Different fractions of hemp shives are used in the mixtures of the hemp–lime composite. The market offers shives of different granulation. It depends on the type of industrial hemp and on the capabilities of decortication machines. The aim of the research presented in the article is to check differences in the mechanical and hygro-thermal properties of composites with different shives fractions. The research part of the paper presents the preparation method and investigation on hemp–lime composites. Apparent density, total porosity, thermal conductivity, capillary uptake, vapor permeability, specific heat, mass absorptivity, flexural and compressive strength were examined. The results confirm that the shives fraction influences the individual properties of the composites. Hemp–lime composites with fine shives are characterized by higher water absorption, thermal conductivity, mechanical strength, vapor permeability as well as lower capillary-lifting capacity and specific heat than composites with thick shives.
The evolution of bio-based composites in the building industry is strongly linked with the growing demand for sustainable development, which is relevant nowadays. Hemp shives are a large group of organic residues that are obtained in the process of oil extraction as well as straw processing. These residues could be utilized along with a binder as constituents in the manufacture of bio-based building composites. This study is focused on the impact of density and relative humidity on the effective thermal conductivity of hemp shive-based bio-composites with a magnesium binder. For this reason, a series of samples with variable densities was manufactured and subjected to conditioning in a climatic chamber at a constant temperature and different relative humidity settings. As soon as samples were stabilized, the guarded hot plate method was applied to determine their thermal conductivities. Before each measurement, great care was taken during sample preparation to ensure minimum moisture loss during long-lasting measurements. The results showed that an increase in sample density from 200 kg/m3 to 600 kg/m3 corresponded to up to a three-fold higher composite thermal conductivity. In the case of sample conditioning, a change in relative humidity from a very low value to 90% also resulted in almost 60% average higher thermal conductivity.
The paper presents the initial approach to mathematical and numerical modelling and optimization of heat and mass transfer in elements of the masonry wall. The considered single moist brick is placed in the channel through which the dry air is flowing. Only one wall of the brick is in contact with the flowing air and through this boundary heat and moisture are exchanged. The non-equilibrium mathematical model is formulated for general case with three phases of moisture present in the porous building material, i.e., water vapour in the moist air filling the pores, liquid water (bound water) adsorbed at the surface of the solid component of the material and free liquid water either in a discontinuous form (funicular) or continuous one (pendular). However, at this stage of development of the numerical model the moisture in the form of motionless liquid water and water vapour which reside in the ceramic material are considered. Moreover, the moisture and heat diffusion in the porous hydroscopic material of the brick as well as moisture and heat convection in the flowing air are assumed. The numerical model is developed with the aid of the commercial software ANSYS Fluent and its advanced customisation functionalities like the User-Defined Function, User-Defined Scalar and User-Defined Memory. Subsequently, investigation of the influence of the mass transfer coefficient between the free liquid water and moist air in the porous building material are carried out.
The study aimed to investigate the effect of processing temperature and the content of multi-wall carbon nanotubes (MWCNTs) on the rheological, thermal, and electrical properties of polyphenylene sulfide (PPS)/MWCNT nanocomposites. It was observed that the increase in MWCNT content influenced the increase of the complex viscosity, storage modulus, and loss modulus. The microscopic observations showed that with an increase in the amount of MWCNTs, the areal ratio of their agglomerates decreases. Thermogravimetric analysis showed no effect of processing temperature and MWCNT content on thermal stability; however, an increase in stability was observed as compared to neat PPS. The differential scanning calorimetry was used to assess the influence of MWCNT addition on the crystallization phenomenon of PPS. The calorimetry showed that with increasing MWCNT content, the degree of crystallinity and crystallization temperature rises. Thermal diffusivity tests proved that with an increase in the processing temperature and the content of MWCNTs, the diffusivity also increases and declines at higher testing temperatures. The resistivity measurements showed that the conductivity of the PPS/MWCNT nanocomposite increases with the increase in MWCNT content. The processing temperature did not affect resistivity.