Although photocatalytic concrete can significantly contribute to the degradation of air pollutants and improving the sustainability levels, the complexity of ordinary cement system often caused the uncertain performance of mixed photocatalysts, which limited the real application of photocatalysts. Since the rapid carbonization hardening and relatively simple composition, γ-C₂S carbonated binding material has gained considerable attention for its application in construction material. In this work, quartz sand-supported TiO₂-C₂S(γ) composites (TQSC) were prepared by mixing photocatalytic quartz sand with γ-C₂S and mounting in γ-C₂S matrix surface methods. The TiO₂-coated quartz sand (TQS) was characterized by X-ray diffraction (XRD), quantitative X-ray fluorescence (XRF) and scanning electron microscopy (SEM). The photocatalytic performance and durability (washing resistance) of TQSC were also investigated by the degradation ability of NOx and rhodamine B (RhB). The results show that a uniform TiO₂ layer on quartz sand was prepared, and the photocatalytic De-NOx (degradation of NOx) performance increased with increasing the mounted amounts of TiO₂/quartz sand in γ-C₂S carbonated matrix surface, but would decrease the photocatalytic durability. After water-washing, the De-NOx efficiencies of TQSC specimens decreased quickly at the beginning, which were adhering to the mounted amounts of TiO₂/quartz sand, but would become stable after water-washing for 3600 s for all samples. The relatively high De-NOx stability and good self-cleaning effect of the water-washed TQSC-60% specimen can be considered a promising photocatalytic product for real applications.