The basic oxygen furnace (BOF) is the dominating primary steelmaking process. It is an autothermal process where hot metal and scrap are used as charging materials. The decarbonization and transformation of integrated BOF steelmaking will be the most important challenge in the coming years. Steel scrap is a charge material without new CO2 emissions, whose availability is expected to grow significantly and will play a key role in this decarbonization process. Several solutions have been developed by Primetals Technologies to provide additional energy for processing higher scrap rates in integrated BOF steelmaking. Such solutions include simple upgrade packages installed on existing converters such as process models for heat optimization, post-combustion, and scrap preheating lances. For higher scrap rates from 30% to 50%, a combination blowing converter and JET converter is required to provide sufficient mixing during scrap melting and the highest heat transfer from the increased post-combustion. Hybrid EAF–BOF operation and limitations regarding scrap quality also need to be considered for the transformation of steelmaking. Scrap sorting and processing can be a solution to reduce residual levels in crude steel for high scrap rates. Based on reference plant data, the CO2 reduction potential of the presented solution versus the effort and complexity of implementation is compared.
Since the European Union defined ambitious CO2 emission targets, low-carbon-emission alternatives to the widespread integrated blast furnace (BF)—basic oxygen furnace (BOF) steelmaking strategy—are demanded. Direct reduction (DR) with natural gas as the reducing agent, already an industrially applied technology, is such an alternative. Consequently, the melting behavior of its intermediate product, i.e., direct reduced iron (DRI), in either an electric arc furnace (EAF) or a submerged arc furnace (SAF), is of great interest. Based on the conditions in these aggregates, a test series to experimentally simulate the first few seconds after charging DRI was defined. DRI samples with different carbon contents and hot briquetted iron (HBI) were immersed in high- and low-carbon melts as well as high- and low-iron oxide slags. The reacted samples were quenched in liquid nitrogen. The specimens were qualitatively evaluated by investigating their surfaces and cross sections. The dissolution of carbon-free DRI progressed relatively slowly and was driven by heat transfer. However, carbon, present either in the DRI sample or in the melt, not only accelerated the dissolution process, but also reacted with residual iron oxide in the pellet or the slag.
Hydrogen-based direct reduction is a promising technology for CO2 lean steelmaking. The electric arc furnace is the most relevant aggregate for processing direct reduced iron (DRI). As DRI is usually added into the arc, the behavior in this area is of great interest. A laboratory-scale hydrogen plasma smelting reduction (HPSR) reactor was used to analyze that under inert conditions. Four cases were compared: carbon-free and carbon-containing DRI from DR-grade pellets as well as fines from a fluidized bed reactor were melted batch-wise. A slag layer’s influence was investigated using DRI from the BF-grade pellets and the continuous addition of slag-forming oxides. While carbon-free materials show a porous structure with gangue entrapments, the carburized DRI forms a dense regulus with the oxides collected on top. The test with slag-forming oxides demonstrates the mixing effect of the arc’s electromagnetic forces. The cross-section shows a steel melt framed by a slag layer. These experiments match the past work in that carburized DRI is preferable, and material feed to the hotspot is critical for the EAF operation.