Optical polymers are recognized for their high transparency, raised flexibility, low cost, and good film-forming ability; hence, they introduce a multitude of benefits in a wide range of devices, such as information storage, displays, optical communications, and filters. Among the optical properties, birefringence is an essential parameter in practical cases that demand the control of the state of polarization of light. This review is focused on describing some fundamental and applicative aspects concerning the optical birefringence of the polymer materials. First, elementary notions depicting the phenomenon of light double refraction in macromolecular media are provided. Furthermore, the most relevant optical techniques to determine birefringence are reviewed by highlighting the working principle and mathematical basis for computing this parameter. Then, a series of investigations of optically birefringent polymers are described, summarizing the most utilized approaches to induce light double refraction in such materials. The selected results are analyzed in relation to the pursued applications. In the end, the future of this scientific domain is briefly presented by establishing the research paths that need further exploration. Moreover, the novel directions that could be formulated and might contribute to certain considerable advancements in the materials employed in the modern optical technologies are mentioned.

A simple method for determining the linear birefringence of the thin layers based on the determination of the orientation of the polarization ellipse of totally polarized light is proposed and it is applied to PVA thin foils. Theoretical notions and the experimental procedure are described. The linear birefringence of polymer thin foils with different degrees of stretching is determined and the applicability of the method is discussed.

Thermoplastic polymers have found widespread applicability in electronic industry owing to their facile processing and relatively low costs. Transparent polymer foils, like polyethylene terephthalate (PET), can be utilized in manufacturing components for liquid crystal display (LCD) devices. This work is focused on surface processing of PET through different procedures. The induced surface modifications of polymer samples were analyzed by optical microscopy. Contact angles of nematic drops on PET film are measured to evaluate how the method of surface modification reveals that the surface texturing affects the interactions of polymer with the liquid crystal. The influence of created surface anisotropy on the work of adhesion at polymer/liquid crystal interface is analyzed. Preliminary assessment of nematic orientation on the surface of modified PET foils is performed using polarized light. The results were discussed in regard with the used methodology to adapt the surface of the PET films to achieve optimal orientation of nematic molecules. The obtained data will open new perspectives on processing polymer foils as alignment layers used in LCD devices.