Microplastic pollution is occurring in most ecosystem, yet their presence in high altitude clouds and their influence on cloud formation and climate change are poorly known. Here we analyzed microplastics in cloud water sampled at the summits of Japan mountains at 1300–3776 m altitude by attenuated total reflection imaging and micro-Fourier transform infrared spectroscopy. We observed nine microplastics including polyethylene, polypropylene, polyethylene terephthalate, polymethyl methacrylate, polyamide 6, polycarbonate, ethylene–propylene copolymer or polyethylene–polypropylene alloy, polyurethane, and epoxy resin. Microplastic were fragmented, with mean concentrations ranging from 6.7 to 13.9 pieces per liter, and with Feret diameters ranging from 7.1 to 94.6 μm. Microplastics bearing hydrophilic groups such as carbonyl and/or hydroxyl groups were abundant, suggesting that they might have acted as condensation nuclei of cloud ice and water. Overall, our finding suggest that high-altitude microplastics cloud influence cloud formation and, in turn, might modify the climate.

Forest decline, which occurs in mountainous regions in many countries, may result from the effects of acid fog, ozone, or deposition of other pollutants. We observed wet deposition of air pollutants at different altitudes on Mt. Oyama, situated southwest of Tokyo, for 1994 until 2019. During this period, the domestic atmospheric environment was improved in Japan. The average concentration of air pollutants around all the sampling sites on Mt. Oyama decreased by 63.01%, 32.08%, 8.80%, and 39.73% for NH₃, HCl, HNO₃, and SO₂, respectively. The volume weighted mean (VWM) pH values showed an increasing trend for bulk deposition (+0.70% y^-1), fog water (+2.58% y^-1), and throughfall (+2.60% y^-1). Stemflow also increased (cedar, +1.17% y^-1; fir, +0.82% y^-1), although it included organic acids dissolved from the stem and it primarily had a low VWM pH value. The overall pH value of the fog water increased at the site, although acidic fog was still observed. Comparing fog water between winter and summer, a significant increase in pH occurred in summer, whereas no change occurred in winter. In summer, the sources of pollutants at Mt. Oyama are mainly from mainland Japan, and the frequency of low-pH acidic fog decreased annually. In winter, Mt. Oyama was affected by transboundary pollution, and acid fog occasionally occurred. Improvements in the domestic atmospheric environment and control of transboundary pollution will provide better conditions for mountain ecology that are free from acidic pollutants.

Airborne microplastics (AMPs) are increasingly recognized as an emerging air pollutant. However, observational data remains scarce in Southeast Asia. This study provides the first observations of AMPs in Phnom Penh, Cambodia, using µFTIR-ATR imaging. Number concentration, morphology, polymer composition, aerodynamic size distribution, Feret diameter, and surface aging characteristics were investigated together with meteorological parameters, gaseous pollutants, water-soluble ionic tracers, and HYSPLIT backward trajectories for source attribution. AMPs were dominated by polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET), with 52% classified as fragments and 82% having Feret diameters smaller than 30 µm. AMP concentrations ranged from 0.55 to 1.27 MP m^-3 in TSP (mean: 0.97 ± 0.30 MP m^-3, n = 134) and from 0.23 to 0.49 MP m^-3 in PM2.5 (mean: 0.33 ± 0.10 MP m^-3, n = 46). Carbonyl and hydroxyl indexes indicate that PE and PP were relatively fresh and in low-to-moderate photo-oxidative aging states. Correlation analysis further indicates that PE and PP were mainly associated with local waste fragmentation, whereas PET was linked to precipitation scavenging and resuspension processes. In addition, HYSPLIT backward trajectories suggest regional transport of AMPs by the Southwest Monsoon from marine source regions, including the Indian Ocean, Arabian Sea, and Andaman Sea. These findings provide the first baseline dataset for AMP pollution in Phnom Penh, Cambodia and highlight the combined importance of local emissions and regional atmospheric transport in Southeast Asia.

Airborne micro- and nanoplastic (AMNP) pollution is ubiquitous in the environment, and its abundance and persistence in the atmosphere have raised global concern. Transport and the changing interface of micro- and nanoplastics play an essential role in linking their sources and sinks within the planetary system. In this study, an airborne micro- and nanoplastic measurement campaign was conducted using our newly developed active samplers to investigate the unique sources and interface changes of AMNPs in Hong Kong. These include tyre wear from take-off and landing operations at Hong Kong International Airport (HKIA). Two distinct sampling sites from Tung Chung for airport-related AMNPs were selected. Seasonal measurements were arranged to capture both seasonal and event-based variations in AMNP concentrations. All collected samples underwent Micro-FTIR and PY-GC-MS analyses to determine the physical properties (e.g., size, shape, morphology) and chemical composition of AMNPs, and were subsequently applied to source and receptor analyses. To the best of our knowledge, this is the first survey of atmospheric AMNPs in Hong Kong, providing essential information on background AMNP levels.

Airborne microplastics (AMPs) are increasingly recognized as an emerging air pollutant. However, observational data remain scarce in Southeast Asia. This study provides the first observations of AMPs in Phnom Penh, Cambodia, using µFTIR-ATR imaging. Number concentration, morphology, polymer composition, aerodynamic size distribution, Feret diameter, and surface aging characteristics were investigated together with meteorological parameters, gaseous pollutants, water-soluble ionic tracers, and HYSPLIT backward trajectories to examine possible source attribution. AMPs were dominated by polyethylene (PE), polypropylene (PP), and polyethylene terephthalate (PET), with 52% classified as fragments and 82% having Feret diameter smaller than 30 µm. Across four independent 72-h sampling periods (n = 4), AMP concentrations ranged from 0.55 to 1.27 MP m⁻³ in TSP, with a mean ± standard deviation of 0.97 ± 0.30 MP m⁻³, and from 0.23 to 0.49 MP m⁻³ in the PM_2.5 fraction, with a mean ± standard deviation of 0.33 ± 0.10 MP m⁻³. In total, 134 particles were identified in TSP, of which 46 were detected in the PM_2.5 fraction. Carbonyl and hydroxyl indices indicated that PE and PP were relatively fresh and in low-to-moderate surface aging states. Pearson correlations suggested that the abundances of individual polymers were varied differently in relation to local environmental and precipitation-related variables; however, the limited number of sampling periods precludes source or process attribution. In addition, HYSPLIT backward trajectories showed that some air masses arriving in Phnom Penh had passed over marine regions under southwest monsoon flow. These findings provide the first baseline dataset for AMP pollution in Phnom Penh, Cambodia, and highlight the combined importance of local emissions and regional atmospheric transport in Southeast Asia.