In the past two decades, titanium foams have attracted greater interest from the biomedical industry due to their excellent chemical and mechanical biocompatibility when used as biomimetic implants. The porous structure plays an important role in bone adhesion to an implant, allowing its growth into the component. Moreover, the voids reduce the elastic modulus, promoting greater compatibility with the bone, avoiding the stress shielding effect. In this regard, metal injection molding is an attractive process for titanium foams manufacturing due to the high microstructural control and the possibility of producing, on a large scale, parts with complex near-net-shaped structures. In this review, recent discoveries and advantages regarding the processing of titanium powders and alloys via metal injection molding combined with the space holder method are presented. This approach can be used to obtain foams with high biocompatibility with the human body at a microstructural, chemical, and mechanical level.

Sintered iron-based self-lubricant composites in which graphite reservoirs are generated by the dissociation of silicon carbide (SiC) particles feature low friction coefficients and scuffing resistance combined with high mechanical stress. This work evaluated the influence of the sintering temperature and the SiC polytype on the graphite reservoirs morphology, structure, and friction behaviour. The reservoirs were studied by field emission gun-scanning electron microscopy (FEG-SEM), micro-Raman spectroscopy, and transmission electron microscopy (TEM). The friction behaviour was evaluated by cylinder on plane tests (friction coefficient and scuffing resistance). The results showed that the SiC polytype and the sintering temperature modified the graphite structures. The SiC dissociation promoted the formation of different nano graphites, presenting different turbostratic 2D and 3D arrays. The results showed that the presence of the turbostratic graphite was beneficial to the friction behaviour of these composites, which offered better tribological performance than the composite with 3D graphite.

The dispersion stability of carbon-based solid lubricants/lubricating oils remains a challenge to overcome. Recently, novel processing routes were developed to obtain 2D turbostratic graphite particles via solid-state reactions between B₄C and Cr₃C₂ (GBC) and between SiC and Fe (GSF) that present outstanding tribological properties in a dry scenario, as well as functionalized graphene (GNH). This work investigated the suspension stability of GBC and GSF particles (0.05 wt.%) dispersed in a low-viscosity polyol ester lubricating oil and their tribological performance. Ammonia-functionalized graphene (GNH) particles were also used as a reference. In order to evaluate the dispersion stability, in addition to the classical digital image technique, a much more assertive, reliable, quantitative and rarely reported in the literature technique was used, i.e., the STEP^TM (Space and Time-resolved Extinction Profiles) technology. Reciprocating sphere-on-flat tribological tests were carried out, in which before contact, 0.2 μL of pure oil and suspension (POE + 0.05 wt.% of solid lubricant) was applied on a flat surface. The results showed that the GBC particles remained remarkably stable and reduced the sphere wear rate by 61.8%. From the tribosystem point of view, the presence of GBC and GSF reduced the wear rate by 18.4% and 2.2%, respectively, with respect to the pure oil, while the GNH particles increased the wear rate by 4.2%. Furthermore, the wear rate was improved due to the highly disordered carbon tribolayer formation identified on both surfaces.