Improving thermal efficiency and reducing carbon emissions are the permanent themes for internal combustion (IC) engines. In the past decades, various advanced strategies have been proposed to achieve higher efficiency and cleaner combustion with the increasingly stringent fuel economy and emission regulations. This article reviews the recent progress in the improvement of thermal efficiency of IC engines and provides a comprehensive summary of the latest research on thermal efficiency from aspects of thermodynamic cycles, gas exchange systems, advanced combustion strategies, and thermal and energy management. Meanwhile, the remaining challenges in different modules are also discussed. It shows that with the development of advanced technologies, it is highly positive to achieve 55% and even over 60% in effective thermal efficiency for IC engines. However, different technologies such as hybrid thermal cycles, variable intake systems, extreme condition combustion (manifesting low temperature, high pressure, and lean burning), and effective thermal and energy management are suggested to be closely integrated into the whole powertrains with highly developed electrification and intelligence.

By the fine manipulation of the exceptional long-range germanium-telluride (Ge─Te) bonding through charge transfer engineering, we have achieved exceptional thermoelectric (TE) and mechanical properties in lead-free GeTe. This chemical bonding mechanism along with a semiordered zigzag nanostructure generates a notable increase of the average zT to a record value of ~1.73 in the temperature range of 323 to 773 K with ultrahigh maximum zT ~ 2.7. In addition, we significantly enhanced the Vickers microhardness numbers ( H _v ) to an extraordinarily high value of 247 H _v and effectively eliminated the thermal expansion fluctuation at the phase transition, which was problematic for application, by the present charge transfer engineering process and concomitant formation of microstructures. We further fabricated a single-leg TE generator and obtained a conversion efficiency of ~13.4% at the temperature difference of 463 K on a commercial instrument, which is located at the pinnacle of TE conversion.