Agriculture has significantly aided in meeting the food needs of growing population. In addition, it has boosted economic development in irrigated regions. In this study, an assessment of the groundwater (GW) quality for agricultural land was carried out in El Kharga Oasis, Western Desert of Egypt. Several irrigation water quality indices (IWQIs) and geographic information systems (GIS) were used for the modeling development. Two machine learning (ML) models (i.e., adaptive neuro-fuzzy inference system (ANFIS) and support vector machine (SVM)) were developed for the prediction of eight IWQIs, including the irrigation water quality index (IWQI), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), potential salinity (PS), residual sodium carbonate index (RSC), and Kelley index (KI). The physicochemical parameters included T°, pH, EC, TDS, K⁺, Na⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻, HCO₃⁻, CO₃²⁻, and NO₃⁻, and they were measured in 140 GW wells. The hydrochemical facies of the GW resources were of Ca-Mg-SO₄, mixed Ca-Mg-Cl-SO₄, Na-Cl, Ca-Mg-HCO₃, and mixed Na-Ca-HCO₃ types, which revealed silicate weathering, dissolution of gypsum/calcite/dolomite/ halite, rock–water interactions, and reverse ion exchange processes. The IWQI, SAR, KI, and PS showed that the majority of the GW samples were categorized for irrigation purposes into no restriction (67.85%), excellent (100%), good (57.85%), and excellent to good (65.71%), respectively. Moreover, the majority of the selected samples were categorized as excellent to good and safe for irrigation according to the SSP and RSC. The performance of the simulation models was evaluated based on several prediction skills criteria, which revealed that the ANFIS model and SVM model were capable of simulating the IWQIs with reasonable accuracy for both training “determination coefficient (R²)” (R² = 0.99 and 0.97) and testing (R² = 0.97 and 0.76). The presented models’ promising accuracy illustrates their potential for use in IWQI prediction. The findings indicate the potential for ML methods of geographically dispersed hydrogeochemical data, such as ANFIS and SVM, to be used for assessing the GW quality for irrigation. The proposed methodological approach offers a useful tool for identifying the crucial hydrogeochemical components for GW evolution assessment and mitigation measures related to GW management in arid and semi-arid environments.

In order to evaluate and project the quality of groundwater utilized for irrigation in the Sahara aquifer in Algeria, this research employed irrigation water quality indices (IWQIs), artificial neural network (ANN) models, and Gradient Boosting Regression (GBR), alongside multivariate statistical analysis and a geographic information system (GIS), to assess and forecast the quality of groundwater used for irrigation in the Sahara aquifer in Algeria. Twenty-seven groundwater samples were examined using conventional analytical methods. The obtained physicochemical parameters for the collected groundwater samples showed that Ca²⁺ > Mg²⁺ > Na⁺ > K⁺, and Cl⁻ > SO₄²⁻ > HCO₃⁻ > NO₃⁻, owing to the predominance of limestone, sandstone, and clay minerals under the effects of human activity, ion dissolution, rock weathering, and exchange processes, which indicate a Ca-Cl water type. For evaluating the quality of irrigation water, the IWQIs values such as irrigation water quality index (IWQI), sodium adsorption ratio (SAR), Kelly index (KI), sodium percentage (Na%), permeability index (PI), and magnesium hazard (MH) showed mean values of 47.17, 1.88, 0.25, 19.96, 41.18, and 27.87, respectively. For instance, the IWQI values revealed that 33% of samples were severely restricted for irrigation, while 67% of samples varied from moderate to high restriction for irrigation, indicating that crops that are moderately to highly hypersensitive to salt should be watered in soft soils without any compressed layers. Two-machine learning models were applied, i.e., the ANN and GBR for IWQI, and the ANN model, which surpassed the GBR model. The findings showed that ANN-2F had the highest correlation between IWQI and exceptional features, making it the most accurate prediction model. For example, this model has two qualities that are critical for the IWQI prediction. The outputs’ R² values for the training and validation sets are 0.973 (RMSE = 2.492) and 0.958 (RMSE = 2.175), respectively. Finally, the application of physicochemical parameters and water quality indices supported by GIS methods, machine learning, and multivariate modeling is a useful and practical strategy for evaluating the quality and development of groundwater.

Water shortage and quality are major issues in many places, particularly arid and semi-arid regions such as Makkah Al-Mukarramah province, Saudi Arabia. The current work was conducted to examine the geochemical mechanisms influencing the chemistry of groundwater and assess groundwater resources through several water quality indices (WQIs), GIS methods, and the partial least squares regression model (PLSR). For that, 59 groundwater wells were tested for different physical and chemical parameters using conventional analytical procedures. The results showed that the average content of ions was as follows: Na⁺ > Ca²⁺ > Mg ²⁺ > K⁺ and Cl⁻ > SO₄²⁻ > HCO₃²⁻ > NO₃⁻ > CO₃⁻. Under the stress of evaporation and saltwater intrusion associated with the reverse ion exchange process, the predominant hydrochemical facies were Ca-HCO₃, Na-Cl, mixed Ca-Mg-Cl-SO₄, and Na-Ca-HCO₃. The drinking water quality index (DWQI) has indicated that only 5% of the wells were categorized under good to excellent for drinking while the majority (95%) were poor to unsuitable for drinking, and required appropriate treatment. Furthermore, the irrigation water quality index (IWQI) has indicated that 45.5% of the wells were classified under high to severe restriction for agriculture, and can be utilized only for high salt tolerant plants. The majority (54.5%) were deemed moderate to no restriction for irrigation, with no toxicity concern for most plants. Agriculture indicators such as total dissolved solids (TDS), potential salinity (PS), sodium absorption ratio (SAR), and residual sodium carbonate (RSC) had mean values of 2572.30, 33.32, 4.84, and −21.14, respectively. However, the quality of the groundwater in the study area improves with increased rainfall and thus recharging the Quaternary aquifer. The PLSR models, which are based on physicochemical characteristics, have been shown to be the most efficient as alternative techniques for determining the six WQIs. For instance, the PLSR models of all IWQs had determination coefficients values of R² ranging between 0.848 and 0.999 in the Cal., and between 0.848 and 0.999 in the Val. datasets, and had model accuracy varying from 0.824 to 0.999 in the Cal., and from 0.817 to 0.989 in the Val. datasets. In conclusion, the combination of physicochemical parameters, WQIs, and multivariate modeling with statistical analysis and GIS tools is a successful and adaptable methodology that provides a comprehensive picture of groundwater quality and governing mechanisms.

Water quality has deteriorated in recent years as a result of rising population and unplanned development, impacting ecosystem health. The water quality parameters of Qaroun Lake are contaminated to varying degrees, particularly for aquatic life consumption. For that, the objective of this work is to improve the assessments of surface water quality and to determine the different geo-environmental parameters affecting the lake environmental system in Qaroun Lake utilizing the weighted arithmetic water quality index (WAWQI) and four pollution indices (heavy metal pollution index (HPI), metal index (MI), contamination index (C_d), and pollution index (PI), that are enhanced by multivariate analyses as cluster analysis (CA), principal component analysis (PCA), and support vector machine regression (SVMR). Surface water samples were collected at 16 different locations from the lake during years 2018 and 2019. Thirteen physiochemical parameters were measured and used to calculate water quality indices (WQIs). The WQIs of Qaroun Lake such WAWQI, HPI, MI, C_d, PI revealed a different degree of contamination, with respect to aquatic life utilization. The WQIs result revealed that surface water in the lake is unsuitable, high polluted, and seriously affected by pollution for an aquatic environment. The PI findings revealed that surface water samples of Qaroun Lake were significantly impacted by Al, moderately affected by Cd and Cu, and while slightly affected by Zn due to uncontrolled releases of domestic and industrial wastewater. Furthermore, increasing salinity accelerates the deterioration of the lake aquatic environment. Therefore, sewage and drainage wastewater should be treated before discharging into the lake. The SVMR models based on physiochemical parameters presented the highest performance as an alternative method to predict the WQIs. For example, the calibration (Val.) and the validation (Val.) models performed best in assessing the WQIs with R² (0.99) and with R² (0.97–0.99), respectively. Finally, a combination of WQIs, CA, PCA, and SVMR approaches could be employed to assess surface water quality in Qaroun Lake.