Improving thermal efficiency and reducing carbon emissions are the permanent themes for internal combustion (IC) engines. In the past decades, various advanced strategies have been proposed to achieve higher efficiency and cleaner combustion with the increasingly stringent fuel economy and emission regulations. This article reviews the recent progress in the improvement of thermal efficiency of IC engines and provides a comprehensive summary of the latest research on thermal efficiency from aspects of thermodynamic cycles, gas exchange systems, advanced combustion strategies, and thermal and energy management. Meanwhile, the remaining challenges in different modules are also discussed. It shows that with the development of advanced technologies, it is highly positive to achieve 55% and even over 60% in effective thermal efficiency for IC engines. However, different technologies such as hybrid thermal cycles, variable intake systems, extreme condition combustion (manifesting low temperature, high pressure, and lean burning), and effective thermal and energy management are suggested to be closely integrated into the whole powertrains with highly developed electrification and intelligence.

Ammonia as a carbon-free fuel used in IC engines always suffers from large cyclic variations and high NOx emissions. Ammonia blending with high-reactivity fuels is recognized as an effective attempt to overcome these shortcomings. In this work, for the first time, the combustion and emission characteristics of n-heptane/ammonia were investigated under reactivity-controlled compression ignition (RCCI) conditions in an optical engine. An intake adapter was introduced to modify turbulent flow motion and n-heptane was directly injected to regulate mixture reactivity based on energy ratios. Particle image velocimetry (PIV) was employed for in-cylinder flow measurement, high-speed photography and instantaneous pressure acquisition were used for combustion evolutions, and Fourier transform infrared (FTIR) spectroscopy was adopted for NOx and NH₃ emissions. The results show both mixture reactivity and turbulence have significant impacts on ammonia combustion. Specifically, n-heptane addition manifesting mixture reactivity dominates combustion processes at early-injection conditions, while the turbulence with increasing intensity becomes significant at late-injection conditions. Visualization images show that the initiation of initial flame kernels is controlled by the local distribution of n-heptane fraction, and that high n-heptane fraction at early injection or low n-heptane fraction at late injection conditions tends to induce homogeneous combustion. Flame stretch analysis confirms the promotion of mixture reactivity and turbulence motion on turbulent flame propagation and identifies that a high n-heptane fraction with swirl-tumble motion exhibits lower flame stretch sensitivity, especially for late-injection scenarios. Besides, low mixture reactivity with early injection and high mixture reactivity with late injection strategies can achieve high-efficiency combustion. However, when considering NO_X/NH₃ emissions, a high n-heptane fraction at late injection with swirl-tumble motion has the most potential to achieve the compromise between thermal efficiency and emissions. The present work demonstrates that with optimized fuel injection and flow arrangement, ammonia blending with high-reactivity fuels can achieve high-efficient combustion while maintaining NOx/NH₃ emissions within reasonable levels.