The rate of bitumen extraction in northeastern Alberta, Canada, is outpacing the state of ecological understanding of the region, so that the extent of potential disturbances caused by atmospheric deposition remains largely unknown. Atmospheric SO2 emissions from the Fort McMurray region of Alberta (∼300 t·day–1) constitute ∼5% of the Canadian total. Combined with an estimated NOx production of ∼300 t·day–1, these emissions have the potential to acidify surface waters. Diatom assemblages in dated sediment cores from eight acid-sensitive lakes were analyzed to assess the effects of acidifying emissions on boreal lake ecosystems. There is no evidence that these lakes have become acidified. Instead, many of the lakes show characteristic changes towards greater productivity and occasionally greater alkalinity. The absence of evidence for acidification does not imply that emissions from the Oil Sands are environmentally benign, but rather suggests that the biogeochemistry of these lakes differs fundamentally from well-studied acidified counterparts in northern Europe and eastern North America. Complex interactions involving in-lake alkalinity production, internal nutrient loading, and climate change appear to be driving these lakes towards the new ecological states reported.
Diesel fuel is known to emit pollutants that have a negative impact on environmental and human health. In developing countries like South Africa, attendants are employed to pump fuel for customers at service stations. Attendants refuel vehicles with various octane unleaded fuel, lead-replacement petrol and diesel fuel, on a daily basis. Attendants are at risk to adverse health effects associated with the inhalation of volatile organic compounds released from these fuels. The pollutants released include benzene, toluene, ethylbenzene and xylenes (BTEX), which are significant due to their high level of toxicity. In this study, a risk assessment of BTEX was conducted at a diesel service station for public buses. Using Radiello passive samplers, it was found that benzene concentrations were above recommended international standards. Due to poor ventilation and high exposure duration, the average benzene concentration over the sampling campaign exceeded the US Environmental Protection Agency’s chronic inhalation exposure reference concentration. Lifetime cancer risk estimation showed that on average there is a 3.78 × 10−4 cancer risk, corresponding to an average chronic daily intake of 1.38 × 10−3 mg/kg/day of benzene exposure. Additionally, there were incidences where individuals were at potential hazard risk of benzene and toluene that may pose non-carcinogenic effects to employees.