms a natural matrix by microprocessing with V = 0.6 mm/s, F = 1.7 J/cm², and V = 3.8 mm/s, F = 0.8 J/cm². The tests performed with Mesenchymal stem cells (MSCs) demonstrated that the ultra-short laser surface modification altered the cell orientation and promoted cell growth. The topographical design was tested also for the effectiveness of bacterial attachment concerning chosen parameters for the creation of an array with defined geometrical patterns.