Agriculture has significantly aided in meeting the food needs of growing population. In addition, it has boosted economic development in irrigated regions. In this study, an assessment of the groundwater (GW) quality for agricultural land was carried out in El Kharga Oasis, Western Desert of Egypt. Several irrigation water quality indices (IWQIs) and geographic information systems (GIS) were used for the modeling development. Two machine learning (ML) models (i.e., adaptive neuro-fuzzy inference system (ANFIS) and support vector machine (SVM)) were developed for the prediction of eight IWQIs, including the irrigation water quality index (IWQI), sodium adsorption ratio (SAR), soluble sodium percentage (SSP), potential salinity (PS), residual sodium carbonate index (RSC), and Kelley index (KI). The physicochemical parameters included T°, pH, EC, TDS, K⁺, Na⁺, Mg²⁺, Ca²⁺, Cl⁻, SO₄²⁻, HCO₃⁻, CO₃²⁻, and NO₃⁻, and they were measured in 140 GW wells. The hydrochemical facies of the GW resources were of Ca-Mg-SO₄, mixed Ca-Mg-Cl-SO₄, Na-Cl, Ca-Mg-HCO₃, and mixed Na-Ca-HCO₃ types, which revealed silicate weathering, dissolution of gypsum/calcite/dolomite/ halite, rock–water interactions, and reverse ion exchange processes. The IWQI, SAR, KI, and PS showed that the majority of the GW samples were categorized for irrigation purposes into no restriction (67.85%), excellent (100%), good (57.85%), and excellent to good (65.71%), respectively. Moreover, the majority of the selected samples were categorized as excellent to good and safe for irrigation according to the SSP and RSC. The performance of the simulation models was evaluated based on several prediction skills criteria, which revealed that the ANFIS model and SVM model were capable of simulating the IWQIs with reasonable accuracy for both training “determination coefficient (R²)” (R² = 0.99 and 0.97) and testing (R² = 0.97 and 0.76). The presented models’ promising accuracy illustrates their potential for use in IWQI prediction. The findings indicate the potential for ML methods of geographically dispersed hydrogeochemical data, such as ANFIS and SVM, to be used for assessing the GW quality for irrigation. The proposed methodological approach offers a useful tool for identifying the crucial hydrogeochemical components for GW evolution assessment and mitigation measures related to GW management in arid and semi-arid environments.

In order to evaluate and project the quality of groundwater utilized for irrigation in the Sahara aquifer in Algeria, this research employed irrigation water quality indices (IWQIs), artificial neural network (ANN) models, and Gradient Boosting Regression (GBR), alongside multivariate statistical analysis and a geographic information system (GIS), to assess and forecast the quality of groundwater used for irrigation in the Sahara aquifer in Algeria. Twenty-seven groundwater samples were examined using conventional analytical methods. The obtained physicochemical parameters for the collected groundwater samples showed that Ca²⁺ > Mg²⁺ > Na⁺ > K⁺, and Cl⁻ > SO₄²⁻ > HCO₃⁻ > NO₃⁻, owing to the predominance of limestone, sandstone, and clay minerals under the effects of human activity, ion dissolution, rock weathering, and exchange processes, which indicate a Ca-Cl water type. For evaluating the quality of irrigation water, the IWQIs values such as irrigation water quality index (IWQI), sodium adsorption ratio (SAR), Kelly index (KI), sodium percentage (Na%), permeability index (PI), and magnesium hazard (MH) showed mean values of 47.17, 1.88, 0.25, 19.96, 41.18, and 27.87, respectively. For instance, the IWQI values revealed that 33% of samples were severely restricted for irrigation, while 67% of samples varied from moderate to high restriction for irrigation, indicating that crops that are moderately to highly hypersensitive to salt should be watered in soft soils without any compressed layers. Two-machine learning models were applied, i.e., the ANN and GBR for IWQI, and the ANN model, which surpassed the GBR model. The findings showed that ANN-2F had the highest correlation between IWQI and exceptional features, making it the most accurate prediction model. For example, this model has two qualities that are critical for the IWQI prediction. The outputs’ R² values for the training and validation sets are 0.973 (RMSE = 2.492) and 0.958 (RMSE = 2.175), respectively. Finally, the application of physicochemical parameters and water quality indices supported by GIS methods, machine learning, and multivariate modeling is a useful and practical strategy for evaluating the quality and development of groundwater.

The assessment and prediction of water quality are important aspects of water resource management. Therefore, the groundwater (GW) quality of the Nubian Sandstone Aquifer (NSSA) in El Kharga Oasis was evaluated using indexing approaches, such as the drinking water quality index (DWQI) and health index (HI), supported with multivariate analysis, artificial neural network (ANN) models, and geographic information system (GIS) techniques. For this, physical and chemical parameters were measured for 140 GW wells, which indicated Ca–Mg–SO₄, mixed Ca–Mg–Cl–SO₄, Na–Cl, Ca–Mg–HCO₃, and mixed Na–Ca–HCO₃ water facies under the influence of silicate weathering, rock–water interactions, and ion exchange processes. The GW in El Kharga Oasis had high levels of heavy metals, particularly iron (Fe) and manganese (Mn), with average concentrations above the limits recommended by the World Health Organization (WHO) for drinking water. The DWQI categorized most of the samples as not suitable for drinking (poor to very poor class), while some samples fell in the good water class. The results of the HI indicated a potential health risk due to the ingestion of water, with the risk being higher for children in only one location. However, for both children and adults, there was a low risk of dermal and ingestion exposure to the water in all locations. The contaminants could be from natural sources, such as minerals leaching from rocks and soil, or from human activities. Based on the results of ANN modeling, ANN-SC-13 was the most accurate prediction model, since it demonstrated the strongest correlation between the best characteristics and the DWQI. For example, this model’s thirteen characteristics were extremely important for predicting DWQI. The R² value for the training, cross-validation (CV), and test data was 0.99. The ANN-SC-2 model was the best in measuring HI ingestion in adults. The R² value for the training, CV, and test data was 1.00 for all models. The ANN-SC-2 model was the most accurate at detecting HI dermal in adults (R² = 0.99, 0.99, and 0.99 for the training, CV, and test data sets, respectively). Finally, the integration of physicochemical parameters, water quality indices (WQIs), and ANN models can help us to understand the quality of GW and its controlling factors, and to implement the necessary measures that prevent outbreaks of various water-borne diseases that are detrimental to human health.

Monitoring and managing water quality parameters (WQPs) in water bodies (e.g., lakes) on a large scale using sampling-point techniques is tedious, laborious, and not highly representative. Hyperspectral and data-driven technology have provided a potentially valuable tool for the precise measurement of WQPs. Therefore, the objective of this work was to integrate WQPs, derived spectral reflectance indices (published spectral reflectance indices (PSRIs)), newly two-band spectral reflectance indices (NSRIs-2b) and newly three-band spectral indices (NSRIs-3b), and artificial neural networks (ANNs) for estimating WQPs in Lake Qaroun. Shipboard cruises were conducted to collect surface water samples at 16 different sites throughout Lake Qaroun throughout a two-year study (2018 and 2019). Different WQPs, such as total nitrogen (TN), ammonium (NH₄⁺), orthophosphate (PO₄³⁻), and chemical oxygen demand (COD), were evaluated for aquatic use. The results showed that the highest determination coefficients were recorded with the NSRIs-3b, followed by the NSRIs-2b, and then followed by the PSRIs, which produced lower R² with all tested WQPs. The majority of NSRIs-3bs demonstrated strong significant relationships with three WQPs (TN, NH₄⁺, and PO₄³⁻) with (R² = 0.70 to 0.77), and a moderate relationship with COD (R² = 0.52 to 0.64). The SRIs integrated with ANNs would be an efficient tool for estimating the investigated four WQPs in both calibration and validation datasets with acceptable accuracy. For examples, the five features of the SRIs involved in this model are of great significance for predicting TN. Its outputs showed high R² values of 0.92 and 0.84 for calibration and validation, respectively. The ANN-PO₄³⁻VI-17 was the highest accuracy model for predicting PO₄³⁻ with R² = 0.98 and 0.89 for calibration and validation, respectively. In conclusion, this research study demonstrated that NSRIs-3b, alongside a combined approach of ANNs models and SRIs, would be an effective tool for assessing WQPs of Lake Qaroun.

In the Zeroud basin, a diverse array of methodologies were employed to assess, simulate, and predict the quality of groundwater intended for irrigation. These methodologies included the irrigation water quality indices (IWQIs); intricate statistical analysis involving multiple variables, supported with GIS techniques; an artificial neural network (ANN) model; and an XGBoost regression model. Extensive physicochemical examinations were performed on groundwater samples to elucidate their compositional attributes. The results showed that the abundance order of ions was Na⁺ > Ca²⁺ > Mg²⁺ > K⁺ and SO₄²⁻ > HCO₃⁻ > Cl⁻. The groundwater facies reflected Ca-Mg-SO₄, Na-Cl, and mixed Ca-Mg-Cl/SO₄ water types. A cluster analysis (CA) and principal component analysis (PCA), along with ionic ratios, detected three different water characteristics. The mechanisms controlling water chemistry revealed water–rock interaction, dolomite dissolution, evaporation, and ion exchange. The assessment of groundwater quality for agriculture with respect IWQIs, such as the irrigation water quality index (IWQI), sodium adsorption ratio (SAR), sodium percentage (Na%), soluble sodium percentage (SSP), potential salinity (PS), and residual sodium carbonate (RSC), revealed that the domination of the water samples was valuable for agriculture. However, the IWQI and PS fell between high-to-severe restrictions and injurious-to-unsatisfactory. The ANN and XGBoost regression models showed robust results for predicting IWQIs. For example, ANN-HyC-9 emerged as the most precise forecasting framework according to its outcomes, as it showcased the most robust link between prime attributes and IWQI. The nine attributes of this model hold immense significance in IWQI prediction. The R² values for its training and testing data stood at 0.999 (RMSE = 0.375) and 0.823 (RMSE = 3.168), respectively. These findings indicate that XGB-HyC-3 emerged as the most accurate forecasting model, displaying a stronger connection between IWQI and its exceptional characteristics. When predicting IWQI, approximately three of the model’s attributes played a pivotal role. Notably, the model yielded R² values of 0.999 (RMSE = 0.001) and 0.913 (RMSE = 2.217) for the training and testing datasets, respectively. Overall, these results offer significant details for decision-makers in managing water quality and can support the long-term use of water resources.