The geochemical and mineralogical characteristics of pelagic sediments collected from the Interoceanmetal Joint Organization (IOM) claim area, located in the eastern part of the Clarion-Clipperton Fracture Zone (CCFZ; eastern tropical Pacific), are described in this paper. The concentrations of rare earth elements (REE), as well as other selected critical elements contained in 135 sediment samples of siliceous clayey silts, are presented. The vertical and spatial variabilities of elements, with particular emphasis on REE as well as metals of the highest economic interest such as Cu, Ni, and Co, are detailed. The applied methods include grain size analysis by laser diffraction, geochemistry examination using ICP-MS, XRF, AAS, and CNS spectrometry, and XRD analysis of mineral composition (Rietveld method). Additionally, statistical methods such as factor analysis (FA) and principal components analysis (PCA) were applied to the results. Finally, a series of maps was prepared by geostatistical methods (universal kriging). Grain size analysis showed poor sorting of the examined fine-grained silts. ICP-MS indicated that total REE contents varied from 200 to 577 ppm, with a mean of 285 ppm, which is generally low. The contents of critical metals such as Cu, Ni, and Co were also low to moderate, apart from some individual sampling stations where total contents were 0.15% or more. Metal composition in sediments was dominated by Cu, Ni, and Zn. A mineral composition analysis revealed the dominance of amorphous biogenic opaline silica (27–58%), which were mostly remnants of diatoms, radiolarians, and sponges associated with clay minerals (23% to 48%), mostly Fe-smectite and illite, with mixed-layered illite/smectite. The high abundance of diagenetic barite crystals found in SEM−EDX observations explains the high content of Ba (up to 2.4%). The sediments showed complex lateral and horizontal fractionation trends for REE and critical metals, caused mostly by clay components, early diagenetic processes, admixtures of allogenic detrital minerals, or scavenging by micronodules.

The detailed mineralogical and microgeochemical characteristics of polymetallic nodules collected from the Interoceanmetal Joint Organization (IOM, Szczecin, Poland) claim area, Eastern Clarion-Clipperton Fracture Zone (CCFZ, Eastern Pacific) were described in this study. The obtained data were applied for the delimitation of nodule growth generations and estimation of the growth ratios (back-stripping using the Co-chronometer method). The applied methods included bulk X-ray powder diffraction (XRD) and electron probe microanalysis (EPMA), providing information about Mn-Fe minerals and clays composing nodules, as well as the geochemical zonation of the growth generations. The analyzed nodules were mostly diagenetic (Mn/Fe > 5), with less influence on the hydrogenous processes, dominated by the presence of 10-Å phyllomanganates represented by todorokite/buserite, additionally mixed with birnessite and vernadite. The specific lithotype (intranodulith), being an integral part of polymetallic nodules, developed as a result of the secondary diagenetic processes of lithification and the cementation of Fe-rich clays (potentially nontronite and Fe-rich smectite), barite, zeolites (Na-phillipsite), bioapatite, biogenic remnants, and detrital material, occurs in holes, microcaverns, and open fractures in between ore colloforms. The contents of ∑(Ni, Cu, and Co) varied from 1.54 to 3.06 wt %. Several remnants of siliceous microorganisms (radiolarians and diatoms) were found to form pseudomorphs. The applied Co-chronometer method indicated that the nodules’ age is mainly Middle Pliocene to Middle Pleistocene, and the growth rates are typical of diagenetic and mixed hydrogenetic–diagenetic (HD) processes. Additionally, few nodules showed suboxic conditions of nucleation. Growth processes in the eastern part of the CCFZ deposit might have been induced with the Plio-Pleistocene changes in the paleooceanographic conditions related to the deglaciation of the Northern Hemisphere.

Mineralogy of phosphatized and zeolitized hydrogenous cobalt-rich ferromanganese crusts from Dirck Hartog Ridge (DHR), the Perth Abyssal Plain (PAP), formed on an altered basaltic substrate, is described. Detail studies of crusts were conducted using optical transmitted light microscopy, X-ray Powder Diffraction (XRD) and Energy Dispersive X-ray Fluorescence (EDXRF), Differential Thermal Analysis (DTA) and Electron Probe Microanalysis (EPMA). The major Fe-Mn mineral phases that form DHR crusts are low-crystalline vernadite, asbolane and a feroxyhyte-ferrihydrite mixture. Accessory minerals are Ca-hydroxyapatite, zeolites (Na-phillipsite, chabazite, heulandite-clinoptilolite), glauconite and several clay minerals (Fe-smectite, nontronite, celadonite) are identified in the basalt-crust border zone. The highest Ni, Cu and Co contents are observed in asbolane and Mn-(Fe) vernadite. There is significant enrichment of Ti in feroxyhyte−ferrihydrite and vernadite. The highest rare earth element (REE) content is measured in the phosphate minerals, less in phyllosilicates and Na-phillipsite. The geochemical composition of minerals in the DHR crusts supports the formation of crusts by initial alteration, phosphatization and zeolitization of the substrate basalts followed by oscillatory Fe-Mn oxyhydroxides precipitation of hydrogenous vernadite (oxic conditions) and diagenous asbolane (suboxic conditions).

Late Pleistocene–Holocene rocks from the western part of Cocos-Nazca Spreading Centre (C-NSC) include ferromanganese crusts that elucidate the geochemistry and mineralogy of a deep-sea geological setting. Six representative Fe-Mn crust samples were studied using petrological methods, such as optical transmitted light microscopy, energy dispersive X-ray fluorescence spectrometry, inductively coupled plasma mass spectrometry, bulk X-ray diffraction, scanning electron microscopy and electron probe microanalysis. Geochemical, mineralogical and petrological signatures indicate complex formation influenced by mild hydrothermal processes. These crusts consist mostly of mixed birnessite, todorokite-buserite, and Mn-(Fe) vernadite with traces of diagenetic manganates (asbolane), Fe-oxides and oxyhydroxides or hydrothermally associated and relatively pure Mn-oxyhydroxides (manganite). The average Mn/Fe ratio is 2.7, which suggests predominant mixed hydrogenous-early diagenetic crusts with hydrothermal influences. The mean concentrations of three prospective metals (Ni, Cu and Co) are low: 0.17, 0.08 and 0.025 wt %, respectively. The total content of ΣREY is also low, and ranges from 81 to 741 mg/kg (mean 339 mg/kg). We interpret the complex geochemical and mineralogical data to reflect mixed origin of the crusts, initially related with formation of hydrothermal plume over the region. This process occurred during further interactions with seawater from which additional diagenetic and hydrogenetic elemental signatures were acquired.

At the Galapagos triple junction in the equatorial Pacific Ocean, the Cocos‐Nazca spreading center does not meet the East Pacific Rise (EPR) but, instead, rifts into 0.4 Myr‐old lithosphere on the EPR flank. Westward propagation of Cocos‐Nazca spreading forms the V‐shaped Galapagos gore. Since ~1.4 Ma, opening at the active gore tip has been within the Cocos‐Galapagos microplate spreading regime. In this paper, bathymetry, magnetic, and gravity data collected over the first 400 km east of the gore tip are used to examine rifting of young lithosphere and transition to magmatic spreading segments. From inception, the axis shows structural segmentation consisting of rifted basins whose bounding faults eventually mark the gore edges. Rifting progresses to magmatic spreading over the first three segments (s1–s3), which open between Cocos‐Galapagos microplate at the presently slow rates of ~19–29 mm/year. Segments s4–s9 originated in the faster‐spreading (~48 mm/year) Cocos‐Nazca regime, and well‐defined magnetic anomalies and abyssal hill fabric close to the gore edges show the transition to full magmatic spreading was more rapid than at present time. Magnetic lineations show a 20% increase in the Cocos‐Nazca spreading rate after 1.1 Ma. The near‐axis Mantle Bouguer gravity anomaly decreases eastward and becomes more circular, suggesting mantle upwelling, increasing temperatures, and perhaps progression to a developed melt supply beneath segments. Westward propagation of individual Cocos‐Nazca segments is common with rates ranging between 12 and 54 mm/year. Segment lengths and lateral offsets between segments increase, in general, with distance from the tip of the gore.