The numerical modeling of a copper zinc tin sulfide (CZTS)-based kesterite solar cell is described in detail in this article. To model FTO/ZnO/CdS/CZTS/MO structured solar cells, the Solar Cell Capacitance Simulator-one-dimension (SCAPS-1D) program was utilized. Numerical modeling was used to estimate and assess the parameters of various photovoltaic thin film solar cells. The impact of different parameters on solar cell performance and conversion efficiency were explored. Because the response of a solar cell is partly determined by its internal physical mechanism, J-V characteristic characteristics are insufficient to define a device’s behavior. Regardless of the conviction in solar cell modeling, variable attributes as well as many probable conditions must be handled for simulation. Promising optimized results were obtained with a conversion efficiency of ($\eta$% = 25.72%), a fill factor of (FF% = 83.75%), a short-circuit current of ($J_{SC }$ = 32.96436 mA/cm²), and an open-circuit voltage of ($V_{OC}$ = 0.64 V). The findings will aid in determining the feasibility of manufacturing high-efficiency CZTS-based solar cells. First, in the SCAPS-1D environment, the impacts of experimentally constructed CZTS solar cells were simulated. The experimental data was then compared to the simulated results from SCAPS-1D. After optimizing cell parameters, the conversion efficiency of the improved system was observed to rise. The influence of system factors, such as the thickness, acceptor, and donor carrier concentration densities of the absorber and electron transport layers, and the effect of temperature on the efficiency of CZTS-based photovoltaic cells, was explored using one-dimensional SCAPS-1D software. The suggested findings will be extremely useful to engineers and researchers in determining the best method for maximizing solar cell efficiency, as well as in the development of more efficient CZTS-based solar cells.

Cadmium telluride (CdTe), a metallic dichalcogenide material, was utilized as an absorber layer for thin film–based solar cells with appropriate configurations and the SCAPS–1D structures program was used to evaluate the results. In both known and developing thin film photovoltaic systems, a CdS thin–film buffer layer is frequently employed as a traditional n–type heterojunction partner. In this study, numerical simulation was used to determine a suitable non–toxic material for the buffer layer that can be used instead of CdS, among various types of buffer layers (ZnSe, ZnO, ZnS and In₂S₃) and carrier concentrations for the absorber layer (N_A) and buffer layer (N_D) were varied to determine the optimal simulation parameters. Carrier concentrations (N_A from 2 × 10¹² cm⁻³ to 2 × 10¹⁷ cm⁻³ and N_D from 1 × 10¹⁶ cm⁻³ to 1 × 10²² cm⁻³) differed. The results showed that the use of CdS as a buffer–layer–based CdTe absorber layer for solar cell had the highest efficiency (%) of 17.43%. Furthermore, high conversion efficiencies of 17.42% and 16.27% were for the ZnSe and ZnO-based buffer layers, respectively. As a result, ZnO and ZnSe are potential candidates for replacing the CdS buffer layer in thin–film solar cells. Here, the absorber (CdTe) and buffer (ZnSe) layers were chosen to improve the efficiency by finding the optimal density of the carrier concentration (acceptor and donor). The simulation findings above provide helpful recommendations for fabricating high–efficiency metal oxide–based solar cells in the lab.

Pure and Ni-doped (1%, 2%, and 3%) nanostructures were synthesized using a novel laser-assisted chemical bath synthesis (LACBS) technique. For the first time, LACBS was used to create a doping solution utilizing a 7 W blue laser with a 444.4 nm wavelength and a continuous beam. The Ni-doping concentration was varied by changing the amount of Ni precursor added. All samples were analyzed using XRD, SEM, EDX, FTIR, UV–Vis, and photocatalysis tests for photodegradation under blue laser illumination. XRD was used to confirm that the tested ZnO had a hexagonal wurtzite structure. The crystallite size decreased as the Ni-doping concentration rose. EDX experiments were conducted to analyze the elemental characteristics of the pure and Ni-doped (1%, 2%, and 3%) nanostructures. The existence of nanoscale hexagonal structures was confirmed through SEM studies. The band gap values of the pure and Ni-doped ZnO nanostructures decreased as the doping concentration increased. FTIR studies were conducted to examine the functional groups of the pure and doped samples. The produced materials exhibited excellent photocatalytic performance toward the degradation of MB organic dye, an example of a pollutant found in wastewater.

We used the blast wave model with the Boltzmann–Gibbs statistics and analyzed the experimental data measured by the NA61/SHINE Collaboration in inelastic (INEL) proton–proton collisions at different rapidity slices at different center-of-mass energies. The particles used in this study were ${\pi }^{+}$, ${\pi }^{-}$, $K^{+}$, $K^{-}$, and $\overline{p}$. We extracted the kinetic freeze-out temperature, transverse flow velocity, and kinetic freeze-out volume from the transverse momentum spectra of the particles. We observed that the kinetic freeze-out temperature is rapidity and energy dependent, while the transverse flow velocity does not depend on them. Furthermore, we observed that the kinetic freeze-out volume is energy dependent, but it remains constant with changing the rapidity. We also observed that all three parameters are mass dependent. In addition, with the increase of mass, the kinetic freeze-out temperature increases, and the transverse flow velocity, as well as kinetic freeze-out volume decrease.

We analyze the transverse momentum ($p_T$) spectra of ${\pi }^{+}$, ${\pi }^{-}$, $K^{+}$, $K^{-}$, p, $\overline{p}$, $\Lambda$, $\overline{\Lambda }$, $\Xi$, $\overline{\Xi }$, ${\Omega }^{-}$, ${\overline{\Omega }}^{+}$ or ${\Omega }^{-}+{\overline{\Omega }}^{+}$ in different centrality intervals in gold–gold (Au–Au) and lead–lead (Pb–Pb) symmetric collisions at 200 GeV and 2.76 TeV, respectively, by Tsallis–Pareto-type function. Proton–proton collisions at the same centre of mass energies are also analyzed for these particles to compare the results obtained from these systems. The present work extracts the effective temperature T, non-extensivity parameter $\left(q\right)$, the mean transverse momentum spectra ($⟨p_T⟩$), the multiplicity parameter ($N_0$), kinetic freeze-out temperature ($T_0$) and transverse flow velocity (${\beta }_T$). We reported a plateau structure of $p_T$, T, $T_0$, ${\beta }_T$, $p_T$ and q in central collisions. Beyond the plateau region, the excitation function of all the above parameters decreases towards the periphery, except q, which has a reverse trend. The multiplicity parameter is also extracted, which is found to be decreasing towards the periphery from the central collisions. In addition, we observed that the excitation function of pp collisions is nearly the same to that of the most peripheral symmetric nucleus–nucleus collisions at the same colliding energy. Throughout the analyses, the same multiplicity parameters for particles and their antiparticles have been reported, which show the symmetric production of particles and their antiparticles.