João Rafael Silva

Mr. João Rafael Silva

Chemical and biological engineering, Coimbra Institute of Engineering, Polytechnic Institute of Coimbra, Coimbra, Portugal
orcid

Research Focus & Metrics

Academic Career Length

7Years (2020-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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25 February 2022 in Sustainability
Verified
Journal Article
Open access
PDF file
RBRui Boavida-Dias
Rui Boavida-Dias
JSJoão Rafael Silva
João Rafael Silva
Andreia Duarte SantosAndreia Duarte Santos
Andreia Duarte Santos
Rui MartinsRui Martins
Rui Martins
LCLuis M. Castro
Luis M. Castro
Rosa M. Quinta-FerreiraRosa M. Quinta-Ferreira
Rosa M. Quinta-Ferreira
Dairy industry wastewater is rich in organic content, presenting a high biodegradability, and therefore biological treatments are widely employed. This study aimed to evaluate biosolids production in three systems: activated sludge (AS), movingbed biofilm reactor (MBBR), and sequencingbatch movingbed biofilm reactor (SBMBBR). Simulated dairy wastewater was used at different organic load rates (OLRs): 1.22, 2.87, and 5.44 gCOD L−1d−1. Besides biosolids production, COD, total carbon (TC), and total nitrogen (TN) removal efficiency was evaluated. Biosolids production was measured in the mixed liquor, carrier-adhered biomass, treated wastewater, and surplus sludge. The operational conditions were kept similar for the three systems, with a carrier filling ratio of 50% for MBBR and SBMBBR. The SBMBBR proved to have better performance in the removal efficiencies of COD, TC, and TN for all OLRs studied. The MBBR presented a similar COD and TC removal efficiency as the SBBR for the two highest OLRs (2.87 and 5.44 gCOD L−1d−1). Concerning biosolids production, the MBBR system produced less biomass and delivered the lowest amount of adhered biomass inside the carriers. The AS treatment generated the highest amount of sludge and offered the worst treatment capability for all OLRs evaluated.

19 April 2022 in Journal of Environmental Chemical Engineering
Verified
Journal Article
Open access
JSJoão Rafael Silva
João Rafael Silva
FCFrancisco Carvalho
Francisco Carvalho
CVCarolina Vicente
Carolina Vicente
ASAndreia D. Santos
Andreia D. Santos
RQRosa M. Quinta-Ferreira
Rosa M. Quinta-Ferreira
LCLuís M. Castro
Luís M. Castro

23 May 2025 in Sustainability
Verified
Journal Article
Open access
PDF file
JSJoão Rafael Silva
João Rafael Silva
Rosa M. Quinta-FerreiraRosa M. Quinta-Ferreira
Rosa M. Quinta-Ferreira
LCLuis M. Castro
Luis M. Castro
Volatile organic compounds (VOC) are major contributors to the burgeoning air pollution issue, predominantly from industrial areas, with well-documented environmental and health risks, which demand efficient and sustainable control policies. This review analyzes the current technological challenges and investigates recent developments in biological treatment technologies for VOC-contaminated off-gases, including biofilters, biotrickling filters, and bioscrubber, as well as emerging technologies, such as bioaugmentation and microbial fuel cells (MFCs). Operational performance, economic feasibility, and adaptability to various industrial applications are assessed, alongside opportunities for integration with other technologies, including energy recovery technologies. Biological systems offer considerable advantages regarding cost savings and lower environmental impacts and enhanced operational flexibility, particularly when combined with innovative materials and microbial optimization techniques. Nevertheless, challenges persist, such as choosing the best treatment settings suited to different VOC streams and addressing biofilm control concerns and scalability. Overall, biological VOC treatments are encouraging sustainable solutions, though continued research into reactor design, microbial dynamics, and MFC-based energetic valorization is essential for broader industrial application. These insights cover advancements and highlight the continuous need for innovative prowess to forge sustainable VOC pollution control.

2 February 2022 in Energy Reports
Verified
Journal Article
Open access
Andreia Duarte SantosAndreia Duarte Santos
Andreia Duarte Santos
JSJoão Rafael Silva
João Rafael Silva
LCLuis M. Castro
Luis M. Castro
RQRosa M. Quinta-Ferreira
Rosa M. Quinta-Ferreira

22 March 2023 in Chemosphere
Verified
Journal Article
Open access
CVCarolina Vicente
Carolina Vicente
JSJoão Rafael Silva
João Rafael Silva
Andreia Duarte SantosAndreia Duarte Santos
Andreia Duarte Santos
JSJoão F. Silva
João F. Silva
JMJorge T. Mano
Jorge T. Mano
LCLuis M. Castro
Luis M. Castro
Electrocoagulation was investigated as a method for treating wastewater containing polyvinyl acetate (PVAc) from the furniture industry. The study evaluated the evolution of iron concentration and passivation during the treatment process. Laboratory-scale experiments were conducted to evaluate the effects of inter-electrode distance (d), current density, and mode on treatment performance. Three values of d (0.3, 0.6, and 0.9 cm) were studied and found to have no significant effect on performance. However, lower d values resulted in reduced energy consumption due to a decrease in applied voltage. Three values of current density (132, 158, and 197 A m-2) were studied under two current modes, Direct Current (DC) and Alternating Pulsed Current (APC). The best treatment performance for DC occurred under 158 A m-2 (the treated wastewater was characterized by pH = 4.59 ± 0.02, conductivity = 996 ± 21 μS cm-1, COD = 1940 ± 55 mgO2 L-1, TSS = 105 ± 14 mg L-1, and Fe = 50.39 ± 1.87 mgFe L-1). For APC, the best performance was achieved under 197 A m-2 (the treated wastewater was characterized by pH = 6.33 ± 0.06, conductivity = 988 ± 17 μS cm-1, COD = 1942 ± 312 mgO2 L-1, TSS = 199 ± 55 mg L-1, and Fe = 44.68 ± 4.60 mgFe L-1). Despite the promising results, treatment performance was insufficient to meet the legal requirements for water discharge. APC was found to be a more economically viable approach, as it reduced anode wear, electrode passivation, and energy consumption. The quantity of iron released increased with d, and the effect of current density on iron concentration was found to be non-linear. However, applying APC reduced the iron content for all tested current densities. The tests showed that EC was effective in removing chemical oxygen demand (COD) and total suspended solids (TSS), achieving removal efficiencies above 92% and 99%, respectively. However, the studied treatment procedures were insufficient to meet the EU legal requirements for water discharge. Therefore, the obtained wastewater should undergo a post-treatment process.

2 February 2022 in Energy Reports
Verified
Journal Article
Open access
Andreia Duarte SantosAndreia Duarte Santos
Andreia Duarte Santos
JSJoão Rafael Silva
João Rafael Silva
LCLuis M. Castro
Luis M. Castro
RQRosa M. Quinta-Ferreira
Rosa M. Quinta-Ferreira