In this study, the characteristics and distribution of the organic phosphorus (Po) fractions in the surface sediments of seven inflow rivers around Hongze Lake in China were analyzed with a soil Po fraction method, as used by Ivanoff. The relationships between the Po fractions and physiochemical features of sediments were also discussed. The results showed that, the sediments of the rivers had been moderately pollution with certain ecological risk effects except the Waste Yellow River. The relative contribution order of the Po fractions in the sediments was residual Po > HCl-Po > fulvic acid-Po > humic acid-Po > labile organic phosphorus (LOP). Moderately labile organic phosphorus (MLOP) was the main part of the Po forms in the whole sediments. The risk of phosphorus released from river sediments was the highest in the western region, followed by the southwestern region, and finally the northwestern region. There were significant correlations between Po forms and total phosphorus (TP), inorganic phosphorus (Pi), and Po. Non labile organic phosphorus (NLOP) had the strongest correlation with TP. The distribution of Po forms in each region was different due to the impact of human activities, industrial and agricultural production and the land types; the heaver polluted sediments with higher Po fractions. It is suggested that most of the sediments of the inflow rivers in the regions have certain ecological risk effects and P of them have an important contributions on the eutrophication of Hongze Lake. Po forms can provide a reliable theoretical basis for dealing with the change of water quality and should be paid more attention in the lake eutrophication investigation. There was reciprocal transformation between different Po forms, especially non-bioavailable fraction can change into bio-available ones. The results can provide a basis for the earth cycle of phosphorus and a new perspective of eutrophication control of shallow lakes.

In order to achieve effective eutrophication control and ecosystem restoration, it is of great significance to investigate the distribution characteristics of nutrient elements in sediments, and to perform ecological risk assessments. In the current grading criteria for nutrient elements in sediments, only the overall or organic components of carbon, nitrogen and phosphorus are considered, while the specific species distributions and bioavailability characteristics are rarely taken into account. Hence, using the current grading criteria, the differences in the release, migration and biological activity of nutrient elements in sediments cannot be accurately reflected. Taking the upper reaches of the Minjiang River watershed as an example, we analyzed the overall distributions and the ratio of nutrient elements in sediments, the spatial changes of nitrogen and phosphorus forms, the bioavailability, and the environmental significance. The ecological risk of nitrogen and phosphorus in sediments was assessed using an evaluation method based upon the biological effective parameter. The results were compared with the results of the evaluation methods based on the single pollution index, and then these evaluation methods were confirmed accordingly. From the results, the following conclusions can be obtained: (1) The spatial distributions of nutrient elements in sediments in the upper reaches of the Minjiang River Watershed (including the Jianxi Basin, Futunxi Basin, and Shaxi Basin) were significantly affected by the local ecology and the urban sewage discharge system. (2) The maximum average contents of total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP) in sediments were observed in the Jianxi Basin, the Futunxi Basin and the Shaxi Basin, respectively. (3) According to the contents of nitrogen and phosphorus in sediments, the bioavailable nitrogen (TTN) accounted for 35.49% of the total contents of TN. The components of TTN can be sorted from high to low as follows: Nitrogen in organic sulfide form (SOEF-N) > nitrogen in iron-manganese oxide form (SAEF-N) > nitrogen in ion exchange form (IEF-N) > nitrogen in weak acid leaching form (WAEF-N). Inorganic phosphorus (IP) was the main component of TP. The components of IP can be sorted from high to low as follows: Metal oxide bound phosphorus (NaOH-P) > calcium bound phosphorus (HCl-P) > reduced phosphorus (BD-P) > weakly adsorbed phosphorus (NH₄Cl-P). Meanwhile, bioavailable phosphorus (BAP, BAP = NH₄Cl-P + BD-P + NaOH-P) accounted for 36.94% of TP. According to the results of the single pollution index method, the risk level of TOC pollution in the sediments was relatively low in the whole area, while the risk level of TN pollution was low or moderate in most zones, and severe in certain ones. The risk level of TP pollution was low to moderate. (4) From the results of the bioavailability index evaluation method, based on the total amounts and forms of N and P, the risk level of N pollution was moderate, while the risk of P pollution was negligible. In addition, the results of the bioavailability index evaluation method were more consistent with the actual situation and reflected the overall environmental effects of nitrogen and phosphorus.

Non-point source pollution is widely considered a serious threat to drinking water. Eutrophication in Chinese watershed is mainly due to nitrogen and phosphorus output from agricultural source. Taihu Lake is a typical eutrophic lake in China, a basin representative for the study of the temporal-spatial characteristics of pollution loading of nitrogen and phosphorus to provide scientific basis for reasonable estimation and targeted control measures of nitrogen and phosphorus loss. Based on data from nitrogen and phosphorus loss in agricultural land, livestock breeding, domestic discharge and aquaculture, this study calculated the levels of nitrogen and phosphorus comprehensive loss risk for each pollution source. Using the superposition of ArcGIS raster data, we also described the spatial distribution of nitrogen and phosphorus comprehensive loss risk by the formula of comprehensive loss risk. The results showed that critical risk areas of nitrogen and phosphorus loss mainly originated from livestock breeding and agricultural land during flood period in Tiaoxi watershed. Agricultural land and livestock breeding sources formed major parts of nitrogen loss, accounting for 30.85% and 36.18%, respectively, while phosphorus loss mainly originated from livestock breeding (56.28%). During non-flood period, integrated management of livestock breeding and domestic discharge requires much attention to control nitrogen and phosphorus loss in the critical risk area. Finally, it is of great practical significance to propose spatial-temporal targeted measurements to control nitrogen and phosphorus pollution in watershed for various periods and different areas.

Phosphorus is an essential element for life, an innate constituent of soil organic matter, and a major anthropogenic input to terrestrial ecosystems. This paper employed the sequential extraction method for phosphorus fraction to study the distribution of phosphorus in different region in Wuyishan. Hierarchical cluster and correlation were used for investigating the relationship between the phosphorus form and tea quality-related constituents in Zhengyan Rock Tea (ZYRT), Banyan Rock Tea (BYRT) and Zhou Rock Tea (ZRT). The result showed that the concentration of phosphorus in different regions followed this order: ZYRT>BYRT>ZRT. The relative contribution of phosphorus fraction in different regions show the similar trend: Metal Oxide Bound Phosphorus (NaOH-P)>Calcium Bound Phosphorus (HCl-P)> Reduced Phosphorus (BD-P)>Adsorbed Phosphorus (NH4Cl-P). The maximum content of water extract (WE), caffeine (CF), tea polyphenols (TPP) and total amount of amino acids (TAA) in tea leaves is in ZYRT, followed BYRT, and least in the ZRT. The phosphorus forms seem to have no obvious effects on the tea quality in the ZYRT and BYRT area, while TPP and NaOH-P, TPP and HCl-P are significantly positively correlated (r = 0.912, r = 0.956, r = 0.938; p<0.01) in ZRT.

Soil erosion is an important part of land ecological change and global environmental change. In southern China, the red soil hilly area is a region with serious soil erosion and water and soil loss. In this study, the spatial distribution of soil erosion and its change induced by land use types were obtained with the spatial operation analysis technology of a geographic information system and the revised universal soil loss equation model (RUSLE). The results show that soil erosion is most very lightly eroded in the study area as a whole, and has a wide yet relatively concentrated distribution, namely spatial aggregation distribution. The average soil erosion rate is the highest in Zhenghe County, followed by Wuyishan City, Shunchang County and Changting County, and relatively low in other counties. Further analysis on soil erosion under different land use types shows that erosion is more serious in unused land, orchard, dry land and rural settlements, and less severe in grassland, urban land, woodland and paddy field. This can be explained by the differences in vegetation cover, soil and water conservation measures, and the degree of human disturbance under different land use patterns.

The decline in primary natural forests worldwide has intensified research on the effects of forest transformation on soil carbon (C), nitrogen (N), and phosphorus (P) cycles and stocks. However, the extent to which soil C, N, and P stocks and stoichiometry are affected by forest conversion remains unclear. Here, we examined the effects of forest transformation on soil nutrient storage capacity and stoichiometric characteristics in native broadleaf forests (BFs), plantation forests (PFs), tea gardens (TGs), cultivated lands (CLs), and urban artificial green spaces (GSs) at a county scale in subtropical China. The results showed that the other forest types exhibited significantly reduced soil C and N contents and stocks but increased soil P content and stock compared to BFs. The soil C:N:P stoichiometric ratios for BFs and the converted PFs, TGs, GSs, and CLs were sequentially decreased as follows: 444.8:24.2:1, 95.0:10.0:1, 30.2:3.9:1, 23.1:3.7:1, and 19.4:1.9:1, respectively. Within the altitude (AL) span of 180 to 1200 m surveyed, the AL decided the type of forest conversion and significantly influenced the stock levels and stoichiometric ratios of soil C, N, and P. The results of this study highlight the importance of the ecological management of TGs and the optimization of soil P production in CLs, TGs, and GSs.