In this review, we summarize recent advances in establishing persistently luminescent materials from the view of examining experimental and theoretical approaches to room-temperature phosphorescence and thermally-activated delayed fluorescence.

Singlet oxygen has won a great deal of attention to catalysis and biological studies due to its strong oxidizing properties. However, the photosensitizers which require for the generation of singlet oxygen remain inadequate because of their lack of long-wavelength absorption, weak hydrophilicity, and poor biocompatibility. Here, we develop near-infrared laser activated supramolecular photosensitizers (isophthalic acid/layered double hydroxide nanohybrids) for efficient two-photon photodynamic therapy. The singlet oxygen quantum yield of nanohybrid is up to 0.74. Critically, in vitro tests verify the superior anti-cancer properties of nanohybrid with an IC₅₀ determine to be 0.153 μg mL⁻¹. The nanohybrids take advantage of the superior tissue penetration of 808 nm laser irradiation and exhibit a dramatically strong ability to ablate tumors in vivo, with extremely low toxicity. This work provides the proof of concept that ultralong-lived triplet excitons can function as two-photon-activated photosensitizers for an effective singlet oxygen generation.

The conversion of solar energy into usable chemical fuels, such as hydrogen gas, via photo(electro)chemical water splitting is a promising approach for creating a carbon neutral energy ecosystem. The deployment of this technology industrially and at scale requires photoelectrodes that are highly active, cost-effective, and stable. To create these new photoelectrodes, transition metal-based electrocatalysts have been proposed as potential cocatalysts for improving the performance of water splitting catalysts. Layered double hydroxides (LDHs) are a class of clays with brucite like layers and intercalated anions. Transition metal-based LDHs are increasingly popular in the field of photo(electro)chemical water splitting due to their unique physicochemical properties. This article aims to review recent advances in transition metal-based LDHs for photo(electro)chemical water splitting. This article provides a brief overview of the research in a format approachable for the general scientific audience. Specifically, this review examines the following areas: (i) routes for synthesis of transition metal-based LDHs, (ii) recent developments in transition metal-based LDHs for photo(electro)chemical water splitting, and (iii) an overview of the structure–property relationships therein.

The orderly assembly of photoactive donor and acceptor phosphors within the gallery of 2D layered nanosheets presents obviously long-lived luminescence and effective energy transfer.