The PietraAlberese is a marly limestone belonging to the Ligurian series (Monte Morello Formation of Eocene age). It is a material rarely mentioned in the historical Florentine architecture because the Pietraforte, the stone of the Medieval Florence and the Pietra Serena, the stone of the Renaissance, were the main lithotypes commonly used in those periods. Nevertheless, the Pietra Alberese has been widely utilized to build the town, because it is the only limestone cropping out in this part of Tuscany allowing the production of lime. In Prato and Pistoia, the Pietra Alberese was also used as stone (e.g., ashlars) in the structures and façades of many public and religious buildings. In this work, the geological setting and a mineralogical, petrographic and physical characterization of Pietra Alberese used as building stone are proposed together with a discussion about its durability. Moreover, the different compositional and macroscopic characteristics of two lithotypes (namely the sasso alberese and sasso porcino) utilized to produce the two types of lime used in the local traditional architecture (calcina dolce and calcina forte) are highlighted.

The Portofino Conglomerate (PC) cropping out in the Eastern Liguria is an approximately 500 m thick, very gently folded succession mainly composed of poorly bedded and mostly matrix-supported conglomerates. It stratigraphically rests on the Helminthoid Flysch (UA3) thrusted onto the Antola Unit. We vertically distinguished three mostly ruditic litho/petrofacies: (i) Paraggi (fP) with carbonate clasts from an Helminthoid Flysch succession; (ii) Monte Pallone (fMP) with prevailing carbonate and meta-carbonate clasts and minor quartz-rich (meta)siliciclastic and high-pressure–low-pressure (HP-LP) metabasite clasts; and (iii) Monte Bocche (fMB) with dominant quartz-rich (meta)siliciclastic, meta-carbonate clasts, and minor granitoid elements and medium-temperature–high-temperature (MT-HT) regional metamorphic rocks. The middle-upper Eocen age of Paraggi litho/petrofacies is constrained by well-preserved microforaminifers (e.g., Globigerinatheka) recovered in the matrix. During its sedimentation, the directions of the paleocurrents would indicate that the PC underwent a counterclockwise rotation coeval with the first Cenozoic rotational phase of the Sardinia–Corsica system (50–30 Ma) and then stopped before the sedimentation of the Monte Pallone and Monte Bocche litho/petrofacies. The vertical compositional variation in the sedimentary inputs suggested that the PC is the result of a progressive deepening of the erosional level of a tectonic pile that can be located in the Ligurian Alps Chain. We considered the PC as the likely apical part of a submarine fan deposited in a piggy-back/thrust-top basin within the Alpine nappe stack. This sedimentary body was later tectonically transported eastward with its UA3 Helminthoid Flysch substrate (similarly to Epiligurian Units of the Northern Apennines) onto the Apenninic orogenic system (i.e., the Antola Unit).

The study was performed in central-northern Anatolia (from Ankara to Amasya) to investigate the relationships of the Sakarya Zone units and the Izmir-Ankara-Erzincan suture (IAES) melange. It reveals that all the Sakarya Zone units are metamorphic and three main tectonostratigraphic units have been distinguished for the first time: the BAA (metasiliciclastic rocks capped by metacarbonates and varicoloured phyllite), the BKC (poly-metamorphic garnet-bearing micaschist and metabasite with a well-preserved relict HP-LT amphibole in a low-amphibolitic to greenschist-facies framework) and the AMC (meta-arkose passing vertically to carbonate-phyllitic alternations and, then, to a thick succession of prevailing acidic to intermediate-basic metavolcanites and volcanic-rich metasediments). The BAA and AMC, whose metamorphic frameworks are of Cimmerian age, underlie the Mesozoic carbonate cover sequences (e.g. t(2-3,) j(3)-k(1)) that often show tectonic detachments and slicing. The piling up of the BAA above the HP-LT BKC can be correlated to the tectonic superposition of two similar units (i.e. the Cimmerian Cangalda Complex and the Alpine Middle-Upper Cretaceous Domuzda Complex, respectively) defined by previous authors in other sectors of the Central Pontides front. The ophiolitic melange generally underlies the Sakarya Zone, but locally (e.g. SE of Amasya) tectonically rests above the latter, probably owing to back-thrusting that occurred during the Tertiary syn-collisional shortenings and the later strike-slip tectonics. We hypothesize that, also in these areas, the Sakarya Zone-IAES consists of a complex tectonic stack of different units, belonging to different palaeogeographic domains and orogenic events (Cimmerian versus Alpine orogenies), but originated within a single long-lived (since Late Triassic to Paleocene/Eocene times), prograding subduction-accretion system in front of the Laurasian continent.

The present study is aimed at providing a brief overview of the Italian acidic waters based on literature and unpublished data. Acidic waters in Italy, as elsewhere, are relatively common and associated with extremely variable geological settings. Owing to their peculiar features, these waters may seriously affect the environment and the ecosystems. Along the Apennine belt, the western and inner sectors of the Italian peninsula record an anomalous geothermal gradient, mostly overlapping with the Neogene-to-present magmatism, that explains the presence of a huge amount of CO2(H2S)-rich gas and thermal water discharges, geothermal fields (e.g. Larderello and Mt. Amiata) and ore deposits (e.g. Fe- and polymetallic sulfides, e.g. Elba Island and Colline Metallifere). Acidic waters (pH ≤5) from volcanic and geothermal areas show outlet temperatures and Total Dissolved Solids (TDS) from 10 to 96°C and <1 to ≈30 g/L, respectively, with a chemical composition usually belonging to the Ca-SO4, NH4-SO4 or Na-Cl facies. Frequently, they are related to bubbling and boiling pools due to the interaction between deepsourced gases and shallow aquifers or meteoric waters. Concentrations of heavy metals and metalloids are in most cases high. Extremely high contents of metals are also recorded for those acidic waters that characterize the main Italian mining districts, mostly located in Sardinia (not included in the present study), Tuscany and NW Alps, where they are related to Acid Mine Drainage l.s. or Acid Rock Drainage. The pH values are as low as 2.08, with variable TDS concentrations. Compositionally, they are Na-SO4, Ca(Mg)-SO4, and/or Mg(Ca)-SO4 waters, prevalently due to oxidative processes affecting polymetallic sulfides.