Developing highly efficient and durable hydrogen evolution reaction (HER) electrocatalysts is crucial for addressing the energy and environmental challenges. Among the 2D-layered chalcogenides, MoSe₂ possesses superior features for HER catalysis. The van der Waals attractions and high surface energy, however, stack the MoSe₂ layers, resulting in a loss of edge active catalytic sites. In addition, MoSe₂ suffers from low intrinsic conductivity and weak electrical contact with active sites. To overcome the issues, this work presents a novel approach, wherein the in situ incorporated diethylene glycol solvent into the interlayers of MoSe₂ during synthesis when treated thermally in an inert atmosphere at 600 °C transformed into graphene (Gr). This widened the interlayer spacing of MoSe₂, thereby exposing more HER active edge sites with high conductivity offered by the incorporated Gr. The resulting MoSe₂-Gr composite exhibited a significantly enhanced HER catalytic activity compared to the pristine MoSe₂ in an acidic medium and demonstrated a superior HER catalytic activity compared to the state-of-the-art Pt/C catalyst, particularly at a high current density beyond ca. 55 mA cm⁻². Additionally, the MoSe₂-Gr catalyst demonstrated long-term electrochemical stability during HER. This work, thus, presents a facile and novel approach for obtaining an efficient MoSe₂ electrocatalyst applicable in green hydrogen production.

A carbonized interlayer effectively helps to improve the electrochemical performance of lithium–sulfur (Li–S) batteries. In this study, a simple and inexpensive carbon intermediate layer was fabricated using a traditional Korean paper called “hanji”. This carbon interlayer has a fibrous porous structure, with a specific surface area of 91.82 m² g⁻¹ and a BJH adsorption average pore diameter of 26.63 nm. The prepared carbon interlayer was utilized as an intermediary layer in Li–S batteries to decrease the charge-transfer resistance and capture dissolved lithium polysulfides. The porous fiber-shaped carbon interlayer suppressed the migration of polysulfides produced during the electrochemical process. The carbon interlayer facilitates the adsorption of soluble lithium polysulfides, allowing for their re-utilization in subsequent cycles. Additionally, the carbon interlayer significantly reduces the polarization of the cell. This simple strategy results in a significant improvement in cycle performance. Consequently, the discharge capacity at 0.5 C after 150 cycles was confirmed to have improved by more than twofold, reaching 230 mAh g⁻¹ for cells without the interlayer and 583 mAh g⁻¹ for cells with the interlayer. This study demonstrates a simple method for improving the capacity of Li–S batteries by integrating a functional carbon interlayer.