Within integrated steelmaking industries significant research efforts are devoted to the efficient use of resources and the reduction of CO₂ emissions. Integrated steelworks consume a considerable quantity of raw materials and produce a high amount of by-products, such as off-gases, currently used for the internal production of heat, steam or electricity. These off-gases can be further valorized as feedstock for methane and methanol syntheses, but their hydrogen content is often inadequate to reach high conversions in synthesis processes. The addition of hydrogen is fundamental and a suitable hydrogen production process must be selected to obtain advantages in process economy and sustainability. This paper presents a comparative analysis of different hydrogen production processes from renewable energy, namely polymer electrolyte membrane electrolysis, solid oxide electrolyze cell electrolysis, and biomass gasification. Aspen Plus^® V11-based models were developed, and simulations were conducted for sensitivity analyses to acquire useful information related to the process behavior. Advantages and disadvantages for each considered process were highlighted. In addition, the integration of the analyzed hydrogen production methods with methane and methanol syntheses is analyzed through further Aspen Plus^®-based simulations. The pros and cons of the different hydrogen production options coupled with methane and methanol syntheses included in steelmaking industries are analyzed.

The steel industry is among the highest carbon-emitting industrial sectors. Since the steel production process is already exhaustively optimized, alternative routes are sought in order to increase carbon efficiency and reduce these emissions. During steel production, three main carbon-containing off-gases are generated: blast furnace gas, coke oven gas and basic oxygen furnace gas. In the present work, the addition of renewable hydrogen by electrolysis to those steelworks off-gases is studied for the production of methane and methanol. Different case scenarios are investigated using AspenPlus^TM flowsheet simulations, which differ on the end-product, the feedstock flowrates and on the production of power. Each case study is evaluated in terms of hydrogen and electrolysis requirements, carbon conversion, hydrogen consumption, and product yields. The findings of this study showed that the electrolysis requirements surpass the energy content of the steelwork’s feedstock. However, for the methanol synthesis cases, substantial improvements can be achieved if recycling a significant amount of the residual hydrogen.

Island energy systems are becoming an important part of energy transformation due to the growing needs for the penetration of renewable energy. Among the possible systems, a combination of different energy generation technologies is a viable option for local users, as long as energy storage is implemented. The presented paper describes an energy-economic assessment of an island system with a photovoltaic field, small wind turbine, wood chip gasifier, battery, and hydrogen circuit with electrolyzer and fuel cell. The system is designed to satisfy the electrical energy demand of a tourist facility in two European localizations. The operation of the system is developed and dynamically simulated in the Transient System Simulation (TRNSYS) environment, taking into account realistic user demand. The results show that in Gdansk, Poland, it is possible to satisfy 99% of user demand with renewable energy sources with excess energy equal to 31%, while in Agkistro, Greece, a similar result is possible with 43% of excess energy. Despite the high initial costs, it is possible to obtain Simple Pay Back periods of 12.5 and 22.5 years for Gdansk and Agkistro, respectively. This result points out that under a high share of renewables in the energy demand of the user, the profitability of the system is highly affected by the local cost of energy vectors. The achieved results show that the system is robust in providing energy to the users and that future development may lead to an operation based fully on renewables.