The potential energy of compressed air represents a multi-application source of power. Historically employed to drive certain manufacturing or transportation systems, it became a source of vehicle propulsion in the late 19th century. During the second half of the 20th century, significant efforts were directed towards harnessing pressurized air for the storage of electrical energy. Today’s systems, which are based on storing the air at a high pressure, are usually recognized as compressed air energy storage (CAES) installations. This paper aims to provide an overview of different technologies that take advantage of the energy accumulated in the compressed air. Particular attention is paid to the CAES installations that are working as electrical energy storage systems (EESs). These systems, developed originally as large capacity (>100 MW_e) and fuel-based installations, may soon become fully scalable, highly efficient, and fuel-free electrical energy storage systems. To present this opportunity, a thorough review encompassing previous and up-to-date advancements in their development was carried out. In particular, CAES concepts, such as diabatic (D-CAES), adiabatic (A-CAES), and isothermal (I-CAES), are described in detail. This review also provides the detailed characteristics of the crucial elements of these configurations, including compressors, expanders, air storage chambers, and thermal storage tanks. Knowledge of these components and their role allows us to understand the main challenges behind the further development of the mentioned CAES setups. Apart from the CAES systems that are designed as EES systems, this paper describes other prospective technologies that utilize the energy of pressurized air. Accordingly, compressed air cars and their key elements are explained in detail. Moreover, the technology renowned as wave-driven compressed air energy storage (W-CAES) is described as well, indicating that the utilization of pressurized air represents a viable option for converting ocean energy into electrical power.

The energy sector is nowadays facing new challenges, mainly in the form of a massive shifting towards renewable energy sources as an alternative to fossil fuels and a diffusion of the distributed generation paradigm, which involves the application of small-scale energy generation systems. In this scenario, systems adopting one or more renewable energy sources and capable of producing several forms of energy along with some useful substances, such as fresh water and hydrogen, are a particularly interesting solution. A hybrid polygeneration system based on renewable energy sources can overcome operation problems regarding energy systems where only one energy source is used (solar, wind, biomass) and allows one to use an all-in-one integrated systems in order to match the different loads of a utility. From the point of view of scientific literature, medium- and large-scale systems are the most investigated; nevertheless, more and more attention has also started to be given to small-scale layouts and applications. The growing diffusion of distributed generation applications along with the interest in multipurpose energy systems based on renewables and capable of matching different energy demands create the necessity of developing an overview on the topic of small-scale hybrid and polygeneration systems. Therefore, this paper provides a comprehensive review of the technology, operation, performance, and economical aspects of hybrid and polygeneration renewable energy systems in small-scale applications. In particular, the review presents the technologies used for energy generation from renewables and the ones that may be adopted for energy storage. A significant focus is also given to the adoption of renewable energy sources in hybrid and polygeneration systems, designs/modeling approaches and tools, and main methodologies of assessment. The review shows that investigations on the proposed topic have significant potential for expansion from the point of view of system configuration, hybridization, and applications.

Island energy systems are becoming an important part of energy transformation due to the growing needs for the penetration of renewable energy. Among the possible systems, a combination of different energy generation technologies is a viable option for local users, as long as energy storage is implemented. The presented paper describes an energy-economic assessment of an island system with a photovoltaic field, small wind turbine, wood chip gasifier, battery, and hydrogen circuit with electrolyzer and fuel cell. The system is designed to satisfy the electrical energy demand of a tourist facility in two European localizations. The operation of the system is developed and dynamically simulated in the Transient System Simulation (TRNSYS) environment, taking into account realistic user demand. The results show that in Gdansk, Poland, it is possible to satisfy 99% of user demand with renewable energy sources with excess energy equal to 31%, while in Agkistro, Greece, a similar result is possible with 43% of excess energy. Despite the high initial costs, it is possible to obtain Simple Pay Back periods of 12.5 and 22.5 years for Gdansk and Agkistro, respectively. This result points out that under a high share of renewables in the energy demand of the user, the profitability of the system is highly affected by the local cost of energy vectors. The achieved results show that the system is robust in providing energy to the users and that future development may lead to an operation based fully on renewables.