In this paper, we present ship-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements of tropospheric trace gases' distribution along the Yangtze River during winter 2015. The measurements were performed along the Yangtze River between Shanghai and Wuhan, covering major industrial areas in eastern China. Tropospheric vertical column densities (VCDs) of nitrogen dioxide (NO₂), sulfur dioxide (SO₂), and formaldehyde (HCHO) were retrieved using the air mass factor calculated by the radiative transfer model. Enhanced tropospheric NO₂ and SO₂ VCDs were detected over downwind areas of industrial zones over the Yangtze River. In addition, spatial distributions of atmospheric pollutants are strongly affected by meteorological conditions; i.e., positive correlations were found between concentration of pollutants and wind speed over these areas, indicating strong influence of transportation of pollutants from high-emission upwind areas along the Yangtze River. Comparison of tropospheric NO₂ VCDs between ship-based MAX-DOAS and Ozone Monitoring Instrument (OMI) satellite observations shows good agreement with each other, with a Pearson correlation coefficient (R) of 0.82. In this study, the NO₂ ∕ SO₂ ratio was used to estimate the relative contributions of industrial sources and vehicle emissions to ambient NO₂ levels. Analysis results of the NO₂ ∕ SO₂ ratio show a higher contribution of industrial NO₂ emissions in Jiangsu Province, while NO₂ levels in Jiangxi and Hubei provinces are mainly related to vehicle emissions. These results indicate that different pollution control strategies should be applied in different provinces. In addition, multiple linear regression analysis of ambient carbon monoxide (CO) and odd oxygen (O_x) indicated that the primary emission and secondary formation of HCHO contribute 54.4 ± 3.7 % and 39.3 ± 4.3 % to the ambient HCHO, respectively. The largest contribution from primary emissions in winter suggested that photochemically induced secondary formation of HCHO is reduced due to lower solar irradiance in winter. Our findings provide an improved understanding of major pollution sources along the eastern part of the Yangtze River which are useful for designing specific air pollution control policies.

Environmental trace gas monitoring instrument (EMI) onboard GaoFen-5 was launched in May 2018 and has successfully operated on-orbit for more than a year. EMI contains four grating spectrometers, covering wavelengths in the range 240-710 nm with a spectral resolution of 0.3-0.5 nm, and enables one-day global coverage. For EMI on-orbit calibration, two onboard solar diffusers (SD), one surface reflectance aluminum diffuser, and one quartz volume diffuser (QVD) are used to measure solar spectra. The solar spectra are used to perform accurate spectral and radiometric calibrations. EMI on-orbit spectral calibration contains wavelength calibration and instrument spectral response function (ISRF), both of which are the key quantities in trace gas retrievals based on differential optical absorption spectroscopy (DOAS) analysis. The wavelength calibration is performed using the Fraunhofer lines in the solar spectrum, and the ISRF parameters are obtained by fitting high-resolution and EMI-measured solar spectra. Based on the known solar irradiation and characteristic of SD, SD radiance can be calculated and is used for EMI on-orbit radiometric calibration. The radiometric calibration also determines the absolute Earth reflectance spectra that are used as inputs for atmospheric retrieval algorithms. For EMI on-orbit radiometric monitoring, aluminum diffuser is used as reference SD to monitor QVD degradation. An internal white light source is used to detect pixel performance and monitor radiometric throughput.

During polar spring, the presence of reactive bromine in the polar boundary layer is considered to be the main cause of ozone depletion and mercury deposition. However, many uncertainties still remain regarding understanding the mechanisms of the chemical process and source of the bromine. As Arctic sea ice has recently been dramatically reduced, it is critical to investigate the mechanisms using more accurate measurements with higher temporal and spatial resolution. In this study, a typical process of enhanced bromine and depleted ozone in the Ny-Ålesund boundary layer in late April 2015 was observed by applying ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) technique. The results showed that there were bromine monoxide (BrO) slant columns as high as 5.6 × 10¹⁴ molec cm⁻² above the Kings Bay area on 26 April. Meanwhile, the boundary layer ozone and gaseous elemental mercury (GEM) were synchronously reduced by 85 and 90 %, respectively. Based on the meteorology, sea ice distribution and air mass history, the sea ice in the Kings Bay area, which emerged for only a very short period of time when the enhanced BrO was observed, was considered to be the major source of this bromine enhancement event. The oxidized GEM may be directly deposited onto snow/ice and thereby influence the polar ecosystem.

An environmental trace gases monitoring instrument (EMI) is a nadir-viewing wide-field imaging spectrometer, which aims to quantify the global distribution of tropospheric and stratospheric trace gases, and is planned to be launched on 9 May 2018. The selected wavelength bands for EMI are ultraviolet channels: UV1 (240–315 nm), UV2 (311–403 nm) and visible channels: VIS1 (401–550 nm), and VIS2 (545–710 nm). The spectral resolution is 0.3–0.5 nm, and the swath is approximately 114∘ wide to achieve a one-day global coverage. The preflight calibration of the EMI is discussed in this paper. A tunable laser and rotating platform are adopted for an EMI wavelength calibration of the entire field of view. The accuracy of the wavelength calibration is less than 0.05 nm. In addition, the solar calibration mode shows the same results compared with Earth observation mode. A thermal vacuum test is performed to investigate the influence of in-orbit thermal vacuum conditions on the EMI, and EMI spectral response changes with pressure, optical bench temperature, and charge-coupled device (CCD) detector temperature are obtained. For a radiometric calibration of UV1, a diffuser plate with a 1000 W xenon lamp, which produces sufficient UV output, is selected. An integrating sphere system with tungsten halogen lamp is selected for the UV2, VIS1, and VIS2. The accuracies of radiance calibration are 4.53 % (UV1), 4.52 % (UV2), 4.31 % (VIS1), and 4.30 % (VIS2). The goniometry correction factor and irradiance response coefficient of the EMI are also calibrated on the ground for an in-orbit calibration of the solar. A signal-to-noise ratio (SNR) model of the EMI is introduced, and the EMI in-orbit SNR is estimated using the SNR and MODTRAN radiance models.

In recent years, surface ozone concentrations have increased in many cities in China. Ground-based multi-axis differential optical absorption spectroscopy (MAX-DOAS) is a powerful technique for retrieving the profiles of tropospheric trace gases, such as NO₂, SO₂, and HCHO. However, since the difficulties in deducting the effects of stratospheric ozone, there are few studies on the retrieval of tropospheric ozone profiles using MAX-DOAS measurements. Here, we developed an accurate inversion method to retrieve tropospheric ozone concentrations during the PRIDE-GBA Campaign, wherein the ozone differential slant column densities (DSCDs) were retrieved in QDOAS software using the "time-interpolated zenith spectrum" as the reference spectrum. The tropospheric DSCDs (DSCDs_trop) were then calculated by subtracting the simulated stratospheric DSCDs (DSCDs_str, simulated from the SCIATRAN model) from the DSCDs. Tropospheric ozone profiles were retrieved from the DSCDs_trop using the optimal estimation method (OEM). The results showed that high values of tropospheric ozone were mainly distributed below 1 km, which is consistent with lidar measurements. In addition, the observed surface ozone concentrations were highly correlated with the in-situ measurements, with correlation coefficients (R) of 0.75 and 0.81, respectively. Combined with the retrieved NO₂ and HCHO profiles using the MAX-DOAS measurements, we found that the planetary boundary layer ozone pollution of HeShan Observatory during the PRIDE-GBA Campaign are controlled by the NO_x-limited regime. The results of this study indicate that the MAX-DOAS technique has the potential to retrieve tropospheric ozone profiles with high temporal and spatial resolution.

The environmental trace gas monitoring instrument (EMI) is a space-borne imaging spectrometer onboard GaoFen-5, which was launched in May 2018, covering wavelengths in the range of 240–710 nm to measure NO₂, O₃, HCHO, and SO₂. An advanced EMI-2 instrument with a higher spatial resolution and sufficient signal-to-noise is currently planned for launch on the GaoFen-5(02) satellite in 2021. The EMI-2 instrument bidirectional scattering distribution function (BSDF) is obtained from the absolute irradiance and radiance calibration on-ground. Based on EMI-2 earth and sun optical paths, the key factors of BSDF parameters are introduced. An NIST-calibrated 1000 W FEL quartz tungsten halogen lamp and a 2D turntable are adopted for the absolute irradiance calibration. A large aperture integrating sphere system is used for the absolute radiance calibration. Based on absolute irradiance and radiance calibration functions, the BSDF parameters are obtained, with accuracy of 4.9% for UV1, 4.3% for UV2, 4.1% for VIS1, and 4.2% for VIS2. The on-ground measurement results show that the reflectance spectrum can be calculated from BSDF parameters. On-orbit application of the EMI-2 instrument BSDF are also discussed.