Among microporous storage materials copper benzene-1,3,5-tricarboxylate (CuBTC MOF, Cu₃(BTC)₂ or HKUST-1) holds the greatest potential for clean energy gases. However, its usefulness is challenged by water vapor, either in the gas to be stored or in the environment. To determine the protection potential of graphene oxide (GO) HKUST-1@GO composites containing 0–25% GO were synthesized and studied. In the highest concentration, GO was found to strongly affect HKUST-1 crystal growth in solvothermal conditions by increasing the pH of the reaction mixture. Otherwise, the GO content had practically no influence on the H₂, CH₄ and CO₂ storage capacities, which were very similar to those from the findings of other groups. The water vapor resistance of a selected composite was compared to that of HKUST-1. Powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermogravimetric (TG/DTG) and N₂ adsorption techniques were used to monitor the changes in the crystal and pore structure. It was found that GO saves the copper–carboxyl coordination bonds by sacrificing the ester groups, formed during the solvothermal synthesis, between ethanol and the carboxyl groups on the GO sheets.

The adsorption technique is widely used in water purification, and its efficiency can be significantly improved by target-specific adsorbent design. Research on iodine and its ion removal from water has attracted a great deal of interest due to increased concentrations in the environment and acute toxic effects, e.g., in human thyroid cells. In this work, the iodide removal performance of two high-surface-area resorcinol–formaldehyde-based carbon aerogels was studied under acidic conditions. The BET surface area was 790 m²/g (RF_ac) and 375 m²/g (RMF-GO), with a corresponding micropore ratio of 36 and 26%, respectively. Both aerogels showed outstanding adsorption capacity, exceeding the reported performance of other carbons and Ag-doped materials. Owing to its basic nature, the RMF-GO carbon aerogel showed higher I⁻ capacity, up to 97 mg/g, than the acidic RF_ac, which reached a capacity of 82 mg/g. The surface chemistry of the aerogels also played a distinct role in the removal. In terms of kinetics, RF_ac removed 60% of the iodide ions and RMF-GO 30% within 8 h. The removal kinetics was of the first order, with a half-life of 1.94 and 1.70 h, respectively.