Anomalous solid-like liquids at the solid–liquid interface have been recently reported. The mechanistic factors contributing to these anomalous liquids and whether they can stably exist at high vacuum are interesting, yet unexplored, questions. In this paper, thin slices of silica tubes soaked in hexadecane were observed under a transmission electron microscope at room temperature. The H-spectrum of hexadecane in the microtubules was measured by nuclear magnetic resonance. On the interior surface of these silica tubes, 0.2–30 μm in inside diameter (ID), a layer (12–400 nm) of a type of non-volatile hexadecane was found with thickness inversely correlated with the tube ID. A sample of this anomalous hexadecane in microtubules 0.4 μm in ID was found to be formable by an ion beam. Compared with the nuclear magnetic resonance H-spectroscopy of conventional hexadecane, the characteristic peaks of this abnormal hexadecane were shifted to the high field with a broader characteristic peak, nuclear magnetic resonance hydrogen spectroscopy spectral features typical of that of solids. The surface density of these abnormal hexadecanes was found to be positively correlated with the silanol groups found on the interior silica microtubular surface. This positive correlation indicates that the high-density aggregation of silanol is an essential factor for forming the abnormal hexadecane reported in this paper.

Knowledge of the migration characteristics of polymer systems in pore throats is essential for the effective application of polymers as a profile-control oil-displacement agent for enhanced oil recovery. In this study, the effect of concentration on the viscosity and hydrodynamic radius of polymer systems was investigated using a rheometer and a dynamic light scattering instrument. Furthermore, pore-throat models, homogeneous cores, and multi-measuring-point sand-packed models were constructed to investigate pore-scale migration patterns and the effect of the throat–polymer ratio (defined as the ratio of throat size to polymer hydrodynamic radius) on the migration properties of polymers in porous media. The results showed that the transport of polymer systems in porous media is primarily related to the throat–polymer ratio. When this ratio is sufficiently small (i.e., no more than 18.94), the migration pattern of the polymer systems in the pore-throat model does not exhibit the characteristics of polymer solution flow, but rather, of discontinuous-dispersion retention, plugging-breakthrough migration, and stable-plugging retention. Upon increasing the injection rate, the polymer systems also exhibit the migration characteristics of discontinuous dispersion at a larger throat–polymer ratio. Moreover, polymer system migration resistance and improved sweep efficiency in porous media are influenced by not only the viscosity of polymer systems, but also the throat–polymer ratio. The smaller the throat–polymer ratio, the stronger the retention and plugging ability of the polymer systems. The outcomes of this study are significant for the design of polymer flooding operations in oilfields.