Increasing the energy efficiency of residential and non-residential buildings is a crucial point towards the development of the sustainable cities of the future. To reach such a goal, the commonly employed intervention measures (for instance, on facades and glass) are not sufficient and efforts in reaching a fully renewable energy generation are mandatory. In this context, this paper discusses the applicability of a system with solar and biomass as the main energy sources in different climates for heating, cooling, domestic hot water and electricity generation in office buildings. The energy system includes solar thermal collectors with thermoelectric generators, a biomass boiler, a reversible heat pump/organic Rankine cycle and an adsorption chiller. The results showed that the system can operate with a share of renewables higher than 70% for all energy needs, with up to 80% of the overall energy demand supplied only by solar and biomass sources even in the northern locations.

The present work focuses on the techno-economic assessment and multi-objective genetic algorithm optimization of small-scale (40 kW_th input), solar Organic Rankine Cycle (ORC) systems driven by medium-to-high temperature (up to 210 °C) parabolic dish (PDC) and trough (PTC) collectors. The ORCs are designed to maximize their nominal thermal efficiency for several natural hydrocarbon working fluids. The optimization variables are the solar field area and storage tank capacity, with the goal of minimizing the levelized cost of produced electricity (LCoE) and maximizing the annual solar conversion efficiency. The lowest LCOE (0.34 €/kWh) was obtained in Athens for a high solar field area and low storage tank capacity. Meanwhile, the maximum annual solar conversion efficiencies (10.5–11%) were obtained in northern cities (e.g., Brussels) at lower solar field locations. While PTCs and PDCs result in similar efficiencies, the use of PTCs is more cost-effective. Among the working fluids, Cyclopentane and Cyclohexane exhibited the best performance, owing to their high critical temperatures. Notably, the systems could be more profitable at higher system sizes, as indicated by the 6% LCoE decrease of the solar ORC in Athens when the nominal heat input was increased to 80 kW_th.

In order to reduce the dependence on fossil fuels in the residential sector, low-carbon-footprint technologies such as heat pumps should be used. To fully exploit solar-assisted heat pumps, an effective control strategy is required. This study employs a low-global-warming-potential (GWP) refrigerant for a water-to-water reversible heat pump, which is assisted by a thermal energy storage tank, photovoltaic (PV) installation, and battery storage system using a dedicated control strategy. The heat pump’s operation is validated against the experimental data. Simulations are carried out for three different climates to analyze the performance of reversible heat pumps across Europe. The reversible heat pump fully meets the summer cooling demand in all three climates, while the heating demand is covered with the help of a backup source. An economic analysis is carried out for three different PV sizes and the results are compared with the reference energy systems. The inclusion of a battery storage system results in high payback times but increases overall flexibility and self-sufficiency.

Ejector-based cooling systems have gathered scientific interest as a low-cost alternative for solar-assisted cooling applications, especially in regions with solar abundance. This work presents the experimental investigation of a solar ejector cooling prototype system. The system, developed at the National Technical University of Athens, includes a custom-made ejector and is powered by a 48 m² flat plate solar collector field, assisted by an auxiliary natural gas boiler. Experimental testing under varying operating conditions was conducted to assess the system’s performance, focusing on the influence of evaporation and condensation temperatures. The maximum coefficient of performance (COP) was measured at approximately 0.160–0.165, corresponding to an entrainment ratio of 0.19 at an evaporation temperature of 9 °C and condensation temperatures of 26–27 °C. Ejector performance substantially declined with increased condensation temperatures. However, the influence of the evaporator pressure on system performance was less significant. These findings demonstrate the feasibility of ejector-based solar cooling as a sustainable solution for reducing electricity use in cooling applications, highlighting the critical influence of operating parameters in the system’s performance optimization.