The structure of an autonomous underwater vehicle (AUV), usually composed of a cylindrical shell, may be exposed to high hydrostatic pressures where buckling collapse occurs before yield stress failure. In conventional submarines, welded stiffeners increase the buckling resistance, however, in small AUVs, they reduce the inner space and cause residual stresses. This work presents an innovative concept for the structural design of an AUV, proposing the use of sliding stiffeners that are part of the structure used to accommodate the electronics inside it. Since the sliding stiffeners are not welded to the shell, there are no residual stresses due to welding, the AUV fabrication process is simplified, enabling a reduction of the manufacturing cost, and the inner space is available to accommodate the equipment needed for the AUV mission. Moreover, they provide a higher buckling resistance when compared to that of an unstiffened cylindrical shell. A comparative analysis of the critical buckling loads for different shell designs was carried out considering the following: (i) the unstiffened shell, (ii) the shell with ring stiffeners, and (iii) the shell with sliding stiffeners. Results evidenced that major advantages were obtained by using the latter alternative against buckling.
A characterization of composite materials of a polyester matrix reinforced with natural fibers of Cuban henequen and organophilized Cuban bentonite was carried out, the experimental results of which are used to formulate, implement, and validate a scalar damage model. The fibers were added on a weight basis of 15, 20, and 25% as a reinforcing material, and organophilized Cuban bentonite, in amounts of 3, 5, and 7% by weight, was added. Samples containing only polymer and fibers showed the best mechanical performance for 25% of fiber, with increases of 51% in the tensile strength and 169% on the impact resistance. Samples containing polymer and clay showed the best results for 5% of bentonite, with increases of 89% in the tensile strength and 83% on the impact resistance, and samples containing 25% fiber and 5% clay were also prepared and achieved a 98% increase in the tensile strength and 219% in the impact strength. The scalar damage model deals with an internal variable, which corresponds to the damage variable, together with a failure surface that allows identifying the mechanical state of the material dependent on the mechanical stress, obtaining an adequate correlation with the results of the experimental tests.
The influence of the addition of bentonite nanoparticles on the tensile and flexural strength of a thermosetting polymer matrix composite material reinforced with hemp fibers was de-terminated. All composites were manufactured with 5% of bentonite in the polymer mass–weight ratios and 10 to 45 wt% of fibers with a step of 5%. For mechanical characterization, tensile and flexural tests were performed: scanning electron microscopy and energy-dispersive X-ray spectroscopy analyses were carried out. The tensile strength of the samples containing bentonite compared to the polymer samples with the fiber addition was affected for all fiber addition percentages, except for 35% while the flexural resistance improved with the addition of bentonite in the percentages of 20, 30, 35, and 45% of fiber addition. With the addition of bentonite, the maximum values of tensile and flexural strength were both obtained for the 35% addition of fibers, with values of 34.28 MPa and 98.04 MPa, respectively. The presence of bentonite favored the rigidity of the material to traction and bending, which was reflected through an increase in the elastic modulus compared to the composite that only had fiber. The maximum values obtained were 9065 MPa in tension and 8453 MPa in flexion for the 40% and 35% of addition of fiber, respectively. Microscopy showed a good distribution of fibers in the matrix, the absence of internal porosities, and a good interaction between matrix and reinforcement.
Currently, the cultivation and harvesting of mollusks is a crucial activity worldwide. However, this industry generates a large amount of mollusk shell waste disposed of in landfills, causing environmental pollution. In addition, the companies linked to this item allocate large sums of money to depositing the shells in authorized landfills. In South America, Chile is one of the leading producers worldwide of scallop shell (Argopecten purpuratus) waste, creating a growing environmental and financial problem in the country, especially considering that there has yet to be progress in the development of new technologies that may reuse this waste in Chile. This study used different techniques to completely characterize the northern Chile scallop shell waste’s physical and chemical properties for the first time. The XRD result corresponded with calcite crystal structures (CaCO3), and the XFR showed 97.68% purity. Three particle sizes were obtained: BS (595–100 µm), MS (250–595 µm), and SS (<250 µm). In addition, the potential use of these wastes to remove contaminants present in water from the wine industry (caffeic acid) and some drinking water (arsenic(III)) was evaluated. The powder with the smallest particle size (SS), which has a surface area of 1 m2/g, 0.0050 m3/g of pore volume and pore diameter of 18.0 nm, removed 100.0% of CA and 23.0% As(III) in a pH condition of 4.6. The results show that scallop shell waste can be used to treat water and reinforce polymeric matrix composite materials to improve mechanical properties.
Recently, bismuth oxyiodide (BiOI) is an attractive semiconductor to use in heterogeneous photocatalysis processes. Unfortunately, BiOI individually shows limited photocatalytic efficiency, instability, and a quick recombination of electron/holes. Considering the practical application of this semiconductor, some studies show that synthetic zeolites provide good support for this photocatalyst. This support material permits a better photocatalytic efficiency because it prevents the quick recombination of photogenerated pairs. However, the optimal conditions (time and temperature) to obtain composites (BiOI/ synthetic zeolite) with high photocatalytic efficiency using a coprecipitation-solvothermal growth method have not yet been reported. In this study, a response surface methodology (RSM) based on a central composite design (CCD) was applied to optimize the synthesis conditions of BiOI/mordenite composites. For this purpose, eleven BiOI/mordenite composites were synthesized using a combined coprecipitation-solvothermal method under different time and temperature conditions. The photocatalytic activities of the synthesized composites were evaluated after 20 min of photocatalytic oxidation of caffeic acid, a typical organic pollutant found in agro-industrial wastewater. Moreover, BiOI/mordenite composites with the highest and lowest photocatalytic activity were physically and chemically characterized using nitrogen adsorption isotherms, scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and diffuse reflectance spectroscopy (DRS). The optimal synthesis conditions prove to be 187 °C and 9 h. In addition, the changes applied to the experimental conditions led to surface property modifications that influenced the photocatalytic degradation efficiency of the BiOI/mordenite composite toward caffeic acid photodegradation.