Two eco-respectful, one-step synthetic routes for the preparation of a bio-based epoxy monomer derived from furan precursors are developed.

Thermosetting polymers have been widely used in many industrial applications as adhesives, coatings and laminated materials, among others. Recently, bisphenol A (BPA) has been banned as raw material for polymeric products, due to its harmful impact on human health. On the other hand, the use of aromatic amines as curing agents confers excellent thermal, mechanical and flame retardant properties to the final product, although they are toxic and subject to governmental restrictions. In this context, sugar-derived diepoxy monomers and anhydrides represent a sustainable greener alternative to BPA and aromatic amines. Herein, we report an “in-situ” sol–gel synthesis, using as precursors tetraethylorthosilicate (TEOS) and aminopropyl triethoxysilane (APTS) to obtain bio-based epoxy/silica composites; in a first step, the APTS was left to react with 2,5-bis[(oxyran-2-ylmethoxy)methyl]furan (BOMF) or diglycidyl ether of bisphenol A (DGEBA)monomers, and silica particles were generated in the epoxy in a second step; both systems were cured with methyl nadic anhydride (MNA). Morphological investigation of the composites through transmission electron microscopy (TEM) demonstrated that the hybrid strategy allows a very fine distribution of silica nanoparticles (at nanometric level) to be achieved within a hybrid network structure for both the diepoxy monomers. Concerning the fire behavior, as assessed in vertical flame spread tests, the use of anhydride curing agent prevented melt dripping phenomena and provided high char-forming character to the bio-based epoxy systems and their phenyl analog. In addition, forced combustion tests showed that the use of anhydride hardener instead of aliphatic polyamine results in a remarkable decrease of heat release rate. An overall decrease of the smoke parameters, which is highly desirable in a context of greater fire safety was observed in the case of BOMF/MNA system. The experimental results suggest that the effect of silica nanoparticles on fire behavior appears to be related to their dispersion degree.

The environmental concerns associated with synthetic polymers have intensified the search for sustainable and biodegradable alternatives, particularly for food packaging applications. Natural biopolymers offer promising solutions due to their biodegradability, reduced environmental impact, and reliance on renewable resources. Among these, agri-food waste and by-products have gained significant attention as valuable feedstocks for polymer production, supporting a circular economy approach. This review critically examines the current status of biopolymers derived from plant, animal, and microbial sources, focusing on their physical and chemical properties and their application in food packaging. The findings underscore that the properties of plant- and animal-based biopolymers are heavily influenced by the source material and extraction techniques, with successful examples in biodegradable films, coatings, and composite materials. However, a critical gap remains in the characterization of microbial biopolymers, as research in this area predominantly focuses on optimizing production processes rather than evaluating their material properties. Despite this limitation, microbial biopolymers have demonstrated considerable potential in composite films and fillers. By addressing these gaps and evaluating the key factors that influence the success of biopolymer-based packaging, we contribute to the ongoing efforts to develop sustainable food packaging solutions and reduce the environmental impact of plastic waste.