We report on a fiber-coupled, quartz-enhanced photoacoustic spectroscopy (QEPAS) near-IR sensor for sequential detection of methane (CH₄ or C1) and ethane (C₂H₆ or C2) in air. With the aim of developing a lightweight, compact, low-power-consumption sensor suitable for unmanned aerial vehicles (UAVs)-empowered environmental monitoring, an all-fiber configuration was designed and realized. Two laser diodes emitting at 1653.7 nm and 1684 nm for CH₄ and C₂H₆ detection, respectively, were fiber-combined and fiber-coupled to the collimator port of the acoustic detection module. No cross talk between methane and ethane QEPAS signal was observed, and the related peak signals were well resolved. The QEPAS sensor was calibrated using gas samples generated from certified concentrations of 1% CH₄ in N₂ and 1% C₂H₆ in N₂. At a lock-in integration time of 100 ms, minimum detection limits of 0.76 ppm and 34 ppm for methane and ethane were achieved, respectively. The relaxation rate of CH₄ in standard air has been investigated considering the effects of H₂O, N₂ and O₂ molecules. No influence on the CH₄ QEPAS signal is expected when the water vapor concentration level present in air varies in the range 0.6–3%.

In this paper the performances of two spectrophones for quartz-enhanced photoacoustic spectroscopy (QEPAS)-based ethane gas sensing were tested and compared. Each spectrophone contains a quartz tuning fork (QTF) acoustically coupled with a pair of micro-resonator tubes and having a fundamental mode resonance frequency of 32.7 kHz (standard QTF) and 12.4 kHz (custom QTF), respectively. The spectrophones were implemented into a QEPAS acoustic detection module (ADM) together with a preamplifier having a gain bandwidth optimized for the respective QTF resonance frequency. Each ADM was tested for ethane QEPAS sensing, employing a custom pigtailed laser diode emitting at ~1684 nm as the exciting light source. By flowing 1% ethane at atmospheric pressure, a signal-to-noise ratio of 453.2 was measured by implementing the 12.4 kHz QTF-based ADM, ~3.3 times greater than the value obtained using a standard QTF. The minimum ethane concentration detectable using a 100 ms lock-in integration time achieving the 12.4 kHz custom QTF was 22 ppm.