Platinum (Pt) is one of the most studied materials in catalysis today and considered for a wide range of applications: chemical synthesis, energy conversion, air treatment, water purification, sensing, medicine etc. As a limited and non-renewable resource, optimized used of Pt is key. Nanomaterial design offers multiple opportunities to make the most of Pt resources down to the atomic scale. In particular, colloidal syntheses of Pt nanoparticles are well documented and simple to implement, which accounts for the large interest in research and development. For further breakthroughs in the design of Pt nanomaterials, a deeper understanding of the intricate synthesis-structures-properties relations of Pt nanoparticles must be obtained. Understanding how Pt nanoparticles form from molecular precursors is both a challenging and rewarding area of investigation. It is directly relevant to develop improved Pt nanomaterials but is also a source of inspiration to design other precious metal nanostructures. Here, we review the current understanding of Pt nanoparticle formation. This review is aimed at readers with interest in Pt nanoparticles in general and their colloidal syntheses in particular. Readers with a strongest interest on the study of nanomaterial formation will find here the case study of Pt. The preferred model systems and characterization techniques used to perform the study of Pt nanoparticle syntheses are discussed. In light of recent achievements, further direction and areas of research are proposed.

In this work, we present a facile and straightforward approach to synthesize, activate and benchmark small, i.e. 1.6 nm in diameter, Ir nanoparticles (NP) as oxygen evolution reaction (OER) catalysts. It is shown that the Ir NP, although oxidized after synthesis and drying, can be electrochemically reduced allowing determination of the electrochemically active surface area by CO stripping. Subsequently, an activation protocol is applied forming catalytically active Ir-oxide NP. This oxide formation is shown to be largely irreversible. It is then demonstrated that the activated Ir NP synthesized via our recently introduced colloidal method exhibit extremely high OER activities when normalized to their Ir mass. These high OER activities are related to superior dispersion as compared to state-of-the-art OER catalysts reported in the literature.