In this paper the properties of clay bricks with 5 wt%, 10 wt%, and 20 wt% sewage sludge ash (SSA) were studied and compared with the properties of control bricks made of 100% clay. Sewage sludge (SS) was collected at two wastewater treatment plants (WWTPs) in Croatia—WWTP Zagreb and WWTP Karlovac—and incinerated at a temperature of 900 °C The bricks were produced on a laboratory scale. A total of seven types of bricks were produced—control bricks and six types of bricks as combinations of different wt% of SSA generated from SS that was collected at two different WWTPs. The physical and mechanical properties of produced bricks were tested. Compressive strengths of bricks with 5 wt% SSA (54.0–54.5 N/mm²) and 10 wt% SSA (50.2–51.0 N/mm²) were higher compared to the control bricks (50.4 N/mm²), while bricks with 20 wt% SSA (37.0–43.9) N/mm²) had noticeably lower compressive strenght. The coefficient of saturation was lower for bricks with SSA compared to control bricks. The initial absorption values were more pronounced for SSA fractions of 20 wt%.

The potential for using sewage sludge ash (SSA) as a supplementary cementitious material (SCM) has been investigated. Controlled combustion of sewage sludge collected in Croatia from two wastewater treatment plants produced SSA with different characteristics. These were used to substitute for cement in mortar samples. The chemical composition and physical properties of SSA depend on wastewater composition, the sludge treatment process and the combustion temperature. These factors influence the suitability of SSA to be used as a SCM. For three different combustion temperatures (800, 900 and 1000 °C), it was concluded that properties of fresh mortar were not affected while in the hardened state, the most favorable combustion temperature is 900 °C regarding mechanical properties. Regardless of combustion temperature, for all types of SSA used in mortars as cement replacement (up to 30%), the average decrease in both compressive and flexural strength values was less than 8% for every 10% of added SSA. The results presented indicate that using up to 20% replacement of cement by SSA produces mortars that meet the specific technical requirements analyzed in this work.

The growing amounts of sewage sludge (SS) and water pollution caused by heavy metals are major environmental concerns. This study addresses both issues by investigating the potential of biochar derived from SS gasification at an experimental plant as an effective adsorbent for the removal of selected heavy metals, cadmium, chromium, copper, and lead, from synthetic wastewater. A Box–Behnken design was used to determine the influence of the biochar mass, initial heavy metal concentration, pH, and time on the heavy metal removal. For the statistical analysis, 104 experiments were performed. The pristine SS biochar demonstrated an adsorption capacity reaching up to 46.64 mg/g for Cd, 43.89 mg/g for Cr, 42.42 mg/g for Cu, and 72.66 mg/g for Pb from single-component synthetic solutions in acidic-to-neutral conditions, with an over 99% removal efficiency for all four heavy metals under optimal conditions. The removal of all the tested metals followed pseudo-second-order kinetics, with Cd fitting the Langmuir model and Pb, Cr, and Cu fitting the Freundlich model. This paper also provides suggestions for further research focused on the multiple uses of biochar as an adsorbent and later as a substitute material in the construction industry, aiming to achieve an integrated approach and maximizing the overall sustainability of wastewater treatment and waste management by utilizing waste as a resource.

Developing beneficial applications for sewage sludge is a key challenge in many countries, given the amount of sludge generated and the disposal or recycling options currently available. Sewage sludge from the wastewater treatment plant at Koprivnica in Croatia has been treated using MID-MIX® technology that involves the addition of Ca(OH)2 and CaO to dewatered sludge. This produces a low-density non-hazardous white-grey powder. The treated sewage sludge has been heated to 800, 900 and 1000 °C to form MID-MIX® treated sewage sludge ash with reduced organic content. MID-MIX® treated sewage sludge and ash have been used to replace 10 and 20% of cement in mortar and concrete samples. The addition of MID-MIX® treated sewage sludge causes a significant increase in void content which reduces the mechanical properties and durability of mortar and concrete samples. However, replacement of cement by MID-MIX® ash did not significantly affect the strength, water penetration or gas permeability compared to control samples. Leaching tests on MID-MIX® powder, MID-MIX® ash and mortar samples produced low levels of heavy metal release. The research shows that thermally processed MID-MIX® treated sewage sludge produces an ash product that has potential to be beneficially used in cementitious materials for selected applications.

Final disposal of sewage sludge is important not only in terms of satisfying the regulations, but the aspect of choosing the optimal wastewater treatment technology, including the sludge treatment. In most EU countries, significant amounts of stabilized and dewatered sludge are incinerated, and sewage sludge ash (SSA) is generated as a by product. At the same time, lime is one of the commonly used additives in the sewage sludge treatment primarily to stabilize the sludge. In doing so, the question arose how desirable is such addition of lime if the sludge is subsequently incinerated, and the generated ash is further used in the production of cementitious materials. A series of mortars were prepared where 10–20% of the cement fraction was replaced by SSA. Since all three types of analyzed SSA (without lime, with lime added during sludge stabilization and with extra lime added during sludge incineration) yielded nearly same results, it can be concluded that if sludge incineration is accepted solution, lime addition during sludge treatment is unnecessary even from the standpoint of preserving the pozzolanic properties of the resulting SSA. Results of the research carried out on cement mortars point to the great possibilities of using SSA in concrete industry.