Mineralogy of phosphatized and zeolitized hydrogenous cobalt-rich ferromanganese crusts from Dirck Hartog Ridge (DHR), the Perth Abyssal Plain (PAP), formed on an altered basaltic substrate, is described. Detail studies of crusts were conducted using optical transmitted light microscopy, X-ray Powder Diffraction (XRD) and Energy Dispersive X-ray Fluorescence (EDXRF), Differential Thermal Analysis (DTA) and Electron Probe Microanalysis (EPMA). The major Fe-Mn mineral phases that form DHR crusts are low-crystalline vernadite, asbolane and a feroxyhyte-ferrihydrite mixture. Accessory minerals are Ca-hydroxyapatite, zeolites (Na-phillipsite, chabazite, heulandite-clinoptilolite), glauconite and several clay minerals (Fe-smectite, nontronite, celadonite) are identified in the basalt-crust border zone. The highest Ni, Cu and Co contents are observed in asbolane and Mn-(Fe) vernadite. There is significant enrichment of Ti in feroxyhyte−ferrihydrite and vernadite. The highest rare earth element (REE) content is measured in the phosphate minerals, less in phyllosilicates and Na-phillipsite. The geochemical composition of minerals in the DHR crusts supports the formation of crusts by initial alteration, phosphatization and zeolitization of the substrate basalts followed by oscillatory Fe-Mn oxyhydroxides precipitation of hydrogenous vernadite (oxic conditions) and diagenous asbolane (suboxic conditions).
Late Pleistocene–Holocene rocks from the western part of Cocos-Nazca Spreading Centre (C-NSC) include ferromanganese crusts that elucidate the geochemistry and mineralogy of a deep-sea geological setting. Six representative Fe-Mn crust samples were studied using petrological methods, such as optical transmitted light microscopy, energy dispersive X-ray fluorescence spectrometry, inductively coupled plasma mass spectrometry, bulk X-ray diffraction, scanning electron microscopy and electron probe microanalysis. Geochemical, mineralogical and petrological signatures indicate complex formation influenced by mild hydrothermal processes. These crusts consist mostly of mixed birnessite, todorokite-buserite, and Mn-(Fe) vernadite with traces of diagenetic manganates (asbolane), Fe-oxides and oxyhydroxides or hydrothermally associated and relatively pure Mn-oxyhydroxides (manganite). The average Mn/Fe ratio is 2.7, which suggests predominant mixed hydrogenous-early diagenetic crusts with hydrothermal influences. The mean concentrations of three prospective metals (Ni, Cu and Co) are low: 0.17, 0.08 and 0.025 wt %, respectively. The total content of ΣREY is also low, and ranges from 81 to 741 mg/kg (mean 339 mg/kg). We interpret the complex geochemical and mineralogical data to reflect mixed origin of the crusts, initially related with formation of hydrothermal plume over the region. This process occurred during further interactions with seawater from which additional diagenetic and hydrogenetic elemental signatures were acquired.
11 September 2015 in South African Journal of Geology
The Neoproterozoic Ghanzi Group metasedimentary succession, of northwestern Botswana shows a potential for hosting precious metals. Platinum group minerals (PGM) were discovered in the Quirinus Prospect of the Boseto Exploration Area during preliminary stages of research into copper-silver mineralisation in the D’kar Formation. The PGM are associated mainly with molybdenite, bismuth-bearing minerals and copper sulphides. The combination of reflected light microscopy and SEM-EDAX analyses revealed a presence of Pd-Hg tellurides occurring together with molybdenite and Bi-bearing minerals forming a veinlet cross-cutting a larger quartz-calcite vein. The BSE image shows two mineral phases of diversified chemical composition with concentrations of Pd and Hg reaching maximum of 45.82 weight % and 21.41 weight % respectively.
Indicator minerals (IM) have been used in the research of gemstone and base metals for over 100 years. IMs are a main source of information about the occurrence of deposits, hydrothermal and weathering changes, as well as bedrock source and type. Since 2013, base metal mineral exploration has taken place on New Guinea Island (the Indonesian part). The analysis of chromian spinels as IM in beach and river sediments led to the discovery of rich chromian-bearing deposits in the Botawa River sediments. The dominant detrital minerals include chromian spinels, olivine, pyroxenes and serpentine. The source of chromian spinels, olivine and pyroxenes are most likely peridotites from the Earth’s mantle zone of the ophiolite series, generated under supra-subduction conditions. The terrigenous deposits contain metamorphic minerals, such as staurolites, andalusites, epidotes, amphiboles and fragments of micas, quartz and chlorite schists. Using ICP-MS analysis of the beach sands, the concentration of Cr2O3 was determined to be at the level of 1.17%, while in the heavy minerals concentrate from the Botawa River sediment, the content of Cr2O3 amounts to 24.83%. The authors conclude that the west parts of the Van Rees Mountains are the probable parent rocks for chromium-bearing sediments.