Biodegradable plastics can make an important contribution to the struggle against increasing environmental pollution through plastics. However, biodegradability is a material property that is influenced by many factors. This review provides an overview of the main environmental conditions in which biodegradation takes place and then presents the degradability of numerous polymers. Polylactide (PLA), which is already available on an industrial scale, and the polyhydroxyalkanoates polyhydroxybutyrate (PHB) and polyhydroxybutyrate-co-valerate (PHBV), which are among the few plastics that have been proven to degrade in seawater, will be discussed in detail, followed by a summary of the degradability of further petroleum-, cellulose-, starch-, protein- and CO₂-based biopolymers and some naturally occurring polymers.

In response to the global challenge of reducing carbon emissions and energy consumption from regulating indoor climates, we investigate the applicability of biobased cellulosic materials and bioinspired 4D-printing for weather-responsive adaptive shading in building facades. Cellulose is an abundantly available natural material resource that exhibits hygromorphic actuation potential when used in 4D-printing to emulate motile plant structures in bioinspired bilayers. Three key aspects are addressed: (i) examining the motion response of 4D-printed hygromorphic bilayers to both temperature and relative humidity, (ii) verifying the responsiveness of self-shaping shading elements in lab-generated conditions as well as under daily and seasonal weather conditions for over a year, and (iii) deploying the adaptive shading system for testing in a real building facade by upscaling the 4D-printing manufacturing process. This study demonstrates that hygromorphic bilayers can be utilized for weather-responsive facades and that the presented system is architecturally scalable in quantity. Bioinspired 4D-printing and biobased cellulosic materials offer a resource-efficient and energy-autonomous solution for adaptive shading, with potential contributions towards indoor climate regulation and climate change mitigation.

Presently, almost every industry uses conventional plastics. Its production from petroleum and extensive plastic pollution cause environmental problems. More sustainable alternatives to plastics include bioplastics such as poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), which is produced by bacteria and is biodegradable even in seawater. High temperature sensitivity as well as massive thermal degradation cause difficulties during the processing of PHBV. The aim of this work is to create a detailed rheological characterization and master curves to gain deeper knowledge about the material and its processing parameters. The rheological characterization was performed with frequency sweeps in the range of 0.1 rad/s to 628 rad/s and time sweeps over 300 s. Creating master curves at the reference temperature of 180 °C with the software IRIS delivers Carreau and Arrhenius parameters. These parameters allow for a calculation of the master curves for all other temperatures by means of the temperature shift factor. Moreover, the rheological measurements reveal a minimum rheological measurement temperature of 178 °C and a surprisingly high activation energy of 241.8 kJ/mol.