Aiming at solving the slow-response problem of traditional bead-type thermal conductivity gas sensors, a fast-response thermal conductivity gas sensor can be made by using multiwalled carbon nanotubes (MWNTs), combined with the technology of carrier modification, to modify the performance of the sensor carrier. The carrier material, granular nanoscale γ-Al2O3/ZrO2, was synthesized by chemical precipitation, and its particle size was found to be 50–70 nm through SEM. After the carrier material was wet-incorporated into carbon nanotubes, the composite carrier γ-Al2O3/ZrO2/MWNTs was obtained. The results show that the designed thermal conductivity sensor has a fast response to methane gas, with a 90% response time of 7 s and a recovery time of 16 s. There is a good linear relationship between the sensor output and CH4 gas concentration, with an average sensitivity of 1.15 mV/1% CH4. Thus, the response speed of a thermal conductivity sensor can be enhanced by doping carbon nanotubes into γ-Al2O3/ZrO2.
Surface Acoustic Wave (SAW) methane-sensing technology is a new way to detect methane at room temperature. However, the material and structure of the sensitive film are the important factors affecting the detection performance of the sensor. In this paper—with a SAW methane sensor using graphene–nickel cavitation—a composite film is proposed, which can work at room temperature. A delay linear dual-channel differential oscillator with center frequency of 204.3 MHz and insertion loss of −5.658 dB was designed; Cryptophane-A material was prepared by the “three-step method”. The composite sensitive film was synthesized by a drop coating method, electrochemical deposition method and electroplating method. The composite film was characterized by SEM. The sensor performance test system and gas sensitivity test system were constructed to determine the response performance of the sensor at concentrations of 0~5% CH4. The results showed that the sensor had a good response recovery performance in the test concentration range, and the frequency offset was positively correlated with methane concentration. The 90% average response time and recovery times were 41.2 s and 57 s, respectively. The sensor sensitivity was 809.4 ± 6.93 Hz/(1% CH4). This study provides a good theoretical basis for the development of surface acoustic-wave methane sensors.
In order to improve the response characteristics of the surface acoustic wave (SAW) sensor to trace gases, a SAW CO gas sensor based on a Pd–Pt/SnO2/Al2O3 film with a high-frequency response performance is proposed in this paper. The gas sensitivity and humidity sensitivity of trace CO gas are tested and analyzed under normal temperatures and pressures. The research results show that, compared with the frequency response of the Pd–Pt/SnO2 film, the CO gas sensor based on a Pd–Pt/SnO2/Al2O3 film has a higher frequency response performance, and the sensor has high-frequency response characteristics to CO gas with a concentration in the range of 10–100 ppm. The average response recovery time of 90% ranges from 33.4 s to 37.2 s, respectively. When the CO gas with a concentration of 30 ppm is tested repeatedly, its frequency fluctuation is less than 5%, indicating that the sensor has good stability. In the range of relative humidity (RH) from 25% to 75%, it also has high-frequency response characteristics for CO gas with a 20 ppm concentration.
In order to further improve the degree of frequency response of the surface acoustic wave (SAW) sensor for gas detection, the structure of the forked-finger transducer was analyzed, and its optimal structural parameters were simulated and designed. The simulation model of the unidirectional fork-finger transducer is established by using COMSOL finite element software. The thickness of the piezoelectric substrate, the electrode structure and material, and the thickness of the coating film are optimized and simulated. The results show that: the optimal thickness of the piezoelectric substrate is 3λ. The optimal thickness ratio and the lay-up ratio of the forked-finger electrode are 0.02 and 0.5, respectively. The Al electrode is more suitable as the a forked-finger electrode material compared to Cu, Au and Pt materials. Under the same conditions, the metal oxide-sensitive film (ZnO and TiO2) has a higher frequency response than the polymer-sensitive film (polyisobutylene and polystyrene), and the best sensitive film thickness range is 0.5~1 μm.
27 August 2018 in Journal of Ambient Intelligence and Humanized Computing
Mechanics-seepage synchronous tests on gas-bearing coal under three different stress paths were designed and implemented to evaluate how load path affected the mechanical strength and permeability of deep mining-disturbed coal. The cracks-count evolution of coal specimens during instability was observed through DEM numerical simulation. The results showed significant stress-strain and strength variations under different paths. At the time of failure, the specimen deformation and peak strength were Test 1 > Test 2 > Test 3, while the permeability was Test 3 > Test 2 > Test 1, with specimen permeability in Test 3 rising prominently. From numerical simulation, the cracks count was Test 2 > Test 3 > Test 1, with tensile cracks taking the largest proportion in Test 2 and shear cracks taking the largest proportion in Test 3. Our findings shed some light on the research and disaster prevention regarding coal and gas outburst.