Significance: Clean groundwater is essential for water supply in many regions of the world. Fast flow to the groundwater through enlarged cracks and fissures, which is known to transmit short-lived pollutants into the groundwater, is often neglected in large-scale studies. We quantify the rapid transport of pollutants by fast flow into the carbonate rock groundwater storage in Europe, North Africa, and the Middle East. We show that, through rapid transport, up to 50% of infiltrating pollutants may still reach the groundwater table, which is substantially more than estimated when fast transport is neglected. These results imply that the contamination risk of usable groundwater storages is much larger than expected where fast flow to the groundwater occurs.

Springs play a key role in the hydrology of mountain catchments and their water supply has a considerable impact on regional livelihood, biodiversity, tourism, and power generation. However, there is still limited knowledge of how rain and snow contribute to the recharge of Alpine springs. This study presents a four-year investigation of stable isotopes in precipitation and spring water at the scale of a 240 km² wide dolomitic massif (Dolomites, Italian Alps) with the aim of determining the proportions of snowmelt and rain in spring water and to provide insights on the variability of these contributions in space and time. Four precipitation sampling devices were installed along a strong elevation gradient (from 725 to 2660 m a.s.l.) and nine major springs were monitored seasonally. The monitoring period comprised three extreme weather conditions, i.e., an exceptional snowpack melting period following the highest snowfall in 30 years, an intense precipitation event (386.4 mm of rain in 48 h), and one of the driest periods ever observed in the region. Isotope-based mixing analysis revealed that rain and snowmelt contributions to spring water were noticeably variable, with two main recharge time windows: a late spring–summer snowmelt recharge period with an average snowmelt fraction in spring water up to 94 ± 9%, and a late autumn–early winter period with a rain fraction in spring water up to 68 ± 17%. Overall, during the monitoring period, snowmelt produced high-flow conditions and sustained baseflow more than rain. We argue that the seasonal variability of the snowmelt and rain fractions during the monitoring period reflects the relatively rapid and climate-dependent storage processes occurring in the aquifer. Our results also showed that snowmelt fractions in spring water vary in space around the mountain group as a function of the elevation of their recharge areas. High-altitude recharge areas, above 2500 m a.s.l., are characterized by a predominance of the snowmelt fraction (72% ± 29%) over the rain contribution. Recharge altitudes of approximately 2400 m a.s.l. also show a snow predominance (65 ± 31%), while springs recharged below 2000 m a.s.l. are recharged mostly from rain (snowmelt fraction of 46 ± 26%). Results from this study may be used to develop more accurate water management strategies in mountain catchments and to cope with future climate-change predictions that indicate a decline in the snow volume and duration in Alpine regions.

A 1:50,000 hydrogeological map of the Pale di San Martino Mountains (Northern Italy) was created. The map presents the merge of various pre-existing data with new field data collected between the years 2014 and 2016. Through the use of symbols and specific colours, the map shows various groundwater-related data such as the hydrogeological complexes, the location and size of the main springs, the extension of the recharge areas, the hydrogeological boundaries, as well as information on groundwater usage. Given the absence of hydrogeological maps in the entire mountain range of the Dolomites, the approach followed in this study could be used as a guide for future representations in this alpine region. At the local scale, the map could serve as a conceptual base for future research involving groundwater and for water management planning.

Extreme precipitation events are expected to increase in intensity in Alpine regions due to climate change. While many studies have analyzed the impact of these phenomena on flooding risk, very few deal with their effect on groundwater. This work analyzes the hydrograph response of three springs to an extreme storm, which occurred in Northern Italy in October 2018. We observed that the newly infiltrated storm water contributed to feeding the winter baseflow, increasing its volume up to 85 % compared to normal conditions. It was also found that the response of groundwater to heavy precipitation seems to be influenced by the type of media. A high-altitude spring belonging to the fractured carbonate aquifer shows a quick response to the storm input, while springs outflowing at the base of the mountain slopes (mixed fractured carbonate and porous deposits) exhibit a delayed response. Results are important when analyzing future water availability and to better understand the impact of extreme events on groundwater flow.

Water resources from high-alpine karst aquifers are used for drinking, hydropower generation and artificial snowmaking. Therefore, understanding of their storage and flow dynamics is crucial for a sustainable water management. However, high-alpine karst areas are characterized by a great geological complexity due to the presence of mountain block fractured and karst aquifers interdigitating with the heterogeneous valley floor porous aquifers. For that reason, hydrogeological characterization and model prediction remains a big challenge. In this work, we investigated a geologically complex alpine catchment in the Dolomites (Italian Alps) by using experimental data and a reservoir numerical model to simulate three years of stream discharge. The structure of the model is based on experimental knowledge of the catchment and on previous studies and investigations. It (1) includes snow dynamics and accounts for hydrogeological heterogeneities, (2) separately considers karstic conduit and matrix flow in a dolomitic aquifer and flow through the porous deposits accumulating on the slopes and at the valley floor in an unconsolidated aquifer (non-karst), and (3) takes into account the groundwater transfer between the two aquifers. In the frame of a multi-step model evaluation, we used a Regional Sensitivity Analysis with three performance measures including observations of catchment discharge, karst spring discharge and unconsolidated aquifer spring discharge to assess the realism of model simulations. We show that the newly developed model reliably reproduces the hydrogeological variability of the catchment, even during strongly different hydroclimatic conditions. Analyzing its simulated storage dynamics, we can show that despite its moderate storage, the porous aquifer contributes most to catchment discharge, while the largest storage of the system is the matrix of the dolomite aquifer that recharges the unconsolidated aquifer together with discharge from the karstic conduits. A clear seasonality of groundwater storage in the karst matrix and of unconsolidated aquifer discharge indicates a strong sensitivity of this complex aquifer system to climatic variability.