Emerging 3D printing technologies are enabling the rapid fabrication of complex designs with favorable properties such as mechanically efficient lattices for biomedical applications. However, there is a lack of biocompatible materials suitable for printing complex lattices constructed from beam-based unit cells. Here, we investigate the design and mechanics of biocompatible lattices fabricated with cost-effective stereolithography. Mechanical testing experiments include material characterization, lattices rescaled with differing unit cell numbers, topology alterations, and hierarchy. Lattices were consistently printed with 5% to 10% lower porosity than intended. Elastic moduli for 70% porous body-centered cube topologies ranged from 360 MPa to 135 MPa, with lattices having decreased elastic moduli as unit cell number increased. Elastic moduli ranged from 101 MPa to 260 MPa based on unit cell topology, with increased elastic moduli when a greater proportion of beams were aligned with the loading direction. Hierarchy provided large pores for improved nutrient transport and minimally decreased lattice elastic moduli for a fabricated tissue scaffold lattice with 7.72 kN/mm stiffness that is suitable for bone fusion. Results demonstrate the mechanical feasibility of biocompatible stereolithography and provide a basis for future investigations of lattice building blocks for diverse 3D printed designs.

Energetic ionic liquids (EILs) have various industrial applications because they release chemically stored energy under certain conditions. They can avoid some environmental problems caused by traditionally used toxic fuels. EILs, which are environmentally friendly and safer, are emerging as an alternative source for hypergolic bipropellant fuels. This review focuses on the crucial thermophysical properties of the EILs. The properties of imidazolium and triazolium-based ionic liquids (ILs) are discussed here. The thermophysical properties addressed, such as glass transition temperature, viscosity, and thermal stability, are critical for designing EILs to meet the need for sustainable energy solutions. Imidazolium-based ILs have tunable physical properties making them ideal for use in energy storage while triazolium-based ILs have thermal stability and energetic potential. As a result, it is important to understand and compile thermophysical properties so they can help researchers synthesize tailored compounds with desirable characteristics, advancing their application in energy storage and propulsion technologies.

The study delves into the kinetics of non-isothermal crystallization of Poly (ɛ-caprolactone) (PCL) and MgO-incorporated PCL nanofibers with varying cooling rates. Differential Scanning Calorimetry (DSC-3) was used to acquire crystallization information and investigate the kinetics behavior of the two types of nanofibers under different cooling rates ranging from 0.5–5 K/min. The results show that the crystallization rate decreases at higher crystallization temperatures. Furthermore, the parameters of non-isothermal crystallization kinetics were investigated via several mathematical models, including Jeziorny and Mo’s models. Mo’s approach was suitable to describe the nanofibers’ overall non-isothermal crystallization process. In addition, the Kissinger and Friedman methods were used to calculate the activation energy of bulk-PCL, PCL, and MgO-PCL nanofibers. The result showed that the activation energy of bulk-PCL was comparatively lower than that of nanofibers. The investigation of the kinetics of crystallization plays a crucial role in optimizing manufacturing processes and enhancing the overall performance of nanofibers.