Although γ/η-Mo4O11 and Mo2Ta2O11 are used in a variety of industrial applications and can easily be synthesized in a chemical vapour transport (CVT) process or reactions in silica ampoules, respectively, only few data are available concerning their physical properties. In this paper, we further explore the properties of the three compounds with respect to their thermal and magnetic behavior, surface composition, and Raman spectroscopic properties.
1 December 2018 in Journal of Structural Chemistry
FeBO3 and Fe3BO6 are antiferromagnets with TN≈ 348 K and 508 K respectively. This work presents the results of the study of the thermal expansion and phase transitions occurring in these borates by...