Sand-cement emerged in the early twentieth century as an alternative binder in infrastructures that required a significant amount of concrete volume in order to reduce the costs associated with portland cement. This binder was first used in the United States in several dams before being applied in Camarasa Dam in Spain. Nearly a century after its construction, the dam exhibits degradation phenomena in the downstream face, manifested by losses of mass. The present study aims at assessing the state of the sand-cement concrete in Camarasa Dam and evaluate whether the degradation observed could affect the safety and functionality of the 95-year-old dam. For that, the state of the art on sand-cement is reviewed and an experimental program of physical, mechanical, and chemical tests is performed on samples from the dam. The results reveal that the degradation phenomena may be attributed to physical causes and a general degradation of the concrete properties is discarded as well as any effect on the safety and functionality of the dam.

A correct assessment of the pathologies that can affect a reinforced concrete structure is required in order to define the repair procedure. This work addresses the challenge of quantifying chlorides and sulphates directly on the surface of concrete. The quantification was carried out by means of X-ray fluorescence analysis on the surface of concrete specimens at different points with portable equipment. Concrete prisms were made with different amounts of NaCl and Na₂SO₄. To avoid the influence of coarse aggregate, a qualitative estimate of the amount of coarse aggregate analyzed has been made, although the results show that there is no significant influence. Monte Carlo simulations were carried out in order to establish the necessary number of random analyses of the mean value to be within an acceptable range of error. In the case of quantifying sulphates, it is necessary to carry out six random analyses on the surface, and eight measurements in the case of quantifying chlorides; in this way, it is ensured that errors are below 10% in 95% of the cases. The results of the study highlight that a portable XRF device can be used in situ to obtain concentrations of chlorides and sulphates of a concrete surface with good accuracy. There is no need to take samples and bring them to a laboratory, allowing lower overall costs in inspection and reparation works.