Lead‐based relaxor ferroelectrics are characterized by outstanding piezoelectric and dielectric properties, making them useful in a wide range of applications. Despite the numerous models proposed to describe the relation between their nanoscale polar structure and the large properties, the multiple contributions to these properties are not yet revealed. Here, by combining atomistic and mesoscopic‐scale structural analyses with macroscopic piezoelectric and dielectric measurements across the (100–x)Pb(Mg_1/3Nb_2/3)O₃–xPbTiO₃ (PMN–xPT) phase diagram, a direct link is established between the multiscale structure and the large nonlinear macroscopic response observed in the monoclinic PMN‐xPT compositions. The approach reveals a previously unrecognized softening effect, which is common to Pb‐based relaxor ferroelectrics and arises from the displacements of low‐angle nanodomain walls, facilitated by the nanoscale polar character and lattice strain disorder. This comprehensive comparative study points to the multiple, distinct mechanisms that are responsible for the large piezoelectric response in relaxor ferroelectrics.

The high Curie temperature (T_C ∼ 825 °C) of BiFeO₃ has made this material potentially attractive for the development of high-T_C piezoelectric ceramics. Despite significant advances in the search of new BiFeO₃-based compositions, the piezoelectric behavior of the parent BiFeO₃ at elevated temperatures remains unexplored. We present here a systematic analysis of the converse, longitudinal piezoelectric response of BiFeO₃ measured in situ as a function of temperature (25–260 °C), driving-field frequency, and amplitude. Earlier studies performed at room temperature revealed that the frequency and field dependence of the longitudinal response of BiFeO₃ is dominated by linear and nonlinear piezoelectric Maxwell-Wagner mechanisms, originating from the presence of local conductive paths along domain walls and grain boundaries within the polycrystalline matrix. This study shows that the same mechanisms are responsible for the distinct temperature dependence of the piezoelectric coefficient and phase angle and thus identifies the local electrical conductivity as the key for controlling the temperature dependent piezoelectric response of BiFeO₃ and possibly other, more complex BiFeO₃-based compositions.

Integrating systems are frequently encountered in the oil industry (oil–water–gas separators, distillation columns), power plants, paper-production plants, polymerisation processes, and in storage tanks. Due to the non-self-regulating character of the processes, any disturbance can cause a drift of the process output signal. Therefore, efficient closed-loop control of such processes is required. There are many PI and PID controller tuning methods for integrating processes. However, it is hard to find one requiring only a simple tuning procedure on the process, while the tuning method is based either on time-domain measurements or on a process transfer function of arbitrary order, which are the advantages of the magnitude optimum multiple integration (MOMI) tuning method. In this paper, we propose the extension of the MOMI tuning method to integrating processes. Besides the mentioned advantages, the extension provides efficient closed-loop control, while PI controller parameters calculation is still based on simple algebraic expressions, making it suitable for less-demanding hardware, like simpler programmable logic controllers (PLC). Additionally, the proposed method incorporates reference weighting factor b that allows users to emphasize either the disturbance-rejection or reference-following response. The proposed extension of the MOMI method (time-domain approach) was also tested on a charge-amplifier drift-compensation system, a laboratory hydraulic plant, on an industrial autoclave, and on a solid-oxide fuel-cell temperature control. All closed-loop responses were relatively stable and fast, all in accordance with the magnitude optimum criteria.

Integrating systems are frequently encountered in power plants, paper-production plants, storage tanks, distillation columns, chemical reactors, and the oil industry. Due to the open-loop instability that leads to an unbounded output from a bounded input, the efficient control of integrating systems remains a challenging task. Many researchers have addressed the control of integrating processes: Some solutions are based on a single closed-loop controller, while others employ more complex control structures. However, it is difficult to find one solution requiring only a simple tuning procedure for the process. This is the advantage of the magnitude optimum multiple integration (MOMI) tuning method. In this paper, we propose an extension of the MOMI tuning method for integrating processes, controlled with a two-degrees-of-freedom (2-DOF) proportional–integral–derivative (PID) controller. This extension allows for calculations of the controller parameters from either time domain measurements or from a process transfer function of an arbitrary order with a time-delay, when both approaches are exactly equivalent. The user has the option to emphasise disturbance-rejection or tracking with the reference weighting factor b or apply two different reference filters for the best overall response. The proposed extension was also compared to other tuning methods for the control of integrating processes and tested on a charge-amplifier drift-compensation system. All closed-loop responses were relatively fast and stable, all in accordance with the magnitude optimum criteria.

Piezoelectric resonance impedance spectroscopy is a standardized measurement technique for determining the electromechanical, elastic, and dielectric parameters of piezoceramics. However, commercial measurement setups are designed for small-signal measurements and encounter difficulties when constant driving voltages/currents are required at resonances, higher fields, or combined AC and DC loading. The latter is particularly important to evaluate the DC bias-hardening effect of piezoelectrics. Here, we propose a novel measurement system for piezoelectric resonance impedance spectroscopy under combined AC and high-voltage DC loading that complies with established standards. The system is based on two separate output amplifier stages and includes voltage/current probes, a laser vibrometer, custom protection components, and control software with optimization algorithm. In its current form, the measurement setup allows the application of AC frequencies up to 500 kHz and DC signals up to +/-10 kV on samples with impedance between 10 ^-1 and 10 ⁶ Ω. The operation of the proposed setup was benchmarked against commercial impedance analyzers in the small-signal range and reference equivalent circuits. Test measurements under combined AC and DC loading were performed on a soft Pb(Zr,Ti)O ₃ piezoceramic. The results revealed that a DC bias voltage applied along the polarization direction ferroelectrically hardens the material, while the material softens and eventually depolarizes when the DC bias voltage is applied in the opposite direction. The results confirm the suitability of the designed measurement system and open new exciting possibilities for tuning the piezoelectric properties by DC bias fields.