Two novel multifunctional HLCT materials, namely OCI and OCT, were presented and they proved to be better green hosts than CBP. Acting as a deep-blue emitter, the OCI-based device achieved an EQE of 5.06% and CIEy < 0.04 with an EL peak at 424 nm.
Two novel bipolar carbazole/diphenylquinoxaline-based host materials 3-(2,3-diphenylquinoxalin-6-yl)-9-phenyl-9H-carbazole (M1) and 3-(4-(2,3-diphenylquinoxalin-6-yl)phenyl)-9-phenyl-9H-carbazole (M2) have been rationally designed and synthesized. The phenyl spacer between the functionalized quinoxaline moiety and the carbazole moiety is also introduced to investigate its influence on their photophysical properties. The chemical structures, and thermal, photophysical and electrochemical properties of the two host materials were characterized and explored in detail. Red phosphorescent light-emitting diodes with M1 and M2 as hosts were prepared to explore their electroluminescent properties. Both M1 and M2 host-based red devices exhibit outstanding electroluminescent performance. For example, two red devices all realize good red emission with the maximum at 594 nm, the maximum external quantum efficiency and luminance can reach 14.66% and 28 619 cd m−2 for M1-based devices and 15.07% and 28 818 cd m−2 for M2-based devices, indicating compounds M1 and M2 designed in this work have potential applications in the development of high-performance monochrome and white OLEDs.
Self-designed (NbTi)C nanoparticles were obtained by mechanical alloying, predispersed in Fe powder, and then added to 1045 steel to obtain modified cast steels. The microstructure of cast steels was investigated by an optical microscope, scanning electron microscope, X-ray diffraction, and a transmission electron microscope. The results showed that (NbTi)C particles can be added to steels and occur in the following forms: original ellipsoidal morphology nanoparticles with uniform dispersion in the matrix, cuboidal nanoparticles in the grain, and microparticles in the grain boundary. Calculations by Thermo-Calc software and solubility formula show that cuboidal (NbTi)C nanoparticles were precipitated in the grain, while the (NbTi)C microparticles were formed by eutectic transformation. The results of the tensile strength of steels show that the strength of modified steels increased and then declined with the increase in the addition amount. When the addition amount was 0.16 wt.%, the modified steel obtained the maximum tensile strength of 759.0 MPa, which is an increase of 52% compared with to that with no addition. The hardness of the modified steel increased with the addition of (NbTi)C nanoparticles. The performance increase was mainly related to grain refinement and the particle strengthening of (NbTi)C nanoparticles, and the performance degradation was related to the increase in eutectic (NbTi)C.