In order to achieve effective eutrophication control and ecosystem restoration, it is of great significance to investigate the distribution characteristics of nutrient elements in sediments, and to perform ecological risk assessments. In the current grading criteria for nutrient elements in sediments, only the overall or organic components of carbon, nitrogen and phosphorus are considered, while the specific species distributions and bioavailability characteristics are rarely taken into account. Hence, using the current grading criteria, the differences in the release, migration and biological activity of nutrient elements in sediments cannot be accurately reflected. Taking the upper reaches of the Minjiang River watershed as an example, we analyzed the overall distributions and the ratio of nutrient elements in sediments, the spatial changes of nitrogen and phosphorus forms, the bioavailability, and the environmental significance. The ecological risk of nitrogen and phosphorus in sediments was assessed using an evaluation method based upon the biological effective parameter. The results were compared with the results of the evaluation methods based on the single pollution index, and then these evaluation methods were confirmed accordingly. From the results, the following conclusions can be obtained: (1) The spatial distributions of nutrient elements in sediments in the upper reaches of the Minjiang River Watershed (including the Jianxi Basin, Futunxi Basin, and Shaxi Basin) were significantly affected by the local ecology and the urban sewage discharge system. (2) The maximum average contents of total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP) in sediments were observed in the Jianxi Basin, the Futunxi Basin and the Shaxi Basin, respectively. (3) According to the contents of nitrogen and phosphorus in sediments, the bioavailable nitrogen (TTN) accounted for 35.49% of the total contents of TN. The components of TTN can be sorted from high to low as follows: Nitrogen in organic sulfide form (SOEF-N) > nitrogen in iron-manganese oxide form (SAEF-N) > nitrogen in ion exchange form (IEF-N) > nitrogen in weak acid leaching form (WAEF-N). Inorganic phosphorus (IP) was the main component of TP. The components of IP can be sorted from high to low as follows: Metal oxide bound phosphorus (NaOH-P) > calcium bound phosphorus (HCl-P) > reduced phosphorus (BD-P) > weakly adsorbed phosphorus (NH₄Cl-P). Meanwhile, bioavailable phosphorus (BAP, BAP = NH₄Cl-P + BD-P + NaOH-P) accounted for 36.94% of TP. According to the results of the single pollution index method, the risk level of TOC pollution in the sediments was relatively low in the whole area, while the risk level of TN pollution was low or moderate in most zones, and severe in certain ones. The risk level of TP pollution was low to moderate. (4) From the results of the bioavailability index evaluation method, based on the total amounts and forms of N and P, the risk level of N pollution was moderate, while the risk of P pollution was negligible. In addition, the results of the bioavailability index evaluation method were more consistent with the actual situation and reflected the overall environmental effects of nitrogen and phosphorus.

Phosphorus is an essential element for life, an innate constituent of soil organic matter, and a major anthropogenic input to terrestrial ecosystems. This paper employed the sequential extraction method for phosphorus fraction to study the distribution of phosphorus in different region in Wuyishan. Hierarchical cluster and correlation were used for investigating the relationship between the phosphorus form and tea quality-related constituents in Zhengyan Rock Tea (ZYRT), Banyan Rock Tea (BYRT) and Zhou Rock Tea (ZRT). The result showed that the concentration of phosphorus in different regions followed this order: ZYRT>BYRT>ZRT. The relative contribution of phosphorus fraction in different regions show the similar trend: Metal Oxide Bound Phosphorus (NaOH-P)>Calcium Bound Phosphorus (HCl-P)> Reduced Phosphorus (BD-P)>Adsorbed Phosphorus (NH4Cl-P). The maximum content of water extract (WE), caffeine (CF), tea polyphenols (TPP) and total amount of amino acids (TAA) in tea leaves is in ZYRT, followed BYRT, and least in the ZRT. The phosphorus forms seem to have no obvious effects on the tea quality in the ZYRT and BYRT area, while TPP and NaOH-P, TPP and HCl-P are significantly positively correlated (r = 0.912, r = 0.956, r = 0.938; p<0.01) in ZRT.