In the tire industry, the combination of carbon black and silica is commonly utilized to improve the comprehensive performance of natural rubber so as to realize the best performance and cost-effectiveness. The corresponding mixing is divided into three processes (initial mixing, delivery, reactive mixing) by the serial modular continuous mixing method, thus achieving more accurate control of the mixing process, higher production efficiency and better performance. Moreover, the optimization of serial modular continuous mixing process parameters can not only improve the performance of composite materials, but help people understand the physical and chemical changes and the reinforcing mechanism of fillers in the mixing process. In this paper, the relationship among the parameters of eight processes and filler network structure, tensile strength, chemical reinforcing effect and tear resistance was explored through experiments. The deep causes of performance changes caused by parameters were analyzed. Consequently, the best process condition and the ranking of the influencing factors for a certain performance was obtained. Furthermore, the best preparation process of natural rubber (NR)/carbon black/silica composite was achieved through comprehensive analysis.

The disposal of used automobile tires is a major waste concern. Simply stacking tires and allowing them to decompose will harbor breeding mosquitoes that spread viruses, whereas burning them will release acidic and toxic gases. Therefore, one viable option is pyrolysis, where elevated temperatures are used to facilitate the decomposition of a material. However, the lack of theoretical support for pyrolysis technology limits the development of the pyrolysis industry when it comes to discarded tires. The purpose of this research is to put forward a brand-new multi-kinetic research method for studying materials with complex components through the discussion of various kinetic research methods. The characteristic of this kinetic research method is that it is a relatively complete theoretical system and can accurately calculate the three kinetic factors considered during the pyrolysis of multicomponent materials. The results show that the multi-kinetic research method can obtain the kinetic equation and reaction mechanism for the pyrolysis of tires with high accuracy. The pyrolysis process of this compound was divided into two stages, Reaction I and II, where the kinetic equation of Reaction I was $f\left(\mathsf{\alpha }\right)=0.2473{\mathsf{\alpha }}^{-3.0473}$ , with an activation energy of 155.26 kJ/mol and a pre-exponential factor of 5.88 × 10⁹/min. Meanwhile, the kinetic equation of Reaction II was $f\left(\mathsf{\alpha }\right)=0.4142\left(1-\mathsf{\alpha }\right){[-\ln \left(1-\mathsf{\alpha }\right)]}^{-1.4143}$ , while its activation energy was 315.40 kJ/mol and its pre-exponential factor was 7.86 × 10¹⁷/min. Furthermore, based on the results of the research analysis, the reaction principles corresponding to Reaction I and Reaction II in the pyrolysis process of this compound were established.