Composite polymer membranes of poly(vinyl alcohol) (PVA) and iron oxide (Fe₃O₄) nanoparticles were produced in this work. X-ray diffraction measurements demonstrated the formation of Fe₃O₄ nanoparticles of cubic structures. The nanoparticles were synthesized by a coprecipitation technique and added to PVA solutions with different concentrations. The solutions were then used to generate flexible membranes by a solution casting method. The size and shape of the nanoparticles were investigated using scanning electron microscopy (SEM). The average size of the nanoparticles was $20\pm 9$ nm. Raman spectroscopy and Fourier-transform infrared spectroscopy (FTIR) were utilized to investigate the structure of the membranes, as well as their vibration modes. Thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC) demonstrated the thermal stability of the membranes and the crystallinity degree. Electrical characteristics of the thin membranes were examined using impedance spectroscopy as a function of the nanoparticles’ concentrations and temperatures. The resistivity of the fabricated flexible membranes was possible to adjust by controlled doping with suitable concentrations of nanoparticles. The activation energy decreased with the nanoparticles’ concentrations due to the increase in charge carriers’ concentrations. Therefore, the fabricated membranes may be applied for practical applications that involve the recycling of nanoparticles for multiple application cycles.

Morphologically controlled Pd-based nanocrystals are the most efficient strategies for improving the electrocatalytic ethanol oxidation reaction (EOR) performance; however, their morphological-EOR activity relationship and effect of electrolytes at a wide pH range are still ambiguous. Here, we have synthesized porous self-standing Pd clustered nanospheres (Pd-CNSs) and Pd nanocubes (Pd-NCBs) for the EOR in acidic (H₂SO₄), alkaline (KOH), and neutral (NaHCO₃) electrolytes compared to commercial spherical-like Pd/C catalysts. The fabrication process comprises the ice-cooling reduction of Pd precursor by sodium borohydride (NaBH₄) and l-ascorbic acid to form Pd-CNSs and Pd-NCBs, respectively. The EOR activity of Pd-CNSs significantly outperformed those of Pd-NCBs, and Pd/C in all electrolytes, but the EOR activity was better in KOH than in H₂SO₄ and NaHCO₃. This is due to the 3D porous clustered nanospherical morphology that makes Pd active centers more accessible and maximizes their utilization during EOR. The EOR specific/mass activities of Pd-CNSs reached (8.51 mA/cm²/2.39 A/mg_Pd) in KOH, (2.98 mA/cm²/0.88 A/mg_Pd) in H₂SO₄, and (0.061 mA/cm²/0.0083 A/mg_Pd) in NaHCO₃, in addition to stability after 1000 cycles. This study affirms that porous 3D spherical Pd nanostructures are preferred for the EOR than those of 0D spherical-like and multi-dimensional cube-like nanostructures.

Direct alcohol fuel cells are deemed as green and sustainable energy resources; however, CO-poisoning of Pt-based catalysts is a critical barrier to their commercialization. Thus, investigation of the electrochemical CO oxidation activity (CO_Oxid) of Pt-based catalyst over pH ranges as a function of Pt-shape is necessary and is not yet reported. Herein, porous Pt nanodendrites (Pt NDs) were synthesized via the ultrasonic irradiation method, and its CO oxidation performance was benchmarked in different electrolytes relative to 1-D Pt chains nanostructure (Pt NCs) and commercial Pt/C catalyst under the same condition. This is a trial to confirm the effect of the size and shape of Pt as well as the pH of electrolytes on the CO_Oxid. The CO_Oxid activity and durability of Pt NDs are substantially superior to Pt NCs and Pt/C in HClO₄, KOH, and NaHCO₃ electrolytes, respectively, owing to the porous branched structure with a high surface area, which maximizes Pt utilization. Notably, the CO_Oxid performance of Pt NPs in HClO₄ is higher than that in NaHCO₃, and KOH under the same reaction conditions. This study may open the way for understanding the CO_Oxid activities of Pt-based catalysts and avoiding CO-poisoning in fuel cells.

Tailoring the shape of Pd nanocrystals is one of the main ways to enhance catalytic activity; however, the effect of shapes and electrolyte pH on carbon monoxide oxidation (CO_Oxid) is not highlighted enough. This article presents the controlled fabrication of Pd nanocrystals in different morphologies, including Pd nanosponge via the ice-cooling reduction of the Pd precursor using NaBH₄ solution and Pd nanocube via ascorbic acid reduction at 25 °C. Both Pd nanosponge and Pd nanocube are self-standing and have a high surface area, uniform distribution, and clean surface. The electrocatalytic CO oxidation activity and durability of the Pd nanocube were significantly superior to those of Pd nanosponge and commercial Pd/C in only acidic (H₂SO₄) medium and the best among the three media, due to the multiple adsorption active sites, uniform distribution, and high surface area of the nanocube structure. However, Pd nanosponge had enhanced CO_Oxid activity and stability in both alkaline (KOH) and neutral (NaHCO₃) electrolytes than Pd nanocube and Pd/C, attributable to its low Pd-Pd interatomic distance and cleaner surface. The self-standing Pd nanosponge and Pd nanocube were more active than Pd/C in all electrolytes. Mainly, the CO_Oxid current density of Pd nanocube in H₂SO₄ (5.92 mA/cm²) was nearly 3.6 times that in KOH (1.63 mA/cm²) and 10.3 times that in NaHCO₃ (0.578 mA/cm²), owing to the greater charge mobility and better electrolyte–electrode interaction, as evidenced by electrochemical impedance spectroscopy (EIS) analysis. Notably, this study confirmed that acidic electrolytes and Pd nanocube are highly preferred for promoting CO_Oxid and may open new avenues for precluding CO poisoning in alcohol-based fuel cells.

Graphitic carbon nitrides (gCNs) are promising materials for multidisciplinary catalytic applications due to their inimitable physicochemical merits, thermal-physical-chemical stability, and rich electron density. The catalytic properties of gCNs are determined by their structure and composition; therefore, various methods have been developed for the rational synthesis of gCNs with different morphologies and compositions. Unlike other gCN nanostructures, one-dimensional (1D) nanostructures possess an outstanding accessible surface area, multiple adsorption sites, active catalytic sites, aspect ratio, and short electron-diffusion that enable their utilization in various gas conversion reactions. The thermal CO oxidation reaction (CO OR) on either gCNs or other catalysts is important in industrial, fundamental, and environmental issues; however, the reviews on 1D gCNs for CO oxidation is not yet reported. This chapter highlights the fabrication methods of 1D gCN nanostructures (i.e., nanotubes, nanorods, nanofibers, and needles) and their mechanisms and utilization in thermal CO ORs. Lastly, the current challenges and future prospects on gCNs for CO ORs are also discussed.